14 results match your criteria: "and Waste Management Centre[Affiliation]"

Experimental study for the decontamination of various surfaces from Mo using PVA/Borax/Al(OH) strippable hydrogel.

Appl Radiat Isot

November 2024

Analytical Chemistry and Control Department, Hot Labs and Waste Management Centre, Egyptian Atomic Energy Authority, Cairo, Egypt; Radioactive Waste Management Unit, Hot Labs and Waste Management Centre, Egyptian Atomic Energy Authority, Cairo, Egypt.

Polyvinyl alcohol (PVA) is a beneficial polymer capable of forming hydrogels helpful in a wide range of applications. Hydrogels based on cross-linking of PVA with borax, and able to incorporate with a decontaminating agent have been used in the decontamination of Mo from contaminated surfaces. Aluminum hydroxide has been introduced in the formulations of PVA-borax, to increase the gel efficiency for Mo decontamination from surfaces.

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Article Synopsis
  • The study investigates the sorption of strontium (Sr(II)) and europium (Eu(III)) ions from water using a synthesized tin molybdate talc sorbent made through a precipitation method.
  • Various analytical techniques (e.g., FT-IR, SEM, XRD) were used to characterize the sorbent and the sorption process was influenced by factors like pH, shaking time, and concentration of the ions.
  • Results indicate that the sorption process is efficient, being endothermic and spontaneous, with 0.1 M HCl found to be the most effective for recovering the ions from the sorbent, suggesting its potential for practical applications in removing these contaminants from water.
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The crystalline phase of molybdenum titanium tungsto-phosphate (MoTiWPO) as an inorganic sorbent material was synthesized via the sol-gel method. The physicochemical characteristics of MoTiWPO were evaluated by using Fourier transform infrared (FT-IR), scanning electron microscope (SEM), energy dispersive X-ray (EDX), thermal analysis (TGA-DTA), and X-ray diffraction (XRD). MoTiWPO sorbent material exhibits a high chemical resistance to HNO, HCl, and alkaline media.

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Polymeric gel for surface decontamination of long-lived gamma and beta-emitting radionuclides.

Appl Radiat Isot

July 2023

Analytical Chemistry and Control Department, Hot Labs and Waste Management Centre, Egyptian Atomic Energy Authority, Cairo, Egypt; Radioactive Waste Management Unit, Hot Labs and Waste Management Centre, Egyptian Atomic Energy Authority, Cairo, Egypt.

Synthesis and characterization of strippable polymeric-gel solution based on a water-soluble polymer (PVA), plasticizing agent (glycerol), and chelating agent (8-Hydroxyquinoline) for the surface decontamination from Cs and Co was carried out. Decontamination of glass and PVC surfaces was investigated in the present study, as a function of various chelating agents, gel-layer thickness, and radioactivity level. The decontamination efficiency was up to 95% for both radionuclides after 24 h of contact time with the contaminated surface.

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This article studied the sorption behavior of Cs(I) ions from aqueous solutions onto molybdenum vanadate@bentonite (MoV@bentonite) composite. MoV@bentonite has been fabricated using the precipitation method and was characterized by different analytical tools including, FT-IR, XRD, and SEM attached with an EDX unit. The sorption studies applied on Cs(I) ions include the effect of contact time, pH, initial metal concentrations, ionic strength, desorption, and recycling.

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Using a batch equilibrium technique, the sorption of Cs and Gd onto synthesized zirconium silico antimonate (ZrSiSb) sorbent was examined. The new sorbent was prepared by precipitation technique and characterized by diverse analytical tools. The influence of shaking time, pH, metal ion concentrations, temperature, and a real sample was carried out.

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The existence of toxic heavy metals in the aquatic environment has emphasized a considerable exigency to develop several multifunctional biosorbents for their removal. Herein, three individual bacterial species of Cellulosimicrobium cellulans, Bacillus coagulans, and Microbacterium testaceum were successfully isolated from low-level liquid radioactive wastes. Their loading capacities towards cerium and cobalt metal ions were inclusivity inspected under variable operational parameters of pH, primary pollutant concentration, interaction time, temperature, stirring speed, and biosorbent dosage.

