Removing 65 Years of Approximation in Rotating Ring Disk Electrode Theory with Physics-Informed Neural Networks.

The rotating Ring Disk Electrode (RRDE), since its introduction in 1959 by Frumkin and Nekrasov, has become indispensable with diverse applications in electrochemistry, catalysis, and material science. The collection efficiency () is an important parameter extracted from the ring and disk currents of the RRDE, providing valuable information about reaction mechanism, kinetics, and pathways. The theoretical prediction of is a challenging task: requiring solution of the complete convective diffusion mass transport equation with complex velocity profiles.

POF-based biosensors for cortisol detection in seawater as a tool for aquaculture systems.

A surface plasmon resonance (SPR) phenomenon implemented via D-shaped polymer optical fiber (POF) is exploited to realize cortisol biosensors. In this work, two immonosensors are designed and developed for the qualitative as well as quantitative measurement of cortisol in artificial and real samples. The performances of the POF-based biosensors in cortisol recognition are achieved using different functionalization protocols to make the same antibody receptor layer over the SPR surface via cysteamine and lipoic acid, achieving a limit of detection (LOD) of 0.

Pt Single Atoms on TiO Can Catalyze Water Oxidation in Photoelectrochemical Experiments.

Photoelectrochemical water splitting on n-type semiconductors is highly dependent on catalysis of the rate-determining reaction of O evolution. Conventionally, in electrochemistry and photoelectrochemistry O evolution is catalyzed by metal oxide catalysts like IrO and RuO, whereas noble metals such as Pt are considered unsuitable for this purpose. However, our study finds that Pt, in its single-atom form, exhibits exceptional cocatalytic properties for photoelectrochemical water oxidation on a TiO photoanode, in contrast to Pt in a nanoparticle form.

Improving the operational durability of tangential-rotary picks for rock cutting with central spraying and hydrodynamic rotation.

This article presents a proposal for a new solution of tangential-rotary picks intended for mining, especially hard rocks with roadheaders. The design of these picks is characterized by many innovative solutions aimed at significantly increasing their service life. The method to achieve this goal is to provide effective central spraying of the ring tip picks, crown picks, or similar types of picks while using the spray water to cause the picks to rotate as they contact the rock being mined.

Addressing docking pose selection with structure-based deep learning: Recent advances, challenges and opportunities.

Molecular docking is a widely used technique in drug discovery to predict the binding mode of a given ligand to its target. However, the identification of the near-native binding pose in docking experiments still represents a challenging task as the scoring functions currently employed by docking programs are parametrized to predict the binding affinity, and, therefore, they often fail to correctly identify the ligand native binding conformation. Selecting the correct binding mode is crucial to obtaining meaningful results and to conveniently optimizing new hit compounds.

A graph-theoretic approach to ring analysis: Dominant metric dimensions in zero-divisor graphs.

This article investigates the concept of dominant metric dimensions in zero divisor graphs (ZD-graphs) associated with rings. Consider a finite commutative ring with unity, denoted as , where nonzero elements and are identified as zero divisors if their product results in zero The set of zero divisors in ring is referred to as . To analyze various algebraic properties of , a graph known as the zero-divisor graph is constructed using This manuscript establishes specific general bounds for the dominant metric dimension (Ddim) concerning the ZD-graph of .

Designing a multi-objective energy management system in multiple interconnected water and power microgrids based on the MOPSO algorithm.

In this paper, a method of the energy management system (EMS) in multiple microgrids considering the constraints of power flow based on the three-objective optimization model is presented. The studied model specifications, the variable speed pumps in the water network as well and the storage tanks are optimally planned as flexible resources to reduce operating costs and pollution. The proposed method is implemented hierarchically through two primary and secondary control layers.

Optimizing AVR system performance via a novel cascaded RPIDD2-FOPI controller and QWGBO approach.

Maintaining stable voltage levels is essential for power systems' efficiency and reliability. Voltage fluctuations during load changes can lead to equipment damage and costly disruptions. Automatic voltage regulators (AVRs) are traditionally used to address this issue, regulating generator terminal voltage.

AggreProt: a web server for predicting and engineering aggregation prone regions in proteins.

Recombinant proteins play pivotal roles in numerous applications including industrial biocatalysts or therapeutics. Despite the recent progress in computational protein structure prediction, protein solubility and reduced aggregation propensity remain challenging attributes to design. Identification of aggregation-prone regions is essential for understanding misfolding diseases or designing efficient protein-based technologies, and as such has a great socio-economic impact.

Implementation of a Universal Framework Using Design Patterns for Application Development on Microcontrollers.

This article focuses on the area of software development for microcontrollers and details the implementation of modern programming practices and principles in embedded systems and IoT applications. This article explains how we implemented previously unimplemented principles and applied design patterns for quality software design on microcontrollers, which are currently only used for developing applications on the higher layers of the IoT reference model. A custom modular framework for microcontrollers is presented, based on applying SOLID principles and adapting design patterns specific to the microcontrollers' application development needs.

Influence of Imposed Strain on Weldability of Dievar Alloy.

The presented work is focused on the influence of imposed strain on the weldability of Dievar alloy. Two mechanisms affecting the microstructure and thus imparting changes in the mechanical properties were applied-heat treatment (hardening and tempering), and rotary swaging. The processed workpieces were further subjected to welding with various welding currents.

Charge carrier recombination processes, intragap defect states, and photoluminescence mechanisms in stoichiometric and reduced TiO brookite nanorods: an interpretation scheme through photoluminescence excitation spectroscopy in controlled environment.

