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Effect of mass ratio on micro-mesoporous Cu-SSZ-13/CeWTi composite catalysts for the selective catalytic reduction of NO with ammonia.

RSC Adv

July 2021

Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin Key Laboratory of Applied Catalysis Science & Technology, School of Chemical Engineering & Technology, Tianjin University Tianjin 300350 China

A series of micro-mesoporous SSZ-13/CeWTi composites with different zeolite/oxide ratios were synthesized using a one-step crystallization method. The effects of the mass ratio on the crystal form, specific surface area, pore structure, surface element properties, redox properties, surface acidity and deNO performance of the Cu-SSZ-13/CeWTi composite catalysts were investigated using X-ray diffractometry (XRD), Brunauer-Emmett-Teller analysis (BET), X-ray photoelectron spectroscopy (XPS), H temperature programmed reduction (H-TPR) and NH temperature programmed desorption (NH-TPD). The results reveal that the Cu-SSZ-13/CeWTi composite catalysts formed a micro-mesoporous structure.

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