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The present work aims to radiologically characterize five samples (monazite, zircon, scale waste originating from petroleum production, black sands and phosphate rocks) from different industrial applications and environments in the Egyptian territory. The first section of the present work discusses the measurement and analysis of Ra, Th and K concentrations. Moreover, the assessment of the hazard indices is given in terms of radium equivalent (Ra), external hazard index (H), internal hazard index (H), gamma-activity index (I) and alpha-activity index (I).

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The biocomposites of polypyrrole (PPY), polyaniline (PANI) and sodium alginate (NaAlg) with cellulosic biomass barley husk (BH) were prepared and employed for the removal of 2,4-dichlorophenol (2,4-DCP) form aqueous media. The sorption of 2,4-DCP was studied using native and biocomposites (PPY/BH, PANI/BH and NaAlg/BH) as function of various process variables. The maximum sorption (q, 7.

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Rapid industrialization is polluting the water resources and is becoming a serious environmental issue. In present study, the adsorption-desorption behavior of Direct Orange-26 (DO-26), Direct Red-31 (DR-31), Direct Blue-67 (DB-67) and Ever direct Orange-3GL (EDO-3) dyes on to native, modified rice husk (MRH), polyvinyl alcohol (PVA), carboxymethyl cellulose (CMC) and alginate (ALG) immobilized biomasses were investigated under different experimental conditions. For adsorbent modification, physical and chemical treatments were performed.

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Novel magnetic alginate beads (MagAlgbeads) have been developed by incorporation of magnesium ferrite (MgFeO) in alginate beads with the aim of using them in the removal of strontium from aqueous solution. MagAlgbeads were characterized by transmission electron microscopy, scanning electron microscopy, X-ray fluorescence and Fourier transform infrared spectroscopy. The adsorption of strontium onto MagAlgbeads were found to depend on pH and strontium removal increases with increasing pH until pH is 6.

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Natural radioactivity levels in soils, rocks and water at a mining concession of Perseus gold mine and surrounding towns in Central Region of Ghana.

Springerplus

February 2016

Environmental Protection and Waste Management Centre, Radiation Protection Institute, Ghana Atomic Energy Commission, Legon, P. O. Box LG 80, Accra, Ghana.

Levels of naturally occurring radioactive materials prior to processing of gold ore within and around the new eastern concession area of Perseus Mining (Ghana) Limited were carried out to ascertain the baseline radioactivity levels. The study was based on situ measurements of external gamma dose rate at 1 m above ground level as well as laboratory analysis by direct gamma spectrometry to quantify the radionuclides of interest namely; (238)U, (232)Th and (40)K in soil, rock, ore samples and gross alpha/beta analysis in water samples. The average absorbed dose rate in air at 1 m above sampling point using a radiation survey metre was determined to be 0.

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Assessment of natural and anthropogenic radioactivity levels in soils, rocks and water in the vicinity of Chirano Gold Mine in Ghana.

Radiat Prot Dosimetry

January 2014

Environmental Protection and Waste Management Centre, Radiation Protection Institute, Ghana Atomic Energy Commission, PO Box LG 80, Legon, Accra, Ghana.

Studies have been carried out within and around the operational area of the Chirano Gold Mine Ltd of Ghana to ascertain the baseline radioactivity levels of naturally occurring radioactive materials as well as artificial radionuclides in the surface and underground mines. The analysis was carried out by using gamma spectrometry to quantify the radionuclides of interest, namely (238)U, (232)Th, (137)Cs and (40)K in soil, ore, waste rock and water samples. The average activity concentrations of (238)U, (232)Th, (40)K and (137)Cs in the soil/rock samples were 9.

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Bagasse pith (BP) has been utilized for activated carbon preparation using H(3)PO(4) (BPH) or KOH (BPK) as a chemical activating agent followed by carbonization at 500 degrees C. The physicochemical properties of activated carbon were carried out. The effectiveness of carbon prepared in adsorption of Rhodamine B (RhB) has been studied as a function of adsorbent type, pH, particle size, agitation time, temperature, initial dye concentration, and desorption.

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