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Correction: Second-shell modulation on porphyrin-like Pt single atom catalysts for boosting oxygen reduction reaction.

Chem Sci

November 2024

Shenzhen Key Laboratory of Micro/Nano-Porous Functional Materials (SKLPM), SUSTech-Kyoto University Advanced Energy Materials Joint Innovation Laboratory (SKAEM-JIL), Department of Chemistry and Department of Materials Science and Engineering, Southern University of Science and Technology (SUSTech) Shenzhen 518055 China

Article Synopsis
  • This text is a correction to a previously published article identified by the DOI: 10.1039/D4SC03369H.
  • The correction likely addresses errors or inaccuracies found in the original article.
  • The purpose is to ensure that the scientific record is accurate and reflects the correct information. *
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