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Flexible anode materials for lithium-ion batteries derived from waste biomass-based carbon nanofibers: I. Effect of carbonization temperature.

RSC Adv

February 2018

Yunnan Provincial International Joint Research Center for Bioenergy, Yunnan Provincial Engineering Laboratory for Highly-Efficient Utilization of Biomass, Yunnan Provincial University Key Laboratory for Biomass Chemical Refinery & Synthesis, College of Materials Science & Engineering, Southwest Forestry University Kunming 650224 China +86 13700641767 +86 18787044383.

Carbon nanofibers (CNFs) with excellent electrochemical performance represent a novel class of carbon nanostructures for boosting electrochemical applications, especially sustainable electrochemical energy conversion and storage applications. This work builds on an earlier study where the CNFs were prepared from a waste biomass (walnut shells) using a relatively simple procedure of liquefying the biomass, and electrospinning and carbonizing the fibrils. We further improved the mass ratio of the liquefying process and investigated the effects of the high temperature carbonization process at 1000, 1500 and 2000 °C, and comprehensively characterized the morphology, structural properties, and specific surface area of walnut shell-derived CNFs; and their electrochemical performance was also investigated as electrode materials in Li-ion batteries.

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