Pseudohalide Anions Driven Structural Modulation in Distorted Tetrahedral Manganese(II) Hybrids Toward Tunable Green-Red Emissions.

Mn(II)-based halides have recently garnered significant interest as emerging luminescence materials for diverse photonic applications. Generally, Mn(II) hybrids with tetrahedral coordination show green emission, however, ones with octahedral coordination give red emission. Herein, we design the synthesis of tetrahedral Mn(II) pseudohalide hybrids, (RPhP)MnBrNCS (R=phenyl, pentyl or methyl; PhP=triphenylphosphine; x=1-3), achieved by gradually substituting bromides with pseudohalides (NCS).

Phosphor-in-Ceramic-Converted Laser-Driven Near-Infrared Light Sources for Multiple Intelligent Spectroscopy Applications.

Ultrabright broadband near-infrared (NIR) phosphor-converted laser diode (pc-LD) as a light source is increasingly essential for improving the sensitivity and spatial resolution of intelligent NIR spectroscopy technologies. However, the performance of NIR pc-LD is greatly hindered by the low external quantum efficiency (EQE) and poor thermal resistance of phosphor materials. Herein, a highly stable phosphor-in-ceramic (PiC) film deposited on high thermal conductivity substrate, in which the NIR-emitting CaMgHfGeO:Cr phosphor is incorporated into a glass-crystallized CaGaGeO ceramic matrix, along with the formation of a new type PiC composite material with high efficiency, absorbance, and thermal conductivity, is designed and prepared.

Hybrid Eu(II)-bromide scintillators with efficient 5d-4f bandgap transition for X-ray imaging.

Luminescent metal halides are attracting growing attention as scintillators for X-ray imaging in safety inspection, medical diagnosis, etc. Here we present brand-new hybrid Eu(II)-bromide scintillators, 1D type [EtN]EuBr·MeOH and 0D type [MeN]EuBr·MeOH, with spin-allowed 5d-4f bandgap transition emission toward simplified carrier transport during scintillation process. The 1D/0D structures with edge/face -sharing [EuBr] octahedra further contribute to lowing bandgaps and enhancing quantum confinement effect, enabling efficient scintillation performance (light yield ~73100 ± 800 Ph MeV, detect limit ~18.

A Dataset of apical periodontitis lesions in panoramic radiographs for deep-learning-based classification and detection.

Deep learning has been studied in recent years to identify periapical lesions- a significant indicator of periapical periodontitis in radiographs. An accurate dataset is essential for constructing an efficient learning model for detecting periapical lesions. In order to achieve this goal, we gathered and created a database of panoramic radiographs containing periapical lesions from the High-quality Dental Treatment Centre, School of Dentistry, Hanoi Medical University, between January 2016 and March 2021.

Narrow-Band Green-Emitting Hybrid Organic-Inorganic Eu (II)-Iodides for Next-Generation Micro-LED Displays.

Low-dimensional metal halide perovskites are an emerging class of light-emitting materials for LED-based displays; however, their B-site cations are confined to ns, d and d metals. Here, the design of divalent rare earth ions at B-site is presented and a novel Eu(II)-based iodide hybrid is reported with efficient (PLQY ≈98%) narrow-band (FWHM ≈43 nm) green emission and high thermal stability (97%@150 °C). Owing to reduced lattice vibrations and shrunken average distance of Eu(II)-iodide bonds in the face-sharing 1D-structure, photoluminescence from Eu(II) 4f-5d transition appears along with elevated crystal-field splitting of 5d energy level.

Rapid synthesis of phosphor-glass composites in seconds based on particle self-stabilization.

Phosphor-glass composites (PGC) are excellent candidates for highly efficient and stable photonic converters; however, their synthesis generally requires harsh procedures and long time, resulting in additional performance loss and energy consumption. Here we develop a rapid synthetic route to PGC within about 10 seconds, which enables uniform dispersion of YAlO:Ce (YAG:Ce) phosphor particles through a particle self-stabilization model in molten tellurite glass. Thanks for good wettability between YAG:Ce micro-particles and tellurite glass melt, it creates an energy barrier of 6.

Thermally Stable Red-Emitting Oxide Ceramics for Laser Lighting.

