Polydopamine functionalized TiO with N doping, oxygen vacancies, and carbon layers for enhanced photoelectrocatalytic performance.

The development of a photoelectrode featuring both excellent reusability and a simple preparation process remains exceptionally challenging for TiO-based photoelectrocatalytic technology. Herein, a three-dimensional photoelectrode with N doping, oxygen vacancies (O), and carbon layers (NTC) was prepared via the "carbothermal reduction-pressing-calcination" method. The photoelectrode degraded 97.

Unraveling the impact of drought on waterbird community assembly and conservation strategies.

Drought-induced changes in lakes and wetlands, crucial habitats for migratory waterbirds, can greatly affect their foraging and habitat utilization. These changes lead to a decline in waterbird species richness and may cause shifts in community assembly from phylogenetic and functional trait perspectives. However, a gap remains between ecological mechanistic research about these changes and conservation applications.

Aspartame affects methane yield and enhances transmission of antibiotic resistance genes during anaerobic digestion of sludge.

Aspartame (ASP) is a widely used artificial sweetener, yet recent studies have shown that ASP have potential toxic effect. ASP is also detected in sludge, however, the influence of ASP on the performance of sludge anaerobic digestion and the fate of antibiotic resistance genes (ARGs) have not been thoroughly investigated. Under stress of 0, 0.

Urea promotes alkaline anaerobic fermentation of waste activated sludge for hydrogen production.

Hydrogen production from waste activated sludge (WAS) represents a promising pathway for sustainable energy generation. This study explores the impact of urea on enhancing hydrogen production during alkaline fermentation of WAS, with the aim of reducing alkali use. Experimental results revealed that treating WAS with 90 mg/g VSS urea at a constant pH of 9.

Tungsten phosphide nanoparticles anchored on ultrathin carbon nanosheets for efficient oxidative desulfurization: Pivotal roles and generation pathways of singlet oxygen.

Singlet oxygen (O) is an excellent reactive oxygen species for the selective oxidation of organic compounds. Therefore, its application in oxidative desulfurization (ODS) of fuels is theoretically promising, while this has rarely been systematically investigated. Herein, a novel ultrathin carbon nanosheet (CN)-supported tungsten phosphide (WP) catalyst (WP/CN) was devised and employed to activate hydrogen peroxide (HO) for the efficient O generation in ODS.

Co-grown novel S-scheme tubular P-UCN/S-TCN homojunction mediates photocatalysis-PMS activation synergistic system for efficient degradation of antibiotic.

The low photogenerated carrier separation and transport ability of the photocatalyst are the main factors inhibiting the photocatalytic activity. The construction of composite photocatalysts can effectively improve the efficiency of photogenerated carriers. However, the problem of reduced photocatalyst stability and catalytic activity due to easy separation of unstable composite interfaces has not been well solved for a long time.

Differential photoaging behaviors of different colored commercial polyethylene microplastics in water: The important role of color characteristics.

Upon entering the environment, plastics would undergo photoaging and forming microplastics (MPs). However, information on the photoaging behavior of colored MPs and how the color characteristics (wavelength, lightness, and saturation) influence their photoaging process is still lacking. Thus, attention was paid to comparing the photoaging process of transparent and five-colored MPs.

Recent advancements in antibiotics removal by bio-electrochemical systems (BESs): From mechanisms to application of emerging combined systems.

Recent advancements in bio-electrochemical systems (BESs) for antibiotic removal are receiving great attentions due to the electro-active bacteria on the electrode that could elevate the removal efficiency. Enhanced detoxification performance of BESs compared to the traditional biological processes indicates the great potential serving as a sustainable alternative or a pre-/post-processing unit to improve the performance of biological processes. However, the successfully application of BESs to antibiotic-polluted water remediation requires a deeper discussion on their operational performance and emerging coupled systems.

Co-toxicity and co-contamination remediation of polycyclic aromatic hydrocarbons and heavy metals: Research progress and future perspectives.

The combined pollution of polycyclic aromatic hydrocarbons (PAHs) and heavy metals (HMs) has attracted wide attention due to their high toxicity, mutagenicity, carcinogenicity and teratogenicity. A thorough understanding of the progress of the relevant studies about their co-toxicity and co-contamination remediation is of great importance to prevent environmental risk and develop new efficient remediation methods. This paper summarized the factors resulting in different co-toxic effects, the interaction mechanism influencing co-toxicity and the development of remediation technologies for the co-contamination.

