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Chem Sci
December 2024
Department of Chemistry, The Scripps Research Institute 10550N. Torrey Pines Road, La Jolla CA 92037 USA
Catalytic alkene isomerization is a powerful synthetic strategy for preparing valuable internal alkenes from simple feedstocks. The utility of olefin isomerization hinges on the ability to control both positional and stereoisomerism to access a single product among numerous potential isomers. Within base-metal catalysis, relatively little is known about how to modulate reactivity and selectivity with group 6 metal-catalyzed isomerization.
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