Fragmentation Considerations Using Amidoamine Oxide Homologs.

This study investigates the mass spectrometric analysis of 10 novel amidoamine oxide compounds, which are innovative hydrogelators for polar solvents. This research aims to identify characteristic fragment patterns for these amide compounds using high-resolution mass spectrometry. Methanol solutions of the compounds were analyzed in positive and negative ion modes, and MS1 and MS2 spectra at 6 collision energy levels were obtained via electrospray ionization and hybrid tandem mass spectrometry.

A Multi-Layer Techno-Economic-Environmental Energy Management Optimization in Cooperative Multi-Microgrids with Demand Response Program and Uncertainties Consideration.

This paper presents a multi-layer, multi-objective (MLMO) optimization model for techno-economic-environmental energy management in cooperative multi-Microgrids (MMGs) that incorporates a Demand Response Program (DRP). The proposed MLMO approach simultaneously optimizes operating costs, MMG operator benefits, environmental emissions, and MMG dependency. This paper proposed a new hybrid ε-lexicography-weighted-sum that eliminates the need to normalize or scalarize objectives.

Influence of sipunculan (peanut worm) activity on orifice formation in scleractinian Heterocyathus for adaptation to soft substrates.

Mutualism profoundly affects the morphology and ecological evolution of both hosts and symbionts involved. Heterocyathus is a solitary scleractinian coral that lives on soft substrata, and sipunculan worms live symbiotically in the tube-like cavities (orifice) inside the coral skeletons. This habitat provides protection to the sipunculan worms against predators and-owing to the mobility of the worms-prevents the coral from being buried with sediments.

A new, unusually large, Scherer, 1974 flea beetle from Borneo, described and sequenced in the field by citizen scientists (Coleoptera, Chrysomelidae, Galerucinae).

Background: The genus Scherer 1974 consists of very small, soil-dwelling flea beetles in South, Southeast and East Asia. Due to their diminutive size and morphological similarities, very little is known about their ecology and taxonomical diversity. It is likely that further studies will reveal this genus to be much more speciose than the 30 species currently recognised.

A Study of Chemical Substances Migrated from Plastic Tableware to Evaluate the Food Safety for Pets.

To evaluate the safety of food for pets, the migration of chemical substances from pet tableware was investigated by mass spectrometry. The presence of polymer additives Irgafos 168 and Erucamide were suspected based on mass spectra and were confirmed to be present in polypropylene tableware. The amount of substances migrated using simulated saliva was examined by liquid chromatography-mass spectrometry after solid phase extraction and purification.

Amidoamine Oxide Surfactants as Low-Molecular-Weight Hydrogelators: Effect of Methylene Chain Length on Aggregate Structure and Rheological Behavior.

Rheology control is an important issue in many industrial products such as cosmetics and paints. Recently, low-molecular-weight compounds have attracted considerable attention as thickeners/gelators for various solvents; however, there is still a significant need for molecular design guidelines for industrial applications. Amidoamine oxides (AAOs), which are long-chain alkylamine oxides with three amide groups, are surfactants that act as hydrogelators.

Ammonia tolerance and microbial community in thermophilic co-digestion of sewage sludge initiated with lignocellulosic biomass.

Rice straw is a useful lignocellulosic biomass for controlling ammonia inhibition in the thermophilic anaerobic digestion of sewage sludge. However, it is challenging to procure rice straw throughout the year because of its seasonal production. This study investigated methane production in a laboratory-scale digester by gradually decreasing rice straw addition to solid thermophilic sewage sludge digestion.

Quantitation of guanidine derivatives as representative persistent and mobile organic compounds in water: method development.

Persistent and mobile organic compounds (PMOCs) are highly soluble in water, thereby posing a threat to water resource quality. Currently, there are no methods that can accurately quantify guanidine derivative PMOCs, other than 1,3-diphenylguanidine (DPG) and cyanoguanidine (CG), in aqueous media. In this study, we developed a quantitation method that combines solid-phase extraction and liquid chromatography (LC)-tandem mass spectrometry to detect seven guanidine derivatives in aquatic environments and applied it to environmental water samples.