The role of microorganisms in phosphorus cycling at river-lake confluences: Insights from a study on microbial community dynamics.

River-lake confluences are key zones in the river-lake network, essential for managing contaminant transport and transformation. However, the role of biogeochemical transformations, particularly in phosphorus (P) dynamics, has been underexplored. As a result, this study looks into the dynamics of microbial communities and how important microbes are to the cycling of P.

Humic-like components in dissolved organic matter inhibit cadmium sequestration by sediment.

China's lakes are plagued by cadmium (Cd) pollution. Dissolved organic matter (DOM) significantly regulates Cd(II) transport properties at the sediment-water interface. Understanding the effects of different DOM components on the transportation properties of Cd(II) at the sediment-water interface is essential.

Improved humification and Cr(VI) immobilization by CaO and FeO during composting.

The current research studied how FeO nanomaterials (NMs) and CaO affect humification and Cr(VI) immobilization and reduction during the composting of oil-tea Camellia meal and Cr-contaminated soil. The results showed that FeO NMs and CaO successfully construct a Fenton-like reaction in this system. The excitation-emission matrix-parallel factor (EEM-PARAFAC) demonstrated that this Fenton-like treatment increased the generation of humic acids and accelerated the humification.

Photoaged tire wear particles hinder the transport of Pb(II) in urban soils under acid rain: Experimental and numerical investigations.

Rapid urbanization brought lots of serious environmental contamination, including the accumulation of heavy metals, acid rain, and the emission of tire wear particles (TWPs), with detrimental effects for terrestrial ecosystems. Nevertheless, how naturally aged TWPs affect the mobilization of heavy metals in soils under acid rain is still unclear. Here, we investigate the adsorption and transport mechanisms of Pb(II) co-existing with acid rainwater in soil-TWP mixtures via batch experiments, column experiments and modeling.

Titanium nanoparticles released from orthopedic implants induce muscle fibrosis via activation of SNAI2.

Titanium alloys represent the prevailing material employed in orthopedic implants, which are present in millions of patients worldwide. The prolonged presence of these implants in the human body has raised concerns about possible health effects. This study presents a comprehensive analysis of titanium implants and surrounding tissue samples obtained from patients who underwent revision surgery for therapeutic reasons.

Interaction of Pb(II) with microplastic-sediment complexes: Critical effect of surfactant.

In this study, the impact of surfactants on the adsorption behavior of Pb(II) onto microplastics-sediment (MPs-S) complexes was investigated. Firstly, virgin polyamide (VPA) and polyethylene (VPE) were placed in Xiangjiang River sediment for six months to conduct in-situ aging. The results indicated that the biofilm-developed polyamide (BPA) and polyethylene (BPE) formed new oxygen-containing functional groups and different biofilm species.

Research progress on the environmental risk assessment and remediation technologies of heavy metal pollution in agricultural soil.

Controlling heavy metal pollution in agricultural soil has been a significant challenge. These heavy metals seriously threaten the surrounding ecological environment and human health. The effective assessment and remediation of heavy metals in agricultural soils are crucial.

Electron Delocalization Disentangles Activity-Selectivity Trade-Off of Transition Metal Phosphide Catalysts in Oxidative Desulfurization.

Breaking the activity-selectivity trade-off has been a long-standing challenge in catalysis. Here, we proposed a nanoheterostructure engineering strategy to overcome the trade-off in metal phosphide catalysts for the oxidative desulfurization (ODS) of fuels. Experimental and theoretical results demonstrated that electron delocalization was the key driver to simultaneously achieve high activity and high selectivity for the molybdenum phosphide (MoP)/tungsten phosphide (WP) nanoheterostructure catalyst.

Landscape fragmentation and regularity lead to decreased carbon stocks in basins: Evidence from century-scale research.

Landscapes evolution have significantly altered the Earth's energy balance and biogeochemical cycles, thereby exacerbating climate change. This, in turn, affects surface characteristics and the provision of ecosystem services, especially carbon storage. While recent centuries have witnessed unprecedented landscape changes, limited long-term studies have offered insights into the comparison between present-day features and historical conditions.