Exploitation of a New Nucleating Agent by Molecular Structure Modification of Aryl Phosphate and Its Effect on Application Properties of the Polypropylene.

In this work, a novel α-nucleating agent (NA) for polypropylene (PP) termed APAl-3C-12Li was prepared and evaluated compared with the commercially available type NA-21. For the synthesis of the organophosphate-type NA (APAl-3C), the -OH group of the acid part of NA-21 was substituted by the isopropoxy group. The structure of APAl-3C was analyzed by spectroscopy and element analysis, the results of which were consistent with the theoretical molecular formula.

Boss, Can't You Hear Me? The Impact Mechanism of Supervisor Phone Snubbing (Phubbing) on Employee Psychological Withdrawal Behavior.

With the excessive smartphone use in the workplace, supervisor phubbing has drawn broad concerns in managerial and academic fields. Though the neglect is unintentional, this behavior can generate counterproductive working behaviors. The basic assumptions of this study are that supervisor phubbing can impact employee psychological withdrawal behavior directly and indirectly via work alienation.

Dynamic perturbation analysis of fractional order differential quasiperiodic Mathieu equation.

The paper investigates the influence of parameters on the stability of fractional order differential quasiperiodic Mathieu equations. First, we use the perturbation method to obtain approximate expressions (i.e.

Nutrient-rich hydrothermal carbon production by exogenous nutrients combined with seaweed internal water.

As a product of hydrothermal carbonization (HTC) technology, hydrothermal carbon has shown excellent application potential in soil improvement, greenhouse gas reduction and pollution remediation. Since a large amount of water and biomass are directly used as reaction media, hydrothermal carbon produced by traditional HTC possesses poor nutrient properties and accompanied by the generation of toxic and hazardous wastewater. Here, a versatile and easily scalable strategy has been demonstrated for the one-step production of industrial nutrient-rich hydrothermal carbon (NRHC) by combining the exogenous nutrients with seaweed internal water.

Effects of Pore-Crack Relative Location on Crack Propagation in Porous Granite Based on the Phase-Field Regularized Cohesion Model.

This study employs the phase-field regularized cohesion model (PF-CZM) to simulate crack propagation and damage behavior in porous granite. The impact of the pore radius (r), initial crack-pore distance (D), and pore-crack angle (θ) on crack propagation is investigated. The simulation findings reveal that, with a fixed deflection angle and initial crack-pore distance, larger pores are more likely to induce crack extension under identical loading conditions.

An overview of green synthesized silver nanoparticles towards bioactive antibacterial, antimicrobial and antifungal applications.

Present review emphatically introduces the synthesis, biocompatibility, and applications of silver nanoparticles (AgNPs), including their antibacterial, antimicrobial, and antifungal properties. A comprehensive discussion of various synthesis methods for AgNPs, with a particular focus on green chemistry mediated by plant extracts has been made. Recent research has revealed that the optical properties of AgNPs, including surface plasmon resonance (SPR), depend on the particle size, as well as the synthesis methods, preparation synthesis parameters, and used reducing agents.

An Overview of Metal-Organic Framework Based Electrocatalysts: Design and Synthesis for Electrochemical Hydrogen Evolution, Oxygen Evolution, and Carbon Dioxide Reduction Reactions.

Due to the increasing global energy demands, scarce fossil fuel supplies, and environmental issues, the pursued goals of energy technologies are being sustainable, more efficient, accessible, and produce near zero greenhouse gas emissions. Electrochemical water splitting is considered as a highly viable and eco-friendly energy technology. Further, electrochemical carbon dioxide (CO ) reduction reaction (CO RR) is a cleaner strategy for CO utilization and conversion to stable energy (fuels).

Phyllostachys nigra (Lodd. ex Lindl.) derived polysaccharide with enhanced glycolipid metabolism regulation and mice gut microbiome.

This study focuses on the characterization and regulation of glycolipid metabolism of polysaccharides derived from biomass of Phyllostachys nigra (Lodd. ex Lindl.) root (PNr).

MXene Enhanced 3D Needled Waste Denim Felt for High-Performance Flexible Supercapacitors.