Monitoring trophic status using in situ data and Sentinel-2 MSI algorithm: lesson from Lake Malombe, Malawi.

With excessive nutrient enrichment exacerbated by anthropogenic drivers, many standing water bodies are changing from oligotrophic to mesotrophic, eutrophic, and finally hypertrophic-negatively affecting ecosystem functioning, biodiversity, and human populations. Efforts have been devoted to developing novel algorithms for estimating chlorophyll-a (chl-a), cyno-blooms, and floating vegetation. However, to this date, little research has focused on freshwater lakes in the data-scarce Sub-Saharan African countries such as Malawi.

Human Flow Dataset Reveals Changes in Citizens' Outing Behaviors including Greenspace Visits before and during the First Wave of the COVID-19 Pandemic in Kanazawa, Japan.

Greenspaces, including parks, provide various socio-ecological benefits such as for aesthetics, temperature remediation, biodiversity conservation, and outdoor recreation. The health benefits of urban greenspaces have received particular attention since the onset of the COVID-19 pandemic, which has triggered various movement restrictions and lifestyle changes, including regarding the frequency of people's visits to greenspaces. Using mobile-tracking GPS data of Kanazawa citizens, we explored how citizens' behaviors with respect to outings changed before and during Japan's declaration of a COVID-19 state of emergency (April-May 2020).

Dimorphic life cycle through transverse division in burrowing hard coral Deltocyathoides orientalis.

The azooxanthellate solitary scleractinian Deltocyathoides orientalis (family Turbinoliidae), which has bowl-shaped costate corallites, exhibits burrowing behavior on soft substrates and can adapt to an infaunal mode of life. Here, we describe previously unknown aspects of their life history and asexual mode of reproduction based on morphological and molecular phylogenetic analyses. The findings reveal that (1) D.

Photocatalytic reactor design and its application in real wastewater treatment using TiO coated on the stainless-steel mesh.

The application of wastewater treatment using TiO coated on the stainless-steel mesh is promising for disintegrating organic pollutants in wastewater. This research successfully coated TiO particles on stainless-steel mesh for the photocatalyst process by using the dip-coating method. This method was selected due to its simplicity and low cost, as well as its extensive application prospects in wastewater treatment.

New Records of Azooxanthellate Scleractinian Corals (Cnidaria: Anthozoa) from Sagami Bay and Suruga Bay, Japan.

Sagami Bay and Suruga Bay harbor a rich marine biodiversity; however, their outer-shelf scleractinian coral fauna has not been characterized to date. Scleractinian corals were collected by dredge sampling of the Japanese Association for Marine Biology (JAMBIO) Coastal Organisms Joint Surveys in 2015 to elucidate the diversity of azooxanthellate scleractinian corals from the outer shelf zones of Sagami Bay and Suruga Bay. In this study, a total of 1291 azooxanthellate scleractinian specimens were collected, corresponding to 23 genera and 18 species, five of which are new records for Sagami Bay and eight are new records for Suruga Bay.

Hexabromocyclododecane in riverine and estuarine sediments from Osaka, Japan: spatial distribution and concentration variability within identical samples.

In this study, hexabromocyclododecane (HBCD) in riverine and estuarine sediments was investigated in Osaka, Japan. The mean total HBCD concentration detected in sediments ranged from < 0.50 to 130 ng g dry weight.

Inhomogeneity of sediment samples in analysis of hexabromocyclododecane.

The repeatability test of the analytical method for hexabromocyclododecane (HBCD) was conducted with sediment sample. The maximum HBCD concentration exceeded the minimum by a factor of 90 even though the identical sediment samples were used. Therefore, we examined which step of the analytical method was the factor causing variability.

Three new minute leaf litter beetles discovered by citizen scientists in Maliau Basin, Malaysian Borneo (Coleoptera: Leiodidae, Chrysomelidae).

Background: We coin the term "taxon expeditions" for citizen scientists' field courses to carry out publishable taxonomic work in close association with trained taxonomists.

