Radical-Triggered Bicyclization and Aryl Migration of 1,7-Diynes with Diphenyl Diselenide for the Synthesis of Selenopheno[3,4-]quinolines.

The translocation of an aryl group from selenium into carbon enabled by the cleavage of the C-Se bond is reported by using nitrogen atom-linked 1,7-diynes and diaryl diselenides as starting materials, leading to various selenophene derivatives in a regioselective manner. This method enables the construction of two C-Se bonds and two C-C bonds through sequential radical bicyclization and 1,2-aryl migration under metal-free conditions. Control experiments and mechanistic studies suggest that this reaction proceeds through the cleavage of the inert C(Ph)-Se bond, facilitating the aryl translocation process.

Interfacial Engineering with a Conjugated Conductive Polymer for a Highly Reversible Zn Anode.

For Zn metal batteries, the Zn anode faces several challenges, including Zn dendrites, hydrogen evolution, and corrosion. These issues are closely related to the Zn deposition process at the electrode/electrolyte interface. Herein, we propose interfacial engineering to protect the Zn anode and induce homogeneous deposition using conjugated cyclized polyacrylonitrile (cPAN) polymer nanofibers.

Modulating Built-In Electric Field Via N-Doped Carbon Dots for Robust Oxygen Evolution at Large Current Density.

Constructing a built-in electric field (BIEF) within heterostructures has emerged as a compelling strategy for advancing electrocatalytic oxygen evolution reaction (OER) performance. Herein, the p-n type nanosheet array heterojunction NiP-NCDs-Co(OH)-NF are successfully prepared. The variation in interaction affinity between nitrogen within N-doped carbon dots (NCDs) and Ni/Co induces charge redistribution between Co and Ni in the NiP-NCDs-Co(OH)-NF-3 heterostructure, thereby enhancing the intensity of the BIEF, facilitating electron transfer, and markedly improving OER activity.

Polyhydroxy starch with abundant hydroxyls and a unique structure enables uniform Zn deposition.

Zinc metal is a promising anode material for zinc-ion batteries (ZIBs), but severe side reactions and dendrite formation hinder its commercialization. In this study, starch is introduced into the ZnSO electrolyte for stabilizing the Zn anode. With abundant hydroxyl groups, starch can reconstruct the H-bond system in the electrolyte, suppressing side reactions.

Unlocking new possibilities in ionic thermoelectric materials: a machine learning perspective.

The high thermopower of ionic thermoelectric (-TE) materials holds promise for miniaturized waste-heat recovery devices and thermal sensors. However, progress is hampered by laborious trial-and-error experimentations, which lack theoretical underpinning. Herein, by introducing the simplified molecular-input line-entry system, we have addressed the challenge posed by the inconsistency of -TE material types, and present a machine learning model that evaluates the Seebeck coefficient with an of 0.

Termination-acidity tailoring of molybdenum carbides for alkaline hydrogen evolution reaction.

Transition-metal carbides have been advocated as the promising alternatives to noble-metal platinum-based catalysts in electrocatalytic hydrogen evolution reaction over half a century. However, the effectiveness of transition-metal carbides catalyzing hydrogen evolution in high-pH electrolyte is severely compromised due to the lowered proton activity and intractable alkaline-leaching issue of transition-metal centers. Herein, on the basis of validation of molybdenum-carbide model-catalyst system by taking advantage of surface science techniques, MoC micro-size spheres terminated by Al doped MoO layer exhibit a notable performance of alkaline hydrogen evolution with a near-zero onset-potential, a low overpotential (40 mV) at a typical current density of 10 mA/cm, and a small Tafel slope (45 mV/dec), as well as a long-term stability for continuous hydrogen production over 200 h.

Bioinspired Liquid Pockets with Externally Induced Internal Microscale Flow.

The gastric mucosal barrier, through its gastric pits, serves as a pathway for secretions, ensuring that mucus produced by the gastric glands is transferred to the gastric lumen, providing stable protection. Here a bioinspired liquid pockets material is shown, composed of a thermo-driven hydrogel that acts as an external activation unit to release interflowing liquid responsively, and porous matrices that serve as interconnected pockets to transfer it, enabling controlled internal flow and adaptive barrier functionality. Experiments and theoretical analysis demonstrate the stability and regulatory mechanisms of these liquid pockets, based on the interconnected pockets between the external activation unit and internal fluid flow.

Mechanical properties and microscopic damage characteristics of coal series limestone under coupling effects of high temperature and impact.

