1 results match your criteria: "UK. j.mcmaster@nottingham.ac.uk and The University of Manchester[Affiliation]"
A Ni(i)Fe(ii) analogue of the Ni-L state of the active site of the [NiFe] hydrogenases.
Chem Commun (Camb)
December 2015
The University of Nottingham, University Park, Nottingham, NG7 2RD, UK. and The University of Manchester, Oxford Road, Manchester, M13 9PL, UK.
[Ni(L(1))Fe((t)BuNC)4](PF6)2 is a robust Ni(II)Fe(II) complex that undergoes a reversible one-electron reduction. Spectroscopic and theoretical studies show that [Ni(L(1))Fe((t)BuNC)4](+) is an unprecedented Ni(I)Fe(II) species that reproduces the electronic configuration of the Ni-L state of the [NiFe] hydrogenases.
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