Structure and Reactivity of a Manganese(VI) Nitrido Complex Bearing a Tetraamido Macrocyclic Ligand.

Manganese complexes in +6 oxidation state are rare. Although a number of Mn(VI) nitrido complexes have been generated in solution via one-electron oxidation of the corresponding Mn(V) nitrido species, they are too unstable to isolate. Herein we report the isolation and the X-ray structure of a Mn(VI) nitrido complex, [Mn(N)(TAML)] (), which was obtained by one-electron oxidation of [Mn(N)(TAML)] ().

Contemporary practices of strength and conditioning coaches in professional soccer.

This study describes the contemporary practices of strength and conditioning coaches in professional soccer. Fifty-two strength and conditioning coaches from professional leagues across 18 countries completed an online survey, consisting of 45 questions, with eight sections: (a) background information, (b) muscular strength and power development, (c) speed development, (d) plyometrics, (e) flexibility development, (f) physical testing, (g) technology use, and (h) programing. A frequency analysis was used to assess and report responses to fixed response questions, and thematic-analysis used for open-ended questions to create clear, identifiable and distinct themes.

Phylogenetically divergent bacteria consortium from neutral activated sludge showed heightened potential on bioleaching spent lithium-ion batteries.

Recycling of spent lithium-ion batteries (LIBs) has become a global issue because of the potential environment risks raised by spent LIBs as well as high valuable metal content remaining in them. Although bioleaching is an environmentally friendly method to recover metals from spent LIBs, the commonly utilized bioleaching bacterial consortia or strains enriched/isolated from acidic environments cannot be applied at large scales owing to their long leaching cycle and poor tolerance to organic compounds. Here, two bioleaching consortia were enriched in 60 days from neutral activated sludge and were identified phylogenetically divergent from the documented bioleaching bacteria.

Impact of drivers on real-driving fuel consumption and emissions performance.

Eco-driving has attracted great attention as a cost-effective and immediate measure to reduce fuel consumption significantly. Understanding the impact of driver behaviour on real driving emissions (RDE) is of great importance for developing effective eco-driving devices and training programs. Therefore, this study was conducted to investigate the performance of different drivers using a portable emission measurement system.

In-season training responses and perceived wellbeing and recovery status in professional soccer players.

This study aimed to describe professional soccer players' training responses during a competitive season and to investigate the relationship between these responses with wellbeing and recovery indices. Thirteen professional soccer players from the same Spanish Second Division team were monitored during a sixteen-week in-season period. Players' external loads were analyzed using global positioning measurement units (GPS).

A Comparison of Match Demands Using Ball-in-Play versus Whole Match Data in Professional Soccer Players of the English Championship.

This is the first study to report the whole match, ball-in-play (BiP), ball-out-of-play (BoP), and Max BiP (worst case scenario phases of play) demands of professional soccer players competing in the English Championship. Effective playing time per soccer game is typically <60 min. When the ball is out of play, players spend time repositioning themselves, which is likely less physically demanding.

Acute Responses of Core Muscle Activity during Bridge Exercises on the Floor vs. the Suspension System.

This study aimed to compare the neuromuscular activation of selected core musculature in supine and prone bridge exercises under stable versus suspended conditions. Forty-three healthy male participants were recruited to measure the electromyographic activities of the rectus abdominis (RA), lumbar multifidus (LM), thoracic erector spinae (TES), rectus femoris (RF), gluteus maximus (GM), and biceps femoris (BF) during supine and prone bridge exercises under six conditions: control, both arms and feet on the floor (Prone and Supine); arms on the floor and feet on the suspension system (Prone-Feet and Supine-Feet); and arms on the suspension system and feet on the floor (Prone-Arm and Supine-Arm). Prone-Arm yielded significantly higher activities in the RA, RF, TES, and LM than Prone-Feet ( < 0.

Cross-sectional study of the relationship between the spiritual wellbeing and psychological health among university Students.

University students' spiritual wellbeing has been shown to be associated with quality, satisfaction, and joy of life. This study tested the relationship between spiritual wellbeing and symptoms of psychological disorders (i.e.

Predicting student satisfaction of emergency remote learning in higher education during COVID-19 using machine learning techniques.