To ensure the safe extraction of deep mineral resources, it is imperative to address the mechanical properties and damage mechanism of coal and rock media under the real-time coupling effect of high temperature and impact. In this study, the impact tests (impact velocities of 6.0-10.

Preliminary characterization of Ramaria botrytoides polysaccharide RB-P1-1 and analysis of its hypoglycemic effects by altering the gut microbiota and metabolites in mice with type 2 diabetes mellitus.

Gut microbiota has a symbiotic relationship with the host and is closely linked to the development of type 2 diabetes mellitus (T2DM). Polysaccharides are natural bioactive compounds with beneficial effects on T2DM; however, the mechanisms underlying their effects remain unclear. This study investigated the hypoglycemic effects of a purified polysaccharide, RB-P1-1, from Ramaria botrytoides and assessed its association with gut microbiota and metabolite changes using 16S rDNA sequencing and liquid chromatography-mass spectrometry, respectively.

One-Pot Production of Cinnamonitriles from Lignin β-O-4 Segments Induced by Selective Oxidation of the γ-OH Group.

The construction of N-containing aromatic compounds from lignin is of great importance to expanding the boundary of the biorefinery and meeting the demand for value-added biorefinery. However, it remains a huge challenge due to the complex lignin structure and the incompatible catalysis for C-O/C-C bond cleavage and C-N formation. Herein, sustainable synthesis of cinnamonitrile derivatives from lignin β-O-4 model compounds in the presence of 2,2,6,6-tetramethylpiperidine oxide (TEMPO), (diacetoxyiodo)benzene (BAIB), and a strong base has been achieved in a one-pot, two-step fashion under transition-metal-free conditions.

Merging the theory of planned behaviour and value-belief-norm theory to predict green hotel visit intention among Chinese university students: The case from Xuzhou, China.

Few research studies attempt to merge the theory of planned behaviour and value-belief-norm theory in explaining consumers green hotels visits although they may deem to be complementary. This study attempts to merge both theories by investigating the relationships between the different aspects of values, attitudes, norms, perceived behavioural control, awareness of consequence, ascription of responsibility and intention. A total of 596 young responses were collected, and the results showed that altruistic value positively influenced subjective norm, extrinsic attitude and perceived behavioural control.

Friction and Corrosion Properties of Phytic Acid Ionic Liquid-water Mixtures.

The study involved the preparation of mixtures of phytic acid ionic liquid and water, which were analyzed for their rheological, frictional, and electrochemical properties. The viscosity and friction characteristics of the mixtures are significantly affected by the water content. Mixtures with low water content (below 30%) result in low friction and negligible wear because of the generation of a close adsorption film and high viscosity.

Effect of Addition Amount of Ethylenediamine on Interlayer Nanochannels and the Separation Performance of Graphene Oxide Membranes.

In recent years, graphene oxide (GO)-based two-dimensional (2D) laminar membranes have attracted considerable attention because of their unique well-defined nanochannels and deliver a wide range of molecular separation properties and fundamentals. However, the practical application of 2D GO layered membranes suffers from instability in aqueous solutions as the interlayer -spacing of GO membranes is prone to expansion caused by the hydration effect. In this study, the effects of the ethylenediamine (EDA) addition amount on the structure, crosslinking mechanism and separation performance of GO membranes were investigated systematically, and membrane performance was evaluated using water permeability and dye/salt rejection tests.

Alkali Ion-Accelerated Gelation of MXene-Based Conductive Hydrogel for Flexible Sensing and Machine Learning-Assisted Recognition.

Conductive hydrogels are promising active materials for wearable flexible electronics, yet it is still challenging to fabricate conductive hydrogels with good environmental stability and electrical properties. In this work, a conductive MXene/LiCl/poly(sulfobetaine methacrylate) hydrogel system was successfully prepared with an impressive conductivity of 12.2 S/m.

Remediation of antimony and arsenic in co-contaminated soil by electrolytic manganese residue-biochar composite: Effects, mechanisms, and microbial response.

Antimony (Sb) mining and smelting activities caused Sb and arsenic (As) pollution in the soil, posing a threat to the ecosystem and human health. To remediate Sb and As in co-contaminated soil and realize the resource utilization of typical industrial solid waste, electrolytic manganese residue (EMR)-biochar composite (EB) was prepared from EMR and distillers grains by a facile one-step pyrolysis method. The immobilization effect of EB on Sb and As in soil was studied using a column leaching experiment.

A carrageenan-induced highly stable Zn anode by regulating interface chemistry.

