5,563 results match your criteria: "Universita di Pisa[Affiliation]"

Long-Term Evolution of the Saturnian System.

Space Sci Rev

February 2024

IMCCE, Observatoire de Paris, PSL Research University, CNRS, Sorbonne Université, Université de Lille, 77 av. Denfert-Rochereau, 75014 Paris, France.

Article Synopsis
  • The text explores the long-term evolution of Saturn's moon system, focusing on how tidal forces within Saturn influence the moons' orbits and dynamics.
  • It examines specific orbital resonances between moons, such as Enceladus-Dione and Titan-Hyperion, and their implications for the moons' evolutionary history.
  • The paper also discusses Saturn's spin-axis dynamics and their relationship to tidal evolution and potential historical events within the Saturnian system, while highlighting future directions for research.
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Artificial light at night alters the locomotor behavior of the Mediterranean sea urchin Paracentrotus lividus.

Mar Pollut Bull

September 2024

Dipartimento di Biologia, CoNISMa, Università di Pisa, via Derna No.1, Pisa 56126, Italy. Electronic address:

Artificial light at night (ALAN) is a recognized source of anthropogenic disturbance, although its effects on biological systems have not been fully explored. Within marine ecosystems, coastal areas are the most impacted by ALAN. Here, we focused on the Mediterranean sea urchin Paracentrotus lividus, which has a crucial role in shaping benthic ecosystems.

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Statistical combinations of searches for charginos and neutralinos using various decay channels are performed using 139  fb^{-1} of pp collision data at sqrt[s]=13  TeV with the ATLAS detector at the Large Hadron Collider. Searches targeting pure-wino chargino pair production, pure-wino chargino-neutralino production, or Higgsino production decaying via standard model W, Z, or h bosons are combined to extend the mass reach to the produced supersymmetric particles by 30-100 GeV. The depth of the sensitivity of the original searches is also improved by the combinations, lowering the 95% C.

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Introduction: Urinary incontinence (UI) consists of involuntary leakage of urine during the storage phase of urination.

Methods: An anonymous survey was given to Spanish and Italian veterinarians about canine UI treated cases, diagnosis, treatment, follow-up, and professional interest.

Results And Discussion: Most veterinarians treated ≤3 cases/quarter, resulting in the percentage of incontinence males being lower than that of females (1-4% vs 0-24%).

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Solvation effects on optical rotation are notoriously challenging to model for computational chemistry, as the specific rotatory power of a molecule can vary wildly going from apolar to polar or even protic solvents. To address such a problem, we present a polarizable embedding implementation of an electric and magnetic response property based on density functional theory and the AMOEBA polarizable force field, and apply such an implementation to the study of the optical rotation of camphor in ethanol. By comparing a continuum model, and electrostatic and polarizable embedding QM/MM models, we observe that accounting for the environment's polarization gives rise to not only a different quantitative prediction, in very good agreement with experiments for the QM/AMOEBA model, but also to a very different qualitative picture, with the values of the optical rotation computed along a classical molecular dynamics trajectory with electrostatic embedding being statistically uncorrelated to the ones obtained with the polarizable description.

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Dinuclear enantiopure Ln complexes with (-) and (-) 2-phenylbutyrate ligands. Luminescence, CPL and magnetic properties.

Dalton Trans

August 2024

Departament de Química Inorgànica i Orgànica, Secció de Química Inorgànica, Universitat de Barcelona, Martí i Franquès 1-11, 08028 Barcelona, Spain.

The reaction of Ln(NO)·6HO (Ln = Nd, Sm, Eu, Tb, Dy, Tm and Yb) with the respective enantiopure ()-(-)-2-phenylbutyric or ()-(+)-2-phenylbutyric acid (/-2-HPhBut) and 4,7-diphenyl-1,10-phenanthroline (Bphen) allows the isolation of chiral dinuclear compounds of the formula [Ln(μ-/-2-PhBut)(/-2PhBut)(Bphen)] where Ln = Nd (R/S-Nd-a), Sm (R/S-Sm-a), Eu (R/S-Eu-a), Tb (R/S-Tb-a and R/S-Tb-b), Dy (R/S-Dy-a and R/S-Dy-b), Tm (R/S-Tm-b) and Yb (R/S-Yb-b). Single crystal X-ray diffraction was performed for compounds S-Eu-a and S-Tm-b. Powder crystal X-ray diffraction was performed for all complexes.

