1 results match your criteria: "The University of Tokyo 2-11-16 Yayoi Bunkyo-ku Tokyo 113-0032 Japan aikawa@g.ecc.u-tokyo.ac.jp.[Affiliation]"
Fluoroalkylated hypervalent sulfur fluorides: radical addition of arylchlorotetrafluoro-λ-sulfanes to tetrafluoroethylene.
Chem Sci
November 2023
Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo 2-11-16 Yayoi Bunkyo-ku Tokyo 113-0032 Japan
Fluorinated groups are essential hydrophobic groups in drug design. Combining a carbon-free tetrafluoro-λ-sulfanyl (SF) group with a polyfluoroalkyl group (R) provides SFR groups, exhibiting high hydrophobicity with a short carbon chain. In this study, various aryltetrafluoro(polyfluoroalkyl)-λ-sulfanes (ArSFR) were synthesized through the radical addition of arylchlorotetrafluoro-λ-sulfanes (ArSFCl) to tetrafluoroethylene.
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