Zinc-ion batteries (ZIBs) are promising on account of the inherent safety, minimal toxicity, cost-effectiveness, and high theoretical capacity. However, the critical issues including the Zn dendrites and side reactions impede their commercial application. Here, we propose green, non-toxic and biological carrageenan (Carr) serving as an electrolyte additive to address the aforementioned issues.

Impact of magnetic field-assisted freezing on the physicochemical properties and starch structure of cooked rice: Effects of magnetic types, intensities, and cryostasis time.

A magnetic field-assisted freezing system was developed to mitigate the degradation of taste quality in frozen cooked rice (FCR). The physicochemical properties and starch structure were analyzed under varying magnetic field types, intensities, and cryostasis time. The analysis of freezing characteristics indicated that treatments with 10 mT static magnetic fields (SMF) and 6 mT alternating magnetic fields (AMF) yielded optimal results, significantly reducing the duration of the maximum ice crystal generation zone by approximately 18 min.

Grey preferences selection index with trimmed group preference for evaluating university dormitory renovation design.

Renovating old buildings is a strategic approach to resource optimization and sustainability. However, dormitory design decisions are often made by a limited panel of experts, which risks excluding student preferences-key to the design process. Expert assumptions about student needs can lead to biased outcomes, and attempts to gather student input may suffer from respondent bias and inconsistent engagement, introducing data noise.

Calcium alginate-biochar composite immobilized A. ferrooxidans effectively removes sulfate and ferric iron from acid mine drainage.

Bioremediation has been applied in the treatment of acid mine drainage (AMD), but high levels of sulfate (SO) and ferric iron (Fe) in AMD often affect microbial activity. A novel biochar-microorganism composite (I-CMR600) was developed by alginate gel-embedding method to improve the tolerance of microorganisms and the removal effects of SO and Fe in AMD, and its removal mechanism and biological behavior were explored in this study. The removal performance of I-CMR600 under different influencing factors was studied by batch adsorption experiments.

The (in)congruence effects of organizational green compensation and employee green conscientiousness on pro-environmental behavior: evidence from China.

Background: In past decades, the Chinese government has enacted a series of ecological policies to encourage organizations, the pivotal institutional agents implementing national policies, and employees, the crucial micro-actors engaging in ecological construction, to bring about employee pro-environmental behavior (EPEB) which is the foundation to realize nation's ecological strategies. Yet, the effectiveness of a widely adopted organizational-level green management practice "organizational green compensation" (OGC) and a typical individual-level green personality trait "employee green conscientiousness" (EGC) have been explored alone, ignoring the prevalence of various OGC-EGC combinations and failing to clarify the potential influences of OGC-EGC (in)congruence on EPEB. Our research endeavors to address this limitation by resolving the following two problems: What are the (in)congruence effects of OGC and EGC on EPEB in the Chinese context? And what is the underlying mechanism?

Methods: Study 1 surveyed EGC, OGC, and EPEB among 778 subordinate-supervisor dyads and sought to test two single effects and three sets of comparisons between and within the congruence and incongruence effects using the methodology of polynomial regression and response surface analysis.

Unlocking the Trade-off Between Intrinsic and Interfacial Thermal Transport of Boron Nitride Nanosheets by Surface Functionalization for Advanced Thermal Interface Materials.

The increasing computing power of AI presents a major challenge for high-power chip solution and heat dissipation. Boron nitride nanosheet-based thermal interface materials (BNNS-based TIMs) exhibit excellent electrical insulation property, ensuring the secure and stable operation of chips. However, the efficiency of micro/nano interfacial thermal transport is limited, impeding further enhancements in the thermal conductivity (TC) of BNNS-based TIMs.

A heterotypic tumor-on-a-chip platform for user-friendly combinatorial chemotherapeutic testing.

Background: Three-dimensional (3D) tumor microdevices are promising platform for biomimetic antitumor prediction and high-throughput chemotherapeutic screening and play crucial roles in the exploration of cancer-associated pharmaceutics and therapeutics. Traditional cell manipulation tools (e.g.

Enhancing Adsorption Performance of Ce(III) by Amine-Thiourea and Aniline-Modified Magnetic Chitosan Nanocomposites.

To enhance the adsorption performance of chitosan for rare earth ions, two novel magnetic chitosan-based adsorbents were prepared by using chitosan-coated magnetic silica nanoparticles modified with amine-thiourea and aniline. The structure of copolymers was analyzed using characterization methods such as X-ray diffraction, Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, and thermogravimetric analysis, confirming the successful synthesis of modified magnetic chitosan nanocomposites. The investigation explored the influence of pH, contact time, dosage, initial concentration, and temperature on the adsorption performance.