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The production of ϒ(2S) and ϒ(3S) mesons in lead-lead (Pb-Pb) and proton-proton (pp) collisions is studied in their dimuon decay channel using the CMS detector at the LHC. The ϒ(3S) meson is observed for the first time in Pb-Pb collisions, with a significance above 5 standard deviations. The ratios of yields measured in Pb-Pb and pp collisions are reported for both the ϒ(2S) and ϒ(3S) mesons, as functions of transverse momentum and Pb-Pb collision centrality.

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Geometric Optimization of Restricted-Open and Complete Active Space Self-Consistent Field Wave Functions.

J Phys Chem A

August 2024

CERMICS, Ecole des Ponts and Inria Paris, 6 & 8 Avenue Blaise Pascal, 77455 Marne-la-Vallée, France.

We explore Riemannian optimization methods for Restricted-Open-shell Hartree-Fock (ROHF) and Complete Active Space Self-Consistent Field (CASSCF) methods. After showing that ROHF and CASSCF can be reformulated as optimization problems on so-called "flag manifolds", we review Riemannian optimization basics and their application to these specific problems. We compare these methods to traditional ones and find robust convergence properties without fine-tuning of numerical parameters.

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A search for and production in the final state is presented, where H is the standard model (SM) Higgs boson. The search uses an event sample of proton-proton collisions corresponding to an integrated luminosity of 133 collected at a center-of-mass energy of 13 with the CMS detector at the CERN LHC. The analysis introduces several novel techniques for deriving and validating a multi-dimensional background model based on control samples in data.

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Transition Metal-Driven Selectivity in Direct C-H Arylation of Imidazo[2,1-b]Thiazole.

ChemistryOpen

November 2024

Dipartimento di Chimica e Chimica Industriale, Università di Pisa, Via Giuseppe Moruzzi, 13, 56124, Pisa, Italy.

A selective direct arylation of the different Csp2-H bonds of imidazo[2,1-b]thiazole with (hetero) aryl halides can be achieved simply by switching from a palladium catalyst system to the use of stoichiometric amounts of copper. The observed selectivity, also rationalized by DFT calculations, can be explained by a change in the mechanistic pathways between electrophilic palladation and base-promoted C-H metalation.

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Impact of appropriateness in clinical practice: data from a single-centre nuclear cardiology laboratory.

Eur Heart J Imaging Methods Pract

September 2023

Imaging Department, Fondazione Toscana Gabriele Monasterio, Via Moruzzi 1, Pisa, Italy.

Aims: To verify the level of appropriateness of referral to our nuclear cardiology laboratory for stress myocardial perfusion imaging (MPI) and explore the correlation between test appropriateness patterns and ischaemia.

Methods And Results: In 1870 consecutive patients (mean age 73 ± 12 years; 33% female) undergoing MPI, the level of imaging test appropriateness was evaluated according to the 2023 Appropriate Use Criteria (AUC) and the current European Society of Cardiology (ESC) guidelines for the management of chronic coronary syndromes. The evidence of moderate-to-severe ischaemia (i.

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The first search for singly produced narrow resonances decaying to three well-separated hadronic jets is presented. The search uses proton-proton collision data corresponding to an integrated luminosity of 138  fb^{-1} at sqrt[s]=13  TeV, collected at the CERN LHC. No significant deviations from the background predictions are observed between 1.

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Noise Level of a Ring Laser Gyroscope in the Femto-Rad/s Range.

Phys Rev Lett

July 2024

Physics Division, School of Science and Technology, Università di Camerino, Via Madonna delle Carceri 9, I-62032 Camerino (MC), Italy.

Absolute angular rotation rate measurements with sensitivity better than prad/s would be beneficial for fundamental science investigations. In this regard, large frame Earth based ring laser gyroscopes are top instrumentation as far as bandwidth, long-term operation, and sensitivity are concerned. Here, we demonstrate that the GINGERINO active-ring laser upper limiting noise is close to 2×10^{-15}  rad/s for ∼2×10^{5}  s of integration time, as estimated by the Allan deviation evaluated in a differential measurement scheme.

