Effects of cobalt doping on the reactivity of hausmannite for As(III) oxidation and As(V) adsorption.

Hausmannite is a common low valence Mn oxide mineral, with a distorted spinel structure, in surficial sediments. Although natural Mn oxides often contain various impurities of transitional metals (TMs), few studies have addressed the effect and related mechanism of TM doping on the reactivity of hausmannite with metal pollutants. Here, the reactivity of cobalt (Co) doped hausmannite with aqueous As(III) and As(V) was studied.

Optimized Stoichiometry for CuCrO Thin Films as Hole Transparent Layer in PBDD4T-2F:PCBM Organic Solar Cells.

The performance and stability in atmospheric conditions of organic photovoltaic devices can be improved by the integration of stable and efficient photoactive materials as substituent of the chemically unstable poly (3,4-ethylene dioxythiophene):polystyrene sulfonate (PEDOT:PSS), generally used as organic hole transport layer. Promising candidates are p-type transparent conductive oxides, which combine good optoelectronic and a higher mechanical and chemical stability than the organic counterpart. In this work, we synthesize Cu-rich CuCrO thin films by aerosol-assisted chemical vapour deposition as an efficient alternative to PEDOT:PSS.

An evaluation of sequencing coverage and genotyping strategies to assess neutral and adaptive diversity.

Whole genome sequences (WGS) greatly increase our ability to precisely infer population genetic parameters, demographic processes, and selection signatures. However, WGS may still be not affordable for a representative number of individuals/populations. In this context, our goal was to assess the efficiency of several SNP genotyping strategies by testing their ability to accurately estimate parameters describing neutral diversity and to detect signatures of selection.

Muscle MCT4 Content Is Correlated with the Lactate Removal Ability during Recovery Following All-Out Supramaximal Exercise in Highly-Trained Rowers.

The purpose of this study was to test if the lactate exchange (γ1) and removal (γ2) abilities during recovery following short all-out supramaximal exercise correlate with the muscle content of MCT1 and MCT4, the two isoforms of the monocarboxylate transporters family involved in lactate and H(+) co-transport in skeletal muscle. Eighteen lightweight rowers completed a 3-min all-out exercise on rowing ergometer. Blood lactate samples were collected during the subsequent passive recovery to assess an individual blood lactate curve (IBLC).

Field monitoring of sprinting power-force-velocity profile before, during and after hamstring injury: two case reports.

Very little is currently known about the effects of acute hamstring injury on over-ground sprinting mechanics. The aim of this research was to describe changes in power-force-velocity properties of sprinting in two injury case studies related to hamstring strain management: Case 1: during a repeated sprint task (10 sprints of 40 m) when an injury occurred (5th sprint) in a professional rugby player; and Case 2: prior to (8 days) and after (33 days) an acute hamstring injury in a professional soccer player. A sports radar system was used to measure instantaneous velocity-time data, from which individual mechanical profiles were derived using a recently validated method based on a macroscopic biomechanical model.

Strategy use fully mediates the relationship between working memory capacity and performance on Raven's matrices.

Working memory capacity consistently correlates with fluid intelligence. It has been suggested that this relationship is partly attributable to strategy use: Participants with high working memory capacity would use more effective strategies, in turn leading to higher performance on fluid intelligence tasks. However, this idea has never been directly investigated.

Non-circular chainring improves aerobic cycling performance in non-cyclists.

Non-circular chainrings alter the crank velocity profile over a pedalling cycle. The aim of this study was to investigate the effect of this altered crank velocity profile on the aerobic performance compared to a circular chainring (CC). Ten male non-cyclists performed two incremental maximal tests at 80 rpm on a cycle ergometer: one with a circular (Shimano) and the other with a non-circular chainring Osymetric® (Somovedi), at least 50 h apart.

Breaststroke swimmers moderate internal work increases toward the highest stroke frequencies.

A model to predict the mechanical internal work of breaststroke swimming was designed. It allowed us to explore the frequency-internal work relationship in aquatic locomotion. Its accuracy was checked against internal work values calculated from kinematic sequences of eight participants swimming at three different self-chosen paces.

Acceleration capability in elite sprinters and ground impulse: Push more, brake less?

Overground sprint studies have shown the importance of net horizontal ground reaction force impulse (IMPH) for acceleration performance, but only investigated one or two steps over the acceleration phase, and not in elite sprinters. The main aim of this study was to distinguish between propulsive (IMPH+) and braking (IMPH-) components of the IMPH and seek whether, for an expected higher IMPH, faster elite sprinters produce greater IMPH+, smaller IMPH-, or both. Nine high-level sprinters (100-m best times range: 9.

Different Muscle-Recruitment Strategies Among Elite Breaststrokers.

