Chlorination-induced spread of antibiotic resistance genes in drinking water systems.

Chlorine, the most widely utilized disinfectant for drinking water globally, has recently been implicated in facilitating the spread of antibiotic resistance genes (ARGs), raising concerns about its underestimated environmental and ecological risks. However, given the current fragmented research focus and results, a comprehensive understanding of the potential mechanisms and influencing factors behind chlorination-promoted ARGs transmission in drinking water systems is crucial. This work is the first to systematically review the variations in abundance, transmission mechanisms, influencing factors, and mitigation strategies related to ARGs during the chlorination process.

Using the Forel-Ule index (FUI) to track the water quality of subsidence water bodies across the life cycle of coal mining in eastern China.

The water quality and associated ecological risks in subsidence water bodies formed by underground coal mining are an increasing global concern. However, long-term water quality changes in these subsidence water bodies, especially across different spatial regions, remain poorly understood. This paper, by mapping the Forel-Ule index (FUI) a key indicator of water color, using Landsat datasets to reveal the dynamic evolution of water quality in 402 subsidence water bodies in the Huang-Huai-Hai Plain of eastern China from 1990 to 2020, covering their life cycle from formation to extinction.

MambaPose: A Human Pose Estimation Based on Gated Feedforward Network and Mamba.

Human pose estimation is an important research direction in the field of computer vision, which aims to accurately identify the position and posture of keypoints of the human body through images or videos. However, multi-person pose estimation yields false detection or missed detection in dense crowds, and it is still difficult to detect small targets. In this paper, we propose a Mamba-based human pose estimation.

Temporal and spatial variations of urban surface temperature and correlation study of influencing factors.

Urban overheating significantly affects thermal comfort and livability, making it essential to understand the relationship between urban form and land surface temperature (LST). While the horizontal dimensions of urban form have been widely studied, the vertical structures and their impact on LST remain underexplored. This study investigates the influence of three-dimensional urban form characteristics on LST, using ECOSTRESS sensor data and four machine learning models.

Magnesium/methanol-d1: a practical reductive deuteration system for the deuterium labeling of α,β-unsaturated esters, nitriles and amides.

The use of magnesium and methanol in the reduction of various functional groups has been well established. In this study, we present a reductive deuteration system using Mg/CHOD, which successfully facilitates the conversion of α,β-unsaturated esters, amides, and nitriles to their saturated counterparts. This protocol achieves good yields and high degrees of deuterium incorporation, while avoiding defunctionalization in the presence of various functional groups.

Recent advances in the reactions of isatin-derived MBH carbonates for the synthesis of spirooxindoles.

As one of the main fragments in medical drugs, spirooxindole has received considerable attention from organic and medicinal chemists. In the past few decades, chemists have been searching for more straightforward and efficient methods to produce compounds containing a spirooxindole fragment. In this regard, isatin-derived Morita-Baylis-Hillman (MBH) carbonates have been widely used as versatile building blocks for the synthesis of spirooxindole structures.

A Gravity-Driven Membrane Bioreactor in Treating Real Fruit Juice Wastewater: Response Relationship Between Filtration Behavior and Microbial Community Evolution.

The issue of environmental pollution caused by wastewater discharge from fruit juice production has attracted increasing attention. However, the cost-effectiveness of conventional treatment technology remains insufficient. In this study, a gravity-driven membrane bioreactor (GDMBR) was developed to treat real fruit juice wastewater from secondary sedimentation at pressures ranging from 0.

[Progress in the Application of Biochar in Constructed Wetland].

Constructed wetlands, serving as artificially simulated natural wetland water treatment systems, have emerged as effective technologies for ecologically treating wastewater. Biochar, a carbon material derived from biomass waste pyrolysis, possesses significant specific surface area, abundant functional groups, and high stability. The integration of biochar into artificial wetland systems enhances the removal efficiency of pollutants.

Valence-engineering modulation of MoS clusters for enhancing biocatalytic activity.

Earth-abundant MoS with the advantages of a stable structure, tunable bandgap, and easy shear has great potential for applications in the fields of catalysis, biomedicine, and so on. However, the biocatalytic activity of MoS remains little investigated and is insufficient for biomedical applications. In this work, we develop ultra-small and water-soluble MoS clusters with superior antioxidant activity and enzyme-like activity valence-engineering modulation with Ce doping.