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The expression of both lactate dehydrogenase A (LDH-A) and glucose transporter type 1 (GLUT1) is high in pancreatic, thoracic and many other types of cancer. GLUT1 is also highly expressed in endothelial cells (EC), that play an important role in tumor metastasis. We investigated the effect of inhibition of LDH-A by NHI-2 and GLUT1 by PGL14 on cellular migration, a hallmark of metastasis, in relation to changes in intracellular purine nucleotide and nicotinamide adenine dinucleotide pools in a human microvascular endothelial cell line (HMEC-1).

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The phytochemical profile of essential oils is influenced by genetic and paragenetic factors. In this research, we studied the essential oils of and cultivated in Lebanon. The latter is a cross hybrid between and and is also known as lavandin and .

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We consider a three-dimensional lattice Abelian Higgs gauge model for a charged N-component scalar field ϕ, which is invariant under SO(N) global transformations for generic values of the parameters. We focus on the strong-coupling regime, in which the kinetic Hamiltonian term for the gauge field is a small perturbation, which is irrelevant for the critical behavior. The Hamiltonian depends on a parameter v, which determines the global symmetry of the model and the symmetry of the low-temperature phases.

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We study the out-of-equilibrium behavior of statistical systems along critical relaxational flows arising from instantaneous quenches of the temperature T to the critical point T_{c}, starting from equilibrium conditions at time t=0. In the case of soft quenches, i.e.

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Article Synopsis
  • * The measurements utilized both semileptonic and hadronic decays of top quarks, along with events focused on single top quark production in the electroweak t channel.
  • * The combined result for the top quark mass is 172.52 GeV, with a reduced total uncertainty of 0.33 GeV, showcasing an improvement of 31% over previous measurements.
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Article Synopsis
  • * The study investigates environmental effects on known gravitational wave events and finds no evidence to support significant impacts, ruling out certain star formation scenarios.
  • * Future observatories like the Einstein Telescope and B-DECIGO are expected to explore the influence of environmental factors, such as accretion disks and boson clouds, on compact binary formations.
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We consider the nonlinear Schrödinger equation with multiplicative spatial white noise and an arbitrary polynomial nonlinearity on the two-dimensional full space domain. We prove global well-posedness by using a gauge-transform introduced by Hairer and Labbé (Electron Commun Probab 20(43):11, 2015) and constructing the solution as a limit of solutions to a family of approximating equations. This paper extends a previous result by Debussche and Martin (Nonlinearity 32(4):1147-1174, 2019) with a sub-quadratic nonlinearity.

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Purpose: Uncertainty and complexity have increased in recent decades, posing new challenges to humanitarian organisations. This study investigates whether using standard terminology in Human Resource Management processes can support the Humanitarian supply chain in attracting and maintaining highly skilled operators.

Methodology: We exploit text mining to compare job vacancies on ReliefWeb, the reference platform for humanitarian job seekers, and ESCO, the European Classification of Skills, Competencies, and Occupations.

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Chaetonotidae is the most diversified family of the entire phylum Gastrotricha; it comprises ~430 species distributed across 16 genera. The current classification, established mainly on morphological traits, has been challenged in recent years by phylogenetic studies, indicating that the cuticular ornamentations used to discriminate among species may be misleading when used to identify groupings, which has been the practice until now. Therefore, a consensus is developing toward implementing novel approaches to better define species identity and affiliation at a higher taxonomic ranking.

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Background: The study aimed to determine the most crucial parameters associated with CVD and employ a novel data ensemble refinement procedure to uncover the optimal pattern of these parameters that can result in a high prediction accuracy.

Methods And Results: Data were collected from 369 patients in total, 281 patients with CVD or at risk of developing it, compared to 88 otherwise healthy individuals. Within the group of 281 CVD or at-risk patients, 53 were diagnosed with coronary artery disease (CAD), 16 with end-stage renal disease, 47 newly diagnosed with diabetes mellitus 2 and 92 with chronic inflammatory disorders (21 rheumatoid arthritis, 41 psoriasis, 30 angiitis).

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Biofouling on marine surfaces causes immense material and financial harm for maritime vessels and related marine industries. Previous reports have shown the effectiveness of amphiphilic coating systems based on poly(dimethylsiloxane) (PDMS) against such marine foulers. Recent studies on biofouling mechanisms have also demonstrated acidic microenvironments in biofilms and stronger adhesion at low-pH conditions.

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