The study of titanium dioxide (TiO) in the brookite phase is gaining popularity as evidence has shown the efficient photocatalytic performance of this less investigated polymorph. It has been recently reported that defective anisotropic brookite TiO nanorods display remarkable substrate-specific reactivity towards alcohol photoreforming, with rates of hydrogen production significantly (18-fold) higher than those exhibited by anatase TiO nanoparticles. To elucidate the basic photo-physical mechanisms and peculiarities leading to such an improvement in the photoactive efficiency, we investigated the recombination processes of photoexcited charge carriers in both stoichiometric and reduced brookite nanorods photoluminescence excitation spectroscopy in controlled environment.

Comparing Conventional Physician-Led Education with VR Education for Pacemaker Implantation: A Randomized Study.

Introduction: Education of patients prior to an invasive procedure is pivotal for good cooperation and knowledge retention. Virtual reality (VR) is a fast-developing technology that helps educate both medical professionals and patients.

Objective: To prove non-inferiority of VR education compared to conventional education in patients prior to the implantation of a permanent pacemaker (PPM).

Modeling a neurological disorder as the result of an operator acting on the brain: A first sketch based on network channel modeling.

The brain is a complex network, and diseases can alter its structures and connections between regions. Therefore, we can try to formalize the action of diseases by using operators acting on the brain network. Here, we propose a conceptual model of the brain, seen as a multilayer network, whose intra-lobe interactions are formalized as the diagonal blocks of an adjacency matrix.

Similarities and Differences of Hydridic and Protonic Hydrogen Bonding.

Ab initio calculations were employed to investigate the interactions between selected electron-donating groups, characterized by M-H bonds (where M represents a transition metal and H denotes a hydridic hydrogen), and electron-accepting groups featuring both σ- and π-holes. The study utilized the ωB97X-D3BJ/def2-TZVPPD level of theory. Hydridic hydrogen complexes were found in all complexes with σ- and π-holes.

Comparative study of photocatalysis with bulk and nanosheet graphitic carbon nitrides enhanced with silver.

The main goal of this research is to investigate the effectiveness of graphitic carbon nitride (g-CN, g-CN) in both bulk and nanosheet forms, which have been surface-modified with silver nanoparticles (Ag NPs), as photocatalysts for the degradation of acid orange 7 (AO7), a model dye. The photodegradation of AO7 dye molecules in water was used to test the potential photocatalytic properties of these powder materials under two different lamps with wavelengths of 368 nm (UV light) and 420 nm (VIS light). To produce Ag NPs (Ag content 0.

A statistical framework for a new Kavya-Manoharan Bilal distribution using ranked set sampling and simple random sampling.

In survival and stochastic lifespan modeling, numerous families of distributions are sometimes considered unnatural, unjustifiable theoretically, and occasionally superfluous. Here, a novel parsimonious survival model is developed using the Bilal distribution (BD) and the Kavya-Manoharan (KM) parsimonious transformation family. In addition to other analytical properties, the forms of probability density function (PDF) and behavior of the distributions' hazard rates are analyzed.

Silver-loaded poly(vinyl alcohol)/polycaprolactone polymer scaffold as a biocompatible antibacterial system.

A chronic nonhealing wound poses a significant risk for infection and subsequent health complications, potentially endangering the patient's well-being. Therefore, effective wound dressings must meet several crucial criteria, including: (1) eliminating bacterial pathogen growth within the wound, (2) forming a barrier against airborne microbes, (3) promoting cell proliferation, (4) facilitating tissue repair. In this study, we synthesized 8 ± 3 nm Ag NP with maleic acid and incorporated them into an electrospun polycaprolactone (PCL) matrix with 1.

Hybrid optimal-FOPID based UPQC for reducing harmonics and compensate load power in renewable energy sources grid connected system.

Integration of renewable energy sources (RES) to the grid in today's electrical system is being encouraged to meet the increase in demand of electrical power and also overcome the environmental related problems by reducing the usage of fossil fuels. Power Quality (PQ) is a critical problem that could have an effect on utilities and consumers. PQ issues in the modern electric power system were turned on by a linkage of RES, smart grid technologies and widespread usage of power electronics equipment.

Magnetic Microrobot Swarms with Polymeric Hands Catching Bacteria and Microplastics in Water.

The forefront of micro- and nanorobot research involves the development of smart swimming micromachines emulating the complexity of natural systems, such as the swarming and collective behaviors typically observed in animals and microorganisms, for efficient task execution. This study introduces magnetically controlled microrobots that possess polymeric sequestrant "hands" decorating a magnetic core. Under the influence of external magnetic fields, the functionalized magnetic beads dynamically self-assemble from individual microparticles into well-defined rotating planes of diverse dimensions, allowing modulation of their propulsion speed, and exhibiting a collective motion.

Straw pyrolysis for use in electricity storage installations.

A concept has been proposed for an installation designed to store excess electricity periodically occurring on the grid. Excess electricity will be used for straw pyrolysis. The main pyrolysis product, gas, will be used to generate electricity using a combustion generator to feed back power into the grid during periods of shortage.

Controlling On-Surface Photoactivity: The Impact of π-Conjugation in Anhydride-Functionalized Molecules on a Semiconductor Surface.

On-surface synthesis has become a prominent method for growing low-dimensional carbon-based nanomaterials on metal surfaces. However, the necessity of decoupling organic nanostructures from metal substrates to exploit their properties requires either transfer methods or new strategies to perform reactions directly on inert surfaces. The use of on-surface light-induced reactions directly on semiconductor/insulating surfaces represents an alternative approach to address these challenges.