Flexible and rigid "chirally distorted" π-systems: binaphthyl conjugates as organic CPL-active chromophores.

The inclusion of high-performance dyes into chiral π-conjugated systems is an effective strategy for activating significant chiroptical properties. We report the preparation and characterization of configurationally stable, axially-chiral π-conjugated systems in which acridone or 2,5-diarylamino-terephthalate has been fused into the chiral scaffold of a 1,1'-binaphthyl moiety. The high-yielding synthesis afforded π-conjugated systems with characteristics essentially matching those of the parent dyes while introducing detectable CPL activity in solution.

Activation of Solid-State Emission and Photostability through Molecular Confinement: The Case of Triptycene-Fused Quinacridone Dyes.

We report the facile, metal-free convergent synthesis and the characterization of novel quinacridone dyes in which two triptycene units end-cap and sterically confine the quinacridone chromophore. A precise comparison of the confined dyes with their known homologues reveals that the reduction of π-π interactions in triptycene-fused quinacridone dyes compared to classical quinacridone results not only in an increase of solubility and processability but also in an enhancement of fluorescence quantum yield and photostability in the solid state.

Rationalization of hydrogen production by bulk g-CN: an in-depth correlation between physico-chemical parameters and solar light photocatalysis.

The aim of this work is the systematic study of the photocatalytic activity of bulk graphitic carbon nitride (g-CN) in relation with the physical-chemical, structural and optical properties of the semiconductor. Fourteen g-CN samples have been prepared by thermal condensation starting from three different precursor (melamine, dicyandiamide and urea) and exploring various temperatures (in the range 500-700 °C). The materials obtained have been deeply characterized by high resolution scanning electron microscopy, thermogravimetric analysis, X-ray diffraction, nitrogen adsorption measurements (BET method), X-ray photoelectron spectroscopy and diffuse reflectance spectroscopy.