What is the nature of the uranium(iii)-arene bond?

Complexes of the form [U(η-arene)(BH)] where arene = CH; CHMe; CH-1,3,5-R (R = Et, iPr, Bu, Ph); CMe; and triphenylene (CH) were investigated towards an understanding of the nature of the uranium-arene interaction. Density functional theory (DFT) shows the interaction energy reflects the interplay between higher energy electron rich π-systems which drive electrostatic contributions, and lower energy electron poor π-systems which give rise to larger orbital contributions. The interaction is weak in all cases, which is consistent with the picture that emerges from a topological analysis of the electron density where metrics indicative of covalency show limited dependence on the nature of the ligand - the interaction is predominantly electrostatic in nature.