The removal of high Se(IV) and Cd(II) concentrations in sulfur autotrophic reactor based on the "hibernation-like microbial survival strategy".

The removal of selenite (Se(IV)) and cadmium (Cd(II)) from low-carbon wastewater presents significant challenges. However, the addition of external organic carbon sources is limited in application due to the high cost and potential for secondary pollution. This study introduced a "hibernation-like microbial survival strategy", enabling efficient removal of Se(IV) and Cd(II) in sulfur autotrophic reactor, with S acting as the electron donor.

Evaluation of volatile safety in children's play mats based on non-targeted screening and risk prioritization.

Given the widespread use of play mats and their close contact with children, it is crucial to identify potential chemical hazards associated with these products. In this study, 34 play mats, comprising four materials (3 EPE, 15 XPE, 5 PVC, 11 EVA), were subjected to non-targeted screening based on headspace gas chromatography-Orbitrap high-resolution mass spectrometry (HS-GC-Orbitrap HRMS), which screened out 71 volatile substances. The 20 significantly different substances were recognized by partial least squares discriminant analysis (PLS-DA), while the characteristic substances in each type of play mat were determined through clustering heat map and Venn diagram.

High-stable bimetallic AgCu nanoalloys with core-shell structures for sustainable antibacterial and biofouling mitigation in nanofiltration.

Nanofiltration (NF) is crucial for advancing water purification and wastewater reuse technologies. Incorporating biocidal nanoparticles (NPs) such as AgNPs and CuNPs is promising for developing antibacterial and antibiofouling NF membranes, while their application is limited by NPs aggregation, high cost, and severe ion release. In this study, we developed novel NF membranes by integrating bimetallic AgCu nanoalloys via an in-situ reduction and coordination method facilitated by a polydopamine/polyethyleneimine (PDA/PEI) intermediate layer.

Remodeling the Inflammatory and Immunosuppressive Tumor Microenvironment for Enhancing Antiangiogenic Gene Therapy of Colorectal Cancer.

Fusobacterium nucleatum (Fn), as an intestinal pathogenic bacterium, is closely related to the occurrence, progression, and limited therapeutic efficacy of colorectal cancer (CRC). The presence of Fn within CRC communities induces an inflammatory and immunosuppressive microenvironment while promoting new vessel formation. Therefore, developing novel methods to efficiently eliminate Fn and enhance the therapeutic outcomes against Fn-associated CRC is of great significance.

Porous polyurethane biocarriers could enhance system nitrification resilience under high organic loading by retaining key functional bacteria.

Resilience to increasing organic loading rates (OLRs) is the key to maintaining stable performance in treating industrial wastewater. First, this study compared the stability, particularly the nitrification performance, of two lab-scale moving bed biofilm reactors (MBBRs) filled with porous polyurethane biocarriers with two conventional activated sludge reactors (ASRs) in the treatment of synthetic coking wastewater under OLRs increasing from 0.3 kg to 1.

Study on the mechanism of regulating micromolar Fe utilization and promoting denitrification by guanosine monophosphate (GMP) based multi-signal functional material Hematin@Fe/GMP.

A novel multi-signal functional material consisting of Hematin, Fe, and guanosine monophosphate (GMP) was successfully constructed (Hematin@Fe/GMP) to enhance denitrification efficiency based on the signal network regulation of electron transfer, micromolar Fe utilization, and microbial community. Hematin@Fe/GMP enhanced nitrate reduction rate by 2.33-fold with a 9.

Clay minerals-mediated removal of Norfloxacin and Norfloxin-resistant bacteria from water environments and associated mechanisms.

Norfloxacin (NOR) is frequently detected in various water bodies and has the potential to promote the proliferation of NOR-resistant bacteria/genes in the environment. Efficiently removing residual NOR and NOR-resistant bacteria from contaminated water is critical to mitigating their environmental risks. This study investigated the ability of two common clay minerals, kaolinite and montmorillonite, to remove NOR and NOR-resistant bacteria from five different water environments (ultrapure water, simulated and real freshwater, and simulated and real seawater) and explored the underlying removal mechanisms.

