Phosphorus-substitution effect on the phase stabilization, electrical and spectroscopic properties of LAMOX-based electrolyte for solid oxide fuel cells.

A series of P - doped LaMoO phases with different concentrations of P were prepared using conventional solid-state reactions. The formation of phase-pure P-doped LaMoO has been monitored by powder X-ray diffraction, thermal analysis, conductivity measurements, Raman, and FT-IR absorption techniques. The structure and lattice parameters of LaMoPO are obtained from Rietveld refinement.

On the high-temperature phase transition of a new chlorocadmate(ii) complex incorporating symmetrical CdCl clusters: structural, optical and electrical properties.

In the present investigation, a new hybrid crystal, with the formula [(CH)P]CdCl has been synthesized by the slow evaporation method at room temperature. It was characterized by X-ray diffraction (XRD), Hirshfeld surface, differential scanning calorimetry (DSC), optical measurement and complex impedance. Single crystal X-ray diffraction structural analysis revealed that the title compound crystallizes in the triclinic system with space group 1̄ and cell parameters: = 11.