New Information: During the first-ever taxon expedition, in Maliau Basin Studies Centre, Sabah, Malaysian Borneo, the participants sampled leaf litter beetles from lowland dipterocarp forest using the Winkler apparatus. The collected material proved to contain at least three undescribed species of small-bodied (ca.

First real-time observation of transverse division in azooxanthellate scleractinian corals.

Asexual reproduction is one of the most important traits in the evolutionary history of corals. No real-time observations of asexual reproduction in azooxanthellate solitary scleractinian corals have been conducted to date. Here, we describe previously unknown aspects of asexual reproduction by using Truncatoflabellum spheniscus (Family Flabellidae) based on observations of transverse division conducted over 1200 days.

Revaluation of stockpile amount of PFOS-containing aqueous film-forming foam in Japan: gaps and pitfalls in the stockpile survey.

Stockpiles of perfluoro-octane sulfonic acid (PFOS) containing aqueous film-forming foam (AFFF) have the potential to be emitted by leaching, spills, and during use in fire response and other processes. Several studies have discussed the high levels of stockpiled PFOS-containing AFFF and the risk they pose to the environment; however, there are large gaps in the amounts in Japan compared with other countries. For example, 300 tons are stockpiled in Canada, 2200-2600 tons in Switzerland, 1400 tons in Norway, and 19,000 tons in Japan from their reports for publication.

Identification of Anthropogenic Compounds in Urban Environments and Evaluation of Automated Methods for Reading Fragmentation-A Case of River Water.

A workflow based on liquid chromatography/high-resolution mass spectrometry (LC/HR-MS) was applied for the identification of compounds in urban environments. Substances extracted by solid-phase extraction from river water were wholly analyzed by LC/HR-MS without any purification. Fragmentation in collision-induced dissociation was manually studied for the 20 most intense ions in positive- and negative-ion electrospray ionization with accurate mass determination at a resolution of 100,000.

Burrowing hard corals occurring on the sea floor since 80 million years ago.

We describe a previously unknown niche for hard corals in the small, bowl-shaped, solitary scleractinian, Deltocyathoides orientalis (Family Turbinoliidae), on soft-bottom substrates. Observational experiments were used to clarify how the sea floor niche is exploited by turbinoliids. Deltocyathoides orientalis is adapted to an infaunal mode of life and exhibits behaviours associated with automobility that include burrowing into sediments, vertical movement through sediments to escape burial, and recovery of an upright position after being overturned.

Why do boys prefer to play with their fathers rather than with their mothers?

Previous studies carried out in Western countries on mother-infant and father-infant interactions in play activities revealed the following tendencies. (1) Play activities between fathers and their children are physical and unusual, whereas, play between mothers and their children are conventional and moderate. (2) Boys prefer to play with their fathers, whereas, girls prefer to play with their mothers.

Ethological analysis of children-parent interaction in outdoor play.

Previous studies clarified more affinity toward fathers by boys and toward mothers by girls (FB&MG tendency) in indoor play interactions between infants (a few years old) and parents of Western countries. In the present study, behavioral interactions by Japanese parents and children including infants and elementary school pupils were examined in a naturalisitic outdoor park. The results indicated that the FB&MG tendency is also seen in infants of a non-Western country (Japan), in outdoor play interaction, and in older children.

Gender differences in memory for film of pigmies' hunting-gathering activities among Japanese children and adults.

Although adaptation to hunting-gathering life is a main hypothesis for understanding of the nature of humans, studies directly examining the hypothesis have not been done. In the present study, we used the method of showing a film depicting hunting and housework by African hunter-gatherers to elementary pupils and university students to examine their memories. In pupils and students, males showed higher percentage of correct answers than females for hunting-related questions, and female showed higher percentage for housework-related questions.

Female-left and male-right positioning by young Japanese couples.

I discovered a phenomenon related to nonverbal sex differences in young Japanese couples in which the female tends to assume the left side position and the male tends to assume the right position (FM tendency) when the couple are walking on sidewalks and in parks. As the first step of the present study, some aspects of this phenomenon were examined through field observation. In total, 2,827 couples (teens and 20s: 1,799; 30s and 40s: 732; older than 50: 296) were examined.