Late-stage (radio)fluorination of alkyl phosphonates via electrophilic activation.

Constructing organic fluorophosphines, vital drug skeletons, through the direct fluorination of readily available alkyl phosphonates has been impeded due to the intrinsic low electrophilicity of P and the high bond energy of P═O bond. Here, alkyl phosphonates are electrophilically activated with triflic anhydride and N-heteroaromatic bases, enabling nucleophilic fluorination at room temperature to form fluorophosphines via reactive phosphine intermediates. This approach facilitates the late-stage (radio)fluorination of broad dialkyl and monoalkyl phosphonates.

Phenylmethylsiloxanes in the typically human-impacted Xiaoqing River of China: Their distribution and degradation in both waterbodies and mussels.

Based on sampling from Xiaoqing River of China and elimination experiments, this study first investigated spatial/seasonal profiles and fates of phenylmethylsiloxanes (PMSs), as modified products of dimethylsiloxanes (DMSs), in natural waterbody. Overall, the average water (6.7 ng/L) and sediment (28.

Potassium-Based Solid Sorbents for CO Adsorption: Key Role of Interconnected Pores.

Industrial CO emissions contribute to pollution and greenhouse effects, highlighting the importance of carbon capture. Potassium carbonate (KCO) is an effective CO absorbent, yet its liquid-phase absorption faces issues like diffusion resistance and corrosion risks. In this work, the solid adsorbents were developed with KCO immobilized on the selected porous supports.

Uniform anchoring of MoS nanosheets on MOFs-derived CoFeO porous nanolayers to construct heterogeneous structural configurations for efficient and stable overall water splitting.

Rational interfacial engineering and morphology modulation are recognized as effective strategies to modulate the electronic structure and improving the activity of spinel materials. In this paper, we report a strategy of Fe-induced creation of porous nanolayers of CoFeO with unique morphology derived from MOFs by introducing ferrocene, and then constructed CoFeO/MoS heterostructures were fabricated by homogeneously anchoring MoS nanosheets onto the surface of CoFeO. The triple synergistic effect of heterogeneous interfaces, highly active Mo(IV) sites, and unsaturated S effectively accelerates the cycling process between Fe(III)/Fe(II) and Co(III)/Co(II), which in turn enhances the adsorption of reactive intermediates on the active sites, as further corroborates by density functional theory (DFT) calculations.

Non-target analysis of organic pollutants in oil-production wastewater treatment stations and surrounding soils: Their profiles, electro-transformation, and environmental risks.

Although pollution during crude oil production has been paid attention, there is lack of studies on organic pollutants generated/emitted from oil-production wastewater (OPW) treatment processes, especially advanced oxidation process. Based on GC-Q-Orbitrap-HRMS, the present study performed non-target analysis of volatile/semi-volatile organic compounds in physical and electro-oxidation units of OPW treatment stations located in Shengli Oilfield of China. Overall, 64-227 organic compounds were respectively identified in different units, and electro-oxidation was found elevating (by 2.

Reducing carbon emissions in the cement industry using effective measures based on countries' characteristics.

Cement production contributes 5% of global anthropogenic CO2 emissions (CEs), and more than 90% of the CEs are in the procedure of pyroprocessing. Thus calculating the pyroprocessing CO2 emission number (PCEN), determining CE-impacted factors, and investigating tailored measures of PCEN reduction for countries based on their characteristics is quite necessary. More specifically, different countries can meet different obstacles to reducing PCENs, such as different restrictions on natural resources and policies, improper energy structures, and so on.

Unraveling the mechanisms of anammox coupled process with thiosulfate-driven denitrification: Community succession and substrate competition.

Thiosulfate-driven denitrification coupled with anammox (TDDA) has garnered interest for its efficient and innovative nitrogen removal capabilities. However, the intricate dynamics of the internal microbial community and the specific characteristics of anaerobic ammonium oxidizing bacteria (AnAOB) remain incompletely understood. This study combines experimental methods with density functional theory (DFT) calculations to address these gaps.