Laser-driven phosphor-converted white light sources are highly desirable for their unprecedented energy efficiency and lighting quality. However, important challenges remain due to a lack of efficient and stable red-emitting materials. Here Eu -activated oxide-based double perovskites are explored as red emitters with thermally stable photoluminescence.

Energy-Trapping Management in X-Ray Storage Phosphors for Flexible 3D Imaging.

X-ray imaging has received sustained attention for healthcare diagnostics and nondestructive inspection. To develop photonic materials with tunable photophysical properties in principle accelerates radiation detection technologies. Here the rational design and synthesis of doped halide perovskite CsCdCl :Mn , R (R = Ti, Zr, Hf, and Sn) are reported as next generation X-ray storage phosphors, and the capability is greatly improved by trap management via Mn site occupation manipulation and heterovalent substitution.

Clinical characteristics and predictors for cardiovascular system involvement in patients with Behçet's disease.

Objectives: The purpose of this study is to analyse the clinical characteristics of Behçet's disease (BD) patients in China with or without cardiovascular system involvement, and to develop a risk model to identify factors related to cardiovascular involvement in BD.

Methods: This retrospective cohort study, using the information on BD in Shenzhen People's Hospital from January 2000 to December 2021, included 95 patients: BD patients without cardiovascular system involvement (n=63) and with cardiovascular system involvement (n=32).

Results: Patients with BD who were males and had a combination of hypertension and a longer duration of disease were more likely to have cardiovascular involvement (p < 0.

Efficacy of epi-1 modified epirubicin and curcumin encapsulated liposomes targeting-EpCAM in the inhibition of epithelial ovarian cancer cells.

Treatment of epithelial ovarian cancer (EOC) is a challenge because it still leads to unsatisfactory clinical prognosis. This is due to the toxicity and poor targeting of chemotherapeutic agents, as well as metastasis of the tumor. In this study, we designed a targeted liposome with nanostructures to overcome these problems.

Lack of Habituation in Migraine Patients Based on High-Density EEG Analysis Using the Steady State of Visual Evoked Potential.

Migraine is a periodic disorder in which a patient experiences changes in the morphological and functional brain, leading to the abnormal processing of repeated external stimuli in the inter-ictal phase, known as the habituation deficit. This is a significant feature clinically of migraine in both two types with aura or without aura and plays an essential role in studying pathophysiological differences between these two groups. Several studies indicated that the reason for migraine aura is cortical spreading depression (CSD) but did not clarify its impact on migraine without aura and lack of habituation.

Automatic Malignant and Benign Skin Cancer Classification Using a Hybrid Deep Learning Approach.

Skin cancer is one of the major types of cancer with an increasing incidence in recent decades. The source of skin cancer arises in various dermatologic disorders. Skin cancer is classified into various types based on texture, color, morphological features, and structure.

Highly Distorted Antimony(III) Chloride [Sb Cl ] Dimers for Near-Infrared Luminescence up to 1070 nm.

Zero-dimensional (0D) hybrid metal halides with unique compositional and structural tunability appear as an emerging class of luminescent materials, but near-infrared (NIR) emitters therein are largely unexplored to date. This study presents three novel 0D hybrid antimony chlorines with edge-sharing [Sb Cl ] dimers, showing unusual room-temperature broadband NIR emission with the maximum emission wavelength up to 1070 nm. Photoluminescence studies and density functional theory calculation demonstrate that the emissions originate from the highly localized excitons, and that the confined [Sb Cl ] dimers in these structures show low symmetry and a large degree of structural freedom.

Modulation of Thermally Stable Photoluminescence in Cr-Based Near-Infrared Phosphors.

Broadband near-infrared (NIR) light sources based on phosphor-converted light-emitting diodes (pc-LEDs) are desirable for various photonics applications, while developing thermally stable NIR phosphors remains a great challenge. Increasing the temperature accelerates the severe nonradiative relaxation process gorverned by the intrinsic energy gap law, which further suspends the efficient low-energy emission of Cr emitters in the inorganic lattice. To address this rule, several state-of-the-art strategies have been put forward in this perspective to modulate the critical law from the viewpoints of (1) crystal structure design, (2) defect engineering, (3) strengthened rigidity, and (4) energy transfer.

Corneal Endothelial Characteristics in Normal Chinese Han Children and Youngsters: A Study from the Specular Microscopy Descriptions.

Objective: To observe the morphological changes of corneal endothelial cells in healthy Chinese children and youngsters and analyze the sensitive and specificity of the endothelial assessments.