MXene, a transition metal carbide/nitride, has been prominent as an ideal electrochemical active material for supercapacitors. However, the low MXene load limits its practical applications. As environmental concerns and sustainable development become more widely recognized, it is necessary to explore a greener and cleaner technology to recycle textile by-products such as cotton.

Exploring the potential of a novel alternating current stimulated iron‑carbon anammox process: A new horizon for nitrogen removal.

This study explored a novel alternating current (AC) stimulation approach to enhance the nitrogen removal efficiency of an iron‑carbon based anammox (FeC anammox) system. In the preliminary experiment, the TN removal efficiency of the AC stimulated system was 8.06 % higher than that of a DC simulated system in same current densities of 0.

Multifunctional Multigate One-Transistor with Thin Advanced Materials, Logic-in-Memory, and Artificial Synaptic Behaviors.

The high device density and fabrication complexity have hampered the development of the electronics. The advanced designs, which could implement the functions of the circuits with higher device density but less fabrication complexity, are hence required. Meanwhile, the MoS-based devices have recently attracted considerable attention owing to their advantages such as the ultrathin thickness.

Zn-Leaching Induced Rapid Self-Reconstruction of NiFe-Layered Double Hydroxides for Boosted Oxygen Evolution Reaction.

Optimizing the active centers through reconstruction is recognized as the key to construct high-performance oxygen evolution reaction (OER) catalysts. Herein, a simple and rapid in situ leaching strategy to promote the self-reconstruction of NiFe-layered double hydroxides (LDHs) catalysts is reported. The trace Zn dopants are introduced in advance by a facile and one-step hydrothermal method, followed by leaching over the electrochemical activation process, which can remarkably reduce the formation potential of NiFeOOH active centers to enable the deeper self-reconstruction for the formation of abundant highly active centers.

Internal and External Pipe Defect Characterization via High-Frequency Lamb Waves Generated by Unidirectional EMAT.

Periodic permanent magnet(PPM) electromagnetic acoustic transducers (EMATs) are commonly employed for axial defect inspection in pipelines. However, the lowest-order shear horizontal waves (SH0) guided waves have difficulties in distinctly differentiating internal and external defects. To enhance the signal-to-noise ratio and resolution, a unidirectional electromagnetic acoustic transducer (EMAT) based on Circumferential Lamb waves (CLamb waves) is developed.

Mechanical properties and osteogenesis of CFR-PEEK composite with interface strengthening by graphene oxide for implant application.

In this work, 1 wt% of graphite oxide (GO) was used to strengthen the interface of carbon fibers (CF) reinforced polyetheretherketone (CFR-PEEK) composites, so as to obtain sufficiently high mechanical properties and bioactive surfaces which are two fundamental requirements for orthopedic/dental implants. Concretely, aminated GO was grafted onto oxidized CF in aqueous solution in a mild and non-toxic manner, subsequently, the CF grafted by GO was used for injection molding to prepare CFR-PEEK implant. The dispersibility of CF in the composites were remarkably boosted.

Disturbance mitigation of thiencarbazone-methyl·isoxaflutole on bacterial communities through nitrification inhibitor and attapulgite.

There is a knowledge gap in the interaction between the effects of herbicide thiencarbazone-methyl·isoxaflutole on soil microflora and environmental parameters, which leads to a lack of measures in mitigating damage to bacterial communities from the herbicide use. The impacts of thiencarbazone-methyl·isoxaflutole and soil parameters on the diversity, structure and functions of soil bacterial communities were clarified, and the effects and potential mitigation mechanisms of nitrapyrin and modified attapulgite with bacterial function intervention on bacterial communities were explored through incubation and field experiments. The results showed that as thiencarbazone-methyl·isoxaflutole application increased, the stress on soil bacterial community structure and diversity also increased.

An efficient CuZr-based metallic glasses electrode material for electrocatalytic degradation of azo dyes.

Metallic glasses have received a lot of attention on wastewater treatment due to their unique atomic structure, and the use of metallic glasses as electrodes has produced unexpected electrocatalytic degradation effects for many pollutants through combining with electrochemical technology. However, it still is a formidable challenge to find a metallic glass electrode material with both efficient and clean for the catalytic degradation of pollutants. In this work, the CuZr metallic glassy ribbons are used as an electrode to degrade azo dyes and show the excellent degradation effect, which can reach 95.