Despite the wide adoption of emergency remote learning (ERL) in higher education during the COVID-19 pandemic, there is insufficient understanding of influencing factors predicting student satisfaction for this novel learning environment in crisis. The present study investigated important predictors in determining the satisfaction of undergraduate students (N = 425) from multiple departments in using ERL at a self-funded university in Hong Kong while Moodle and Microsoft Team are the key learning tools. By comparing the predictive accuracy between multiple regression and machine learning models before and after the use of random forest recursive feature elimination, all multiple regression, and machine learning models showed improved accuracy while the most accurate model was the elastic net regression with 65.

Fate of Macrolide Antibiotics with Different Wastewater Treatment Technologies.

Unlabelled: This comprehensive study addressed the occurrence, seasonal changes, removal efficiencies, and environmental risk assessments of three macrolide antibiotics in five wastewater treatment plants (WWTPs) with conventional and different additional treatment processes. A 1-year monitoring study was conducted, and influents and effluents were collected from Guangzhou (GZ), Shenzhen (SZ), Tai Po (TP), Shatin (ST), and Stonecutters Island (SI) WWTPs. Solid phase extraction and HPLC-MS/MS were used for the pretreatment and determination.

Strength and Conditioning Practices and Perspectives of Volleyball Coaches and Players.

To the authors' knowledge this is the first study to describe the strength and conditioning (S&C) practices and perspectives of volleyball coaches and players. In total, 30 volleyball coaches (mean age 34.47 ± 7.

Simultaneous PAHs degradation, odour mitigation and energy harvesting by sediment microbial fuel cell coupled with nitrate-induced biostimulation.

The study investigates a bioremediation process of polycyclic aromatic hydrocarbons (PAHs) removal and odour mitigation combined with energy harvesting. Sediment microbial fuel cells (SMFCs) were constructed with the addition of nitrate in the sediment to simultaneously remove acid-volatile sulphide (AVS) and PAHs. With the combined nitrate-SMFC treatment, over 90% of the AVS was removed from the sediment in 6 weeks of the SMFC operation and a maximum of 94% of AVS removal efficiency was reached at Week 10.

Chemical and toxicological characterization of particulate emissions from diesel vehicles.

This paper presents a detailed chemical and toxicological characterization of the diesel particulate matter (PM) emitted from diesel vehicles running on a chassis dynamometer under different driving conditions. Chemical analyses were performed to characterize the contents of organic carbon (OC), elemental carbon (EC), and 31 polycyclic aromatic hydrocarbons (PAHs) in the collected PM samples. The OC-EC analysis results revealed that PM emissions from diesel vehicles in this study were dominated by OC and that the emission of vehicles equipped with diesel particulate filters had high OC/EC ratios.

Practices of Strength and Conditioning Coaches: A Snapshot From Different Sports, Countries, and Expertise Levels.

Weldon, A, Duncan, MJ, Turner, A, LaPlaca, D, Sampaio, J, and Christie, CJ. Practices of strength and conditioning coaches: a snapshot from different sports, countries, and expertise levels. J Strength Cond Res 36(5): 1335-1344, 2022-This study describes the practices of strength and conditioning coaches (SCCs) from different sports, countries, and expertise levels.

Statistical evaluation of on-road vehicle emissions measurement using a dual remote sensing technique.

On-road remote sensing (RS) is a rapid, non-intrusive and economical tool to monitor and control the emissions of in-use vehicles, and currently is gaining popularity globally. However, a majority of studies used a single RS technique, which may bias the measurements since RS only captures a snapshot of vehicle emissions. This study aimed to use a unique dual RS technique to assess the characteristics of on-road vehicle emissions.

Intraday reliability, sensitivity, and minimum detectable change of national physical fitness measurement for preschool children in China.

China General Administration of Sport has published and adopted the National Physical Fitness Measurement (NPFM-preschool children version) since 2000. However, studies on intraday reliability, sensitivity, and minimum detectable change (MDC) are lacking. This study aimed to investigate and compare the reliability, sensitivity, and MDC values of NPFM in preschool children between the ages of 3.

Hyperthermia-Induced Controlled Local Anesthesia Administration Using Gelatin-Coated Iron-Gold Alloy Nanoparticles.