Methods: 14,670 Chinese healthy volunteers enrolled were examined by specular microscopy, and the endothelial descriptive indexes: the central corneal thickness (CCT), endothelial cell density (ECD), coefficient of variation in average cell size (CV), the percentage of regular hexagonal cells (hexagonality, HEX), cell size of minimal cell ( ), cell size of maximal cell ( ), average cell size ( ), and size of standard deviation of cell area ( ) as well as sex and age were analyzed.

Results: The average age of this study is 17.

Hypochlorous Acid Can Be the Novel Option for the Meibomian Gland Dysfunction Dry Eye through Ultrasonic Atomization.

Background: Dry eye is a multifactor disease which needs comprehensive treatments to keep the homeostasis of ocular surface.

Objective: To explore the effect of hypochlorous acid on the meibomian gland dysfunction dry eye through ultrasonic atomization.

Methods: We set this study of 0.

EEG feature fusion for motor imagery: A new robust framework towards stroke patients rehabilitation.

Stroke is the second foremost cause of death worldwide and is one of the most common causes of disability. Several approaches have been proposed to manage stroke patient rehabilitation such as robotic devices and virtual reality systems, and researchers have found that the brain-computer interfaces (BCI) approaches can provide better results. Therefore, the most challenging tasks with BCI applications involve identifying the best technique(s) that can reveal the neuron stimulus information from the patients' brains and extracting the most effective features from these signals as well.

Development and characterization of octreotide-modified curcumin plus docetaxel micelles for potential treatment of non-small-cell lung cancer.

We prepared octreotide (OCT)-modified curcumin plus docetaxel micelles to enhance active targeting and inhibit tumor metastasis by destroying vasculogenic mimicry (VM) channels. Soluplus was applied as an amphiphilic material to form micelles via film dispersion. The cytotoxic effects, active cellular targeting, and inhibitory effects on metastasis were systematically evaluated using A549 cells, and antitumor effects were evaluated using xenograft tumor-bearing mice.

Determination of 3,5 - dimethylpyrazolium glyceroborate nitrification inhibitor in nitrogen fertilizer samples: HPLC-DAD method development and validation for 3,5 - dimethylpyrazole.

3,5 - Dimethylpyrazolium glyceroborate is a nitrification inhibitor (a member of pyrazole derivatives) used for the fixation of nitrogen into the soil. In this study, an HPLC-DAD method was developed and validated for determination of 3,5 - dimethylpyrazole in order to determine 3,5 - dimethylpyrazolium glyceroborate in fertilizer samples. For method development, analytical parameters like type of eluent solution and column filling material and device parameters like eluent flow rate, column oven temperature and measurement wavelength were all optimized.

A new multienzyme-type biosensor for triglyceride determination.

An amperometric multienzyme biosensor for determination of triglycerides (TGs) was constructed by mounting three gelatin membrane-bound enzymes on a glassy carbon electrode (working electrode), then connecting it to electrometer along with an Ag/AgCl reference electrode and a Pt auxiliary electrode. Characterization and optimization of the multienzyme biosensor, which is prepared with glycerol kinase (GK) (E.C.

Sustained delivery of BMP-2 enhanced osteoblastic differentiation of BMSCs based on surface hydroxyapatite nanostructure in chitosan-HAp scaffold.

The surface characteristics of biomaterials, especially regarding the sustained delivery of bone morphogenetic protein-2 (BMP-2), can possibly provide a novel and effective drug delivery system that can enhance osteogenesis. In this study, we evaluated the BMP-2 adsorption and release ability of the surface biomimetic hydroxyapatite (HAp) nanostructure on a new HAp-coated genipin-chitosan conjugation scaffold (HGCCS), and the resulting osteogenic differentiation of rat bone marrow-derived mesenchymal stem cells (BMSCs) in vitro. HGCCS exhibited a loading efficiency of 65% (1.

Fipronil resistance in the whitebacked planthopper (Sogatella furcifera): possible resistance mechanisms and cross-resistance.

Background: The whitebacked planthopper (WBPH), Sogatella furcifera (Horváth), is a major rice pest in many parts of Asia. Fipronil has been widely used to control rice pests, and resistance to fipronil has been reported in some important species.

Results: A field population (F) of WBPH was collected, with 50.