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The interaction of tri-n-butyl phosphate (TBP) with various solutes has been investigated by gas-liquid chromatography (GLC). In the case of benzene and chloroalkane solutes, the formation of 1:1 complexes has been assumed. The nonlinear behaviour of partition coefficients of the solutes with high TBP concentration in an inert solvent (n-tetradecane) has been explained in terms of the dimerization of TBP.

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