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Highly-efficient red-to-yellow/green upconversion sensitized by phthalocyanine palladium with high triplet energy-level.
RSC Adv
May 2021
Suzhou Key Laboratory of Flexible & Printing Optoelectronic Materials, School of Materials Science and Engineering, Suzhou University of Science and Technology Suzhou 215009 China
Soluble 3,7,11,15-tetra(-butyl)phthalocyanine palladium (TBPcPd) and 3,7,11,15-tetra(pentyloxy)phthalocyanine palladium (POPcPd) were synthesized and employed as sensitizers in expectation of achieving red-to-yellow/green upconversion (UC), doped with rubrene (Rub) and 9,10-bis(phenylethynyl)anthracene (BPEA), respectively. Under excitation of a 655 nm diode laser (∼1.5 W cm), a maximum red-to-green UC efficiency of 0.
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