The defect-free surface of MoS is crucial for electronic device applications, with oxidative etching being linked to sulfur vacancy formation, though there's limited experimental evidence on the role of adsorbed oxygen.
By using thermal desorption spectroscopy, the study shows that sulfur loss is connected to adsorbed oxygen, leading to sulfur vacancy defects as sulfur atoms dissociate from MoS due to oxygen at temperatures between 200 °C and 600 °C.
Pre-annealing can effectively remove adsorbed oxygen prior to MoS exfoliation, providing a method to prevent these defects.