Application of an improved whale optimization algorithm in time-optimal trajectory planning for manipulators.

To address the issues of unstable, non-uniform and inefficient motion trajectories in traditional manipulator systems, this paper proposes an improved whale optimization algorithm for time-optimal trajectory planning. First, an inertia weight factor is introduced into the surrounding prey and bubble-net attack formulas of the whale optimization algorithm. The value is controlled using reinforcement learning techniques to enhance the global search capability of the algorithm.

Effect of Heat Treatment Processes on the Microstructure and Mechanical Properties of High-Strength Aluminum Alloy Deposited Layers Processed by Fused Arc Additive Manufacturing.

In this study, 7075 aluminum alloy welding wire with TiB nanoparticle reinforcement as an additive together with the variable polarity TIG welding arc as a heat source were applied to produce thin-walled deposited layer samples. Results indicated that the performance of the deposited structure of 7075 aluminum alloy with a TiB reinforcement phase was significantly improved compared to the deposited structure of ordinary 7075 aluminum alloy welding wire. Meanwhile, the precipitation of the TiB reinforcement phase was insufficient within the structure, and the enhancing effect could not be fully exerted.

Surface Activity, Wetting, and Aggregation of a Perfluoropolyether Quaternary Ammonium Salt Surfactant with a Hydroxyethyl Group.

This paper reports the synthesis of a novel quaternary surfactant containing a hydroxyethyl group (PFPE-C) and the surface properties of its aqueous solution (investigated by comparisons with two structurally similar chemicals, dodecyl-(2-hydroxyethyl)-dimethylammonium chloride (DHDAC) and PFPE-A). The minimum surface tension (γCMC) and critical micelle concentration (CMC) of the PFPE-C aqueous solution were 17.35 mN/m and 0.

Exfoliable and self-healable two-dimensional materials from wurtzite zinc chalcogenides as building blocks of nanodevices.

With the advent of graphene, two-dimensional (2D) materials have emerged as promising candidates for next-generation electronic and optoelectronic applications. The most anticipated 2D materials have been synthesized and exploited for novel applications. Multilayered zinc chalcogenides (ZnX) are the best precursors for obtaining atomic layer two-dimensional materials by exfoliation.

Protective role of metformin in preeclampsia via the regulation of NF-κB/sFlt-1 and Nrf2/HO-1 signaling pathways by activating AMPK.

Introduction: Preeclampsia (PE) is a pregnancy complication that leads to hypertension and proteinuria and causes maternal mortality. Metformin (MET) is an oral hypoglycemic agent that activates AMPK-regulated signaling pathways and inhibits inflammation and oxidative stress responses. This study explored MET's roles and molecular mechanisms in PE.

Development of a novel reciprocating cryogenic tribometer through deformations of measurement structure.

In this study, a novel reciprocating tribometer, in which the frictional pairs were immersed in liquid nitrogen directly, was developed to simulate the cryogenic fluid lubrication. To eliminate the negative influence of extremely low temperature on force sensors, a transfer structure of force-deformation, consisting of cantilever beams and measurement beams, was designed specially. It can transfer the structural deformations caused by the loading force and the friction force from the cryogenic zone to the room-temperature zone.

Constructing a carboxyl-rich angstrom-level trap in a metal-organic framework for the selective capture of lithium.

A metal-organic-framework-based ion trap was designed tailoring linker functionality as well as free -COOH density. The mixed-linker UiO-66-H/H exhibits higher adsorption for Li ions than H-free UiO-66-H because the H linker provides an additional -COOH group in the local region.

A Coin-Sized Oxygen Laser Sensor Based on Tunable Diode Laser Absorption Spectroscopy Combining a Toroidal Absorption Cell.

Laser gas sensors with small volume and light weight are in high demand in the aerospace industry. To address this, a coin-sized oxygen (O) sensor has been successfully developed based on a small toroidal absorption cell design. The absorption cell integrates a vertical-cavity surface-emitting laser (VCSEL) and photodetector into a compact unit, measuring 90 × 40 × 20 mm and weighing 75.