The lack of optimal methods employing nanoparticles to administer local anesthesia often results in posing severe risks such as non-biocompatibility, in vivo cytotoxicity, and drug overdose to patients. Here, we employed magnetic field-induced hyperthermia to achieve localized anesthesia. We synthesized iron-gold alloy nanoparticles (FeAu Nps), conjugated an anesthetic drug, Lidocaine, and coated the product with gelatin to increase the biocompatibility, resulting in a FeAu@Gelatin-Lidocaine nano-complex formation.

Physical fitness improvements of 8-week light vs. heavy tyre flip training in young adults.

This study compared the effects of eight-week tyre flipping training intervention using light and heavy tyres on physical fitness performance. Twenty-nine young physically active males were divided into light (n = 15) and heavy (n = 14) tyre flipping groups evenly according to body weight and height. Body-to-tyre weight ratios were 0.

Promoting Physical Activity in Group Home Settings: Staff Perspectives through a SWOT Analysis.

Purpose: The aim of the study was to investigate perceptions of staff about the promotion of physical activity (PA) in selected group residences of Hong Kong (HK), some of which had experienced a multi-component PA program.

Method: Focus group interviews with nineteen staff members from four group homes (two of which received the program) were conducted.

Findings: A SWOT analysis provided important insights into residential staff views about key influences on the quality of PA programs for residents with intellectual disabilities (ID).

A Rapid, Simple, Inexpensive, and Mobile Colorimetric Assay COVID-19-LAMP for Mass On-Site Screening of COVID-19.

To control the COVID-19 pandemic and prevent its resurgence in areas preparing for a return of economic activities, a method for a rapid, simple, and inexpensive point-of-care diagnosis and mass screening is urgently needed. We developed and evaluated a one-step colorimetric reverse-transcriptional loop-mediated isothermal amplification assay (COVID-19-LAMP) for detection of SARS-CoV-2, using SARS-CoV-2 isolate and respiratory samples from patients with COVID-19 ( = 223) and other respiratory virus infections ( = 143). The assay involves simple equipment and techniques and low cost, without the need for expensive qPCR machines, and the result, indicated by color change, is easily interpreted by naked eyes.

Effects of knee flexion angles in supine bridge exercise on trunk and pelvic muscle activity.

This study investigated the activity of surface electromyography (sEMG) on trunk and pelvic muscles during supine bridge exercise (SBE) with different knee flexion angles. Twenty-five physically active males participated in this study. Subjects received maximum voluntary isometric contraction (MVIC) tests followed by four SBEs with different knee flexion angles (40°, 60°, 90° and 120°) in random.

Evaluating in-use vehicle emissions using air quality monitoring stations and on-road remote sensing systems.

This study investigated real world in-use vehicle emissions using two regulatory techniques simultaneously, namely on-road remote sensing (RS) systems and air quality (AQ) monitoring stations, aiming to provide a full pollution profile from tailpipe to roadside and atmosphere. Two large AQ and RS datasets collected during 2012-2018 were analyzed. The effects of various emission control programmes on the trends of tailpipe emissions and air quality were evaluated.

Engineering and optimization of phosphate-responsive phytase expression in Pichia pastoris yeast for phytate hydrolysis.

Phytate is the major storage form of phosphorus in plants. It is present in cereals and raw materials of vegetable origin used in animal and human diets. However, non-ruminant animals have little phytase activity in their guts and, therefore, cannot digest phytate.

Techno-economic evaluation of a biorefinery applying food waste for sophorolipid production - A case study for Hong Kong.

This study evaluates the techno-economic feasibility of sophorolipid (SL) production process that co-utilizes food waste, glucose and oleic acid as substrates. Two variables are considered in terms of (a) Plant construction: Purchasing equipment either from the US or Mainland China and (b) Production: to produce SL crystals (about 97% active) or a concentrated SL liquid/syrup (about 78% active). Hence, four scenarios are generated: Scenario I: equipment made in the USA + SL crystals; Scenario II: equipment made in the USA + SL syrup; Scenario III: equipment made in China + SL crystals; Scenario IV: equipment made in China + SL syrup.