Purpose: To investigate electromyographical (EMG) profiles characterizing the lower-limb flexion-extension in an aquatic environment in high-level breaststrokers.

Methods: The 2-dimensional breaststroke kick of 1 international- and 2 national-level female swimmers was analyzed during 2 maximal 25-m swims. The activities of biceps femoris, rectus femoris, gastrocnemius, and tibialis anterior were recorded.

Working memory in the processing of the Iowa Gambling Task: an individual differences approach.

The Iowa Gambling Task (IGT) is a sequential learning task in which participants develop a tendency towards advantageous options arising from the outcomes associated with their previous decisions. The role of working memory in this complex task has been largely debated in the literature. On one hand, low working memory resources lead to a decrease in the number of advantageous decisions and make a significant part of participants unable to report explicitly which options are the most profitable.

Effect of using poles on foot-ground kinetics during stance phase in trail running.

The aim of this study was to investigate the effect of using poles on foot-ground interaction during trail running with slopes of varying incline. Ten runners ran on a loop track representative of a trail running field situation with uphill (+9°), level and downhill (-6°) sections at fixed speed (3.2 m.

Optimal force-velocity profile in ballistic movements--altius: citius or fortius?

Purpose: The study's purpose was to determine the respective influences of the maximal power (Pmax) and the force-velocity (F-v) mechanical profile of the lower limb neuromuscular system on performance in ballistic movements.

Methods: A theoretical integrative approach was proposed to express ballistic performance as a mathematical function of Pmax and F-v profile. This equation was (i) validated from experimental data obtained on 14 subjects during lower limb ballistic inclined push-offs and (ii) simulated to quantify the respective influence of Pmax and F-v profile on performance.

Multi scale modal decomposition of primary form, waviness and roughness of surfaces.

This article introduces an innovative method for the multi-scale analysis of high value-added surfaces, which consists of applying a method based on a new parameterization. This kind of surface parameterization refers to natural modes of vibration, and is therefore named modal parameterization. It allows us to characterize the form, waviness and roughness defects of a surface.

One- or two-legged standing: what is the more suitable protocol to assess the postural effects of the rigid ankle orthosis?

To highlight the capacity of one- and two-legged standing protocols when assessing postural behavior induced by a rigid ankle orthosis, 14 healthy individuals stood upright barefoot and wore either an elastic stocking on the preferred leg or a rigid orthosis with or without additional taping in one- or two-legged (TL) conditions. Traditional center-of pressure (CP) measures were evaluated for the total two-feet resultant CP and under the feet (plantar CP). Focusing on the plantar CP displacements under the leg fitted with the various orthoses demonstrated particular postural behaviors for traditional parameters with main effects along the mediolateral axis.

International study of heavy drinking: attitudes and sociodemographic factors in university students.

The authors studied the prevalence of heavy drinking among students in 21 developed and developing countries using an anonymous survey of 7,846 male and 9,892 female students aged 17 to 30 years. There were wide variations in the prevalence of drinking among countries, and the highest rates of heavy drinking (defined as 5 or more drinks for men and 4 or more drinks for women on at least 1 occasion over the past 2 weeks) were reported in Belgium, Colombia, Ireland, and Poland (men), and Ireland and England (women). Heavy drinking was associated with living away from home, having a wealthier family background, and having well-educated parents.

Use of diffuse reflectance spectrometry in spot test reactions for quantitative determination of cations in water.

Diffuse reflectance spectroscopy can be successfully used for the quantitative determination of small amounts of pollutants like metals. The remission function was found to be linearly proportional to the concentration, when we applied the Kubelka-Munk equation. The color reactions of Cu(II), Co(II), and Ni(II) with dithiooxamide, were realised on filter paper.

Bacterial Stimulation in Mixed Cultures of Bacteria and Organic Carbon from River and Lake Waters.

Abstract Interactions between natural bacterial assemblages and dissolved organic carbon (DOC) were investigated in two complementary batch experiments. In the first, a positive relationship was found between the proportion of electron transport system (ETS) active bacteria and the diversity of DOC in microcosms enriched with an increasing number of organic substrates. In a second experiment, bacterial and nutrient dynamics were measured in microcosms with natural bacterial populations and organic matter from rivers and lakes of different trophic levels.

Rapid treatment of water contamined with atrazine and parathion with zero-valent iron.

The utility of fine-grained iron metal in the remediation of water contamined with Atrazine and Parathion was investigated. Batch procedures under water treatment conditions (ambient temperature and pH of approximately 7) indicated that these pesticides degrade rapidly in the presence of iron powder (40-60 mesh, 40 g/l). The decline in the concentration of pesticide was monitored by HPLC.