Rationally designed micropores within a metal-organic framework for selective sorption of gas molecules.

A microporous metal-organic framework, MOF, Cu(FMA)(4,4'-Bpe)0.5 (3a, FMA = fumarate; 4,4'-Bpe = 4,4'-Bpe = trans-bis(4-pyridyl)ethylene) was rationally designed from a primitive cubic net whose pores are tuned by double framework interpenetration. With pore cavities of about 3.

Differential diagnosis of Hispanic children referred for autism spectrum disorders: complex issues.

This study examines the decision-making process used for differential diagnosis of a sample of Hispanic children referred for autism spectrum disorders (ASDs). Of the sample of 28 children, 18 were diagnosed with ASDs. Of the 10 children who were not diagnosed with ASDs, 80% were found to have multiple diagnostic labels or comorbidities.

Predicting physical activity among low-income Mexican American women: application of the theory of planned behavior.

Objectives: To utilize the theory of planned behavior (TPB) in explaining the prediction of physical activity intention and determine if present activity behavior attenuates theory construct relationships in a sample of low-income Mexican women.

Methods: Data were gathered on 201 subjects through a self-report survey instrument and analyzed through structural equation modeling.

Results: Present activity behavior attenuated theory construct influence on intention, and perceived behavioral control was the strongest predictor of intent to engage in physical activity.

Effect of caffeine and alcohol on the toxicity and metabolism of methacrylonitrile in male Sprague-Dawley rats.

This study reports the toxicity and metabolism of methacrylonitrile (MeAN) in normal male Sprague-Dawley rats and those pre-treated with caffeine, alcohol or both. Rats were divided into groups often. One group received an oral dose by gavage of 6 % MeAN solution in corn oil (equivalent to 0.

Loss of escape-related giant neurons in a spiny lobster, Panulirus argus.

When attacked, many decapod crustaceans perform tailflips, which are triggered by a neural circuit that includes lateral giant interneurons, medial giant interneurons, and fast flexor motor giant neurons (MoGs). Slipper lobsters (Scyllaridae) lack these giant neurons, and it has been hypothesized that behavioral (e.g.

Mexican American women's pathways to health.

Self-care represents the bulk of all healthcare and is the first therapeutic mode employed by most people in the lay health arena regardless of cultural affiliation. The purpose of this article is to present a schema describing Mexican American (MA) women's pathways to health, including self-care, via the lay/popular, folk, and professional healthcare arenas. The schema is based on a naturalistic study of MA women in the Texas Rio Grande Valley using Kleinman's cultural model of healthcare systems.

Five-beam interference pattern controlled through phases and wave vectors for diamondlike photonic crystals.

We demonstrate, for what is believed to be the first time, the design of diamondlike photonic crystals made by holographic lithography based on five-beam interference. All five beams are launched from the same half-space, and the exposure can easily be realized by a single diffractive optical element. The photonic structure can be constructed through the translation of the interference pattern controlled by the phase shift of laser beams.

Enhanced near-infrared-luminescence in an erbium tetrafluoroterephthalate framework.

Two erbium-organic frameworks Er2(BDC)3(DMF)2(H2O)2.H2O (1) and Er2(BDC-F4)3(DMF)(H2O).DMF (2) (BDC = 1,4-benzenedicarboxylate; BDC-F(4) = 2,3,5,6-tetrafluoro-1,4-benzenedicarboxylate or tetrafluoroterephthalate; DMF = dimethylformamide) have been synthesized and structurally characterized.

Ab initio self-consistent x-ray absorption fine structure analysis for metalloproteins.

X-ray absorption fine structure is a powerful tool for probing the structures of metals in proteins in both crystalline and noncrystalline environments. Until recently, a fundamental problem in biological XAFS has been that ad hoc assumptions must be made concerning the vibrational properties of the amino acid residues that are coordinated to the metal to fit the data. Here, an automatic procedure for accurate structural determination of active sites of metalloproteins is presented.

Occurrence of Leveillula taurica Cleistothecia on Honey Mesquite in Southern Texas.

Prosopis glandulosa J. Torrey (honey mesquite) is a widespread tree that serves as an important food and cover resource for wildlife in the south plains, gulf marshes, and scrub prairies of Texas. In the fall of 2005, lower leaflets of P.

Expect the unexpected: ability, attitude, and responsiveness to hypnosis.

Participants' expectancies and hypnotic performance throughout the course of a standardized, individually administered hypnotic protocol were analyzed with a structural equation model that integrated underlying ability, expectancy, and hypnotic response. The model examined expectancies and ability as simultaneous predictors of hypnotic responses as well as hypnotic responses as an influence on subsequent expectancies. Results of the proposed model, which fit very well, supported each of the 4 major hypothesized effects: Expectancies showed significant stability across the course of the hypnosis protocol; expectancies influenced subsequent hypnotic responses, controlling for latent ability; hypnotic responses, in turn, affected subsequent expectancies; and a latent trait underlay hypnotic responses, controlling for expectancies.

A band dispersion mechanism for Pt alloy compositional tuning of linear bound CO stretching frequencies.

The C-O stretching frequency (nu(CO)) of atop CO/Pt in PtRu alloys is compositionally tuned in proportion to the Pt mole percent. The application of a Blyholder-Bagus type mechanism (i.e.

Hydrogen adsorption in an interpenetrated dynamic metal-organic framework.

A metal-organic framework Zn(NDC)(4,4'-Bpe)(0.5).xG [NDC = 2,6-naphthalenedicarboxylate; 4,4'-Bpe = 4,4'-trans-bis(4-pyridyl)ethylene; G = guest molecules] has been synthesized, structurally characterized, and rationalized to be a two-interpenetrated elongated primitive cubic net.

Gender and ethnic differences in sexual attitudes at a Hispanic-serving university.

The authors studied sexual attitudes in 328 university students from 10 undergraduate classes at a Hispanic-serving university near the Texas-Mexico border. Men (n = 128) and women (n = 199) rated their level of agreement with 38 items on a revised sexuality questionnaire. There were 283 self-identified Hispanic students and 44 self-identified non-Hispanic students in the sample.

Community-level uninsurance and the unmet medical needs of insured and uninsured adults.

Objective: To examine the relationship between community-level uninsurance rates and the self-reported unmet medical needs of insured and uninsured adults in the U.S.

Data Sources: 2000-2001 Community Tracking Study, which includes data from 60 randomly selected U.

Development of the fear survey for adults with mental retardation.

This paper describes the development of the fear survey for adults with mental retardation (FSAMR) and provides initial evidence of its psychometric properties. The FSAMR was designed to be sensitive to the assessment needs of individuals with mental retardation. The items were developed through open-ended interviews, a review of existing measures, expert input, and pilot testing.

[Ageing, health and economics. National inquest into health and ageing in Mexico].

Mexico is experiencing a demographic transition in which the percentage of the population older than 50 years of age is growing rapidly as a result of increases in life expectancy. This population has special needs that must be taken into account when formulating policy, especially in terms of access to health care services and social security. In this article we present a general description of the Mexican Health and Aging Survey (MHAS), a panel study that began in 2001 and that provides a unique opportunity to study complex demographic and economic issues through the exploration of personal characteristics, socioeconomic transfers and health indicators for a sample of 15 186 middle and older age adults.

Memory retrieval tasks determine the serial position curves of linear orders with categorical structures.

I examined 2 different views on organization of linear order information in memory: the linear schema view and the hierarchical structure view. The linear schema view holds that there is a strong tendency in memory to organize an array of transitively related elements into a unidimensional order. The hierarchical structure view maintains that the transitively related elements are organized in memory in a hierarchy of items.

A case study of mediated learning, delayed auditory feedback, and motor repatterning to reduce stuttering.

A case study of DW, an 11-yr. old monolingual, English-speaking boy who exhibits stuttering, language delay, and ADHD is presented. DW experienced only limited improvement during stuttering therapy received in public schools, according to parents and the public school clinician.

Electrorheological analysis of nano laden suspensions.

The synthesis and characterization of Pb3O2Cl2 nanowires and the electrorheological (ER) properties of carbon nanofiber (CNF), carbon nanotube (CNT) and Pb3O2Cl2 nanowire (NW) laden suspensions is presented. The ER properties were investigated through oscillatory shear experiments. The viscoelastic response in the presence of dc electric fields was analyzed.

The recognition of silicosis: labor unions and physicians in the Chilean copper industry, 1930s-1960s.

By the late 1930s, silicosis had become one of the most important occupational diseases in Chile. It was a medical and scientific problem, and a favorite topic in medical congresses; in Chile, a mining country, it also had serious political and economic implications. The recognition of silicosis did not happen in a vacuum, but was part of a national debate on the social role of the state and its responsibility toward working people's health and safety.

Euthanasia and physicians' moral duties.

Opponents of euthanasia sometimes argue that it is incompatible with the purpose of medicine, since physicians have an unconditional duty never to intentionally cause death. But it is not clear how such a duty could ever actually be unconditional, if due consideration is given to the moral weight of countervailing duties equally fundamental to medicine. Whether physicians' moral duties are understood as correlative with patients' moral rights or construed noncorrelatively, a doctor's obligation to abstain from intentional killing cannot be more than a defeasible duty.

Copper, selenium, and zinc concentrations in human milk during the first three weeks of lactation.

Human milk samples were analyzed by neutron activation analysis (NAA) for three essential trace elements (Cu, Se, and Zn). Mothers' milk samples were collected from 25 lactating mothers from the Central Hospital, Tripoli, Libya. The average concentration level of Cu, Se, and Zn declined from 0.