Prediction of the capture and utilization of atmospheric acidic gases by azo-based square-pillared fluorinated MOFs.

More than the permissible limit of acidic gases like CO, SO, and NO in the atmosphere are responsible for the formation of acid rain, the greenhouse effect and many other undesirable environmental hazards. So, the capture and utilization of these gases are essential for mankind. Herein, we proposed an azo-based square pillared MOF, [Ni(MF)(1,2-bis(4-pyridy)diazene)], with the CUS metal site, M = Al/Fe, for the selective capture and conversion of acidic gas molecules into commodity chemicals such as cyclic carbonate, sulphite and nitrite.

An open carbon-phenolic ablator for scientific exploration.

Space exploration missions rely on ablative heat shields for the thermal protection of spacecraft during atmospheric entry flights. While dedicated research is needed for future missions, the scientific community has limited access to ablative materials typically used in aerospace. In this paper, we report the development of the HEFDiG Ablation-Research Laboratory Experiment Material (HARLEM), a carbon-phenolic ablator designed to supply the need for ablative materials in laboratory experiments.

Role of solution reconstruction in hypersonic viscous computations using a sharp interface immersed boundary method.

This work discusses the development of a sharp interface immersed boundary (IB) method for viscous compressible flows and its assessment for accurate computations of wall shear and heat fluxes in hypersonic flows. The IB method is implemented in an unstructured Cartesian finite-volume (FV) framework and resolves the geometric interface sharply on the nonconformal mesh through direct imposition of boundary conditions employing a local reconstruction approach. The efficacy of the IB-FV solver is investigated for canonical high-speed viscous flows over a range of Mach numbers.

Sanal Flow Choking: A Paradigm Shift in Computational Fluid Dynamics Code Verification and Diagnosing Detonation and Hemorrhage in Real-World Fluid-Flow Systems.

The discovery of Sanal flow choking is a scientific breakthrough and a paradigm shift in the diagnostics of the detonation/hemorrhage in real-world fluid flow systems. The closed-form analytical models capable of predicting the boundary-layer blockage factor for both 2D and 3D cases at the Sanal flow choking for adiabatic and diabatic fluid flow conditions are critically reviewed here. The beauty and novelty of these models stem from the veracity that at the Sanal flow choking condition for diabatic flows all the conservation laws of nature are satisfied at a unique location, which allows for computational fluid dynamics (CFD) code verification.

Stability of the Liquid Water Phase on Mars: A Thermodynamic Analysis Considering Martian Atmospheric Conditions and Perchlorate Brine Solutions.

The stability of the liquid water phase on Mars has been examined on the basis of fundamental thermodynamic principles. The analysis considers the atmospheric pressure and temperature conditions prevalent on Mars. Because of the very low atmospheric pressure on Mars, water cannot exist in the liquid form.

Thermal structure of the Venusian atmosphere from the sub-cloud region to the mesosphere as observed by radio occultation.

We present distributions of the zonal-mean temperature and static stability in the Venusian atmosphere obtained from Venus Express and Akatsuki radio occultation profiles penetrating down to an altitude of 40 km. At latitudes equatorward of 75°, static stability derived from the observed temperature profiles is consistent with previous in-situ measurements in that there is a low-stability layer at altitudes of 50-58 km and highly and moderately stratified layers above 58 km and below 50 km, respectively. Meanwhile, at latitudes poleward of 75°, a low-stability layer extends down to 42 km, which has been unreported in analyses of previous measurements.

Contouring of diffused objects using lensless Fourier transform digital moiré holography.

A method is proposed for contouring of diffused objects using digital holographic moiré interferometry in lensless Fourier transform configuration. Fringe projection moiré technique combined with digital double-exposure holography produces the contours in this method. Two digital holograms of a 10 mm aluminum alloy cube are recorded by tilting the illumination angle slightly between exposures, and a third one is recorded by translating the detector a little laterally with the final illumination angle unchanged.