2 results match your criteria: "The University of Texas at Arlington Arlington TX 76019 USA dias@uta.edu.[Affiliation]"
Correction: When SF outplays CF: effects of pentafluorosulfanyl decorated scorpionates on copper.
Chem Sci
January 2024
Department of Chemistry and Biochemistry, The University of Texas at Arlington Arlington TX 76019 USA
[This corrects the article DOI: 10.1039/D1SC04846E.].
View Article and Find Full Text PDFWhen SF outplays CF: effects of pentafluorosulfanyl decorated scorpionates on copper.
Chem Sci
November 2021
Department of Chemistry and Biochemistry, The University of Texas at Arlington Arlington TX 76019 USA
Polyfluorinated, electron-withdrawing, and sterically demanding supporting ligands are of significant value in chemistry. Here we report the assembly and use of a bis(pyrazolyl)borate, [PhB(3-(SF)Pz)] that combines all such features, and involves underutilized pentafluorosulfanyl substituents. The ethylene and carbonyl chemistry of copper(i) supported by [PhB(3-(SF)Pz)], a comparison to the trifluoromethylated counterparts involving [PhB(3-(CF)Pz)], as well as copper catalyzed cyclopropanation of styrene with ethyl diazoacetate and CFCHN are presented.
View Article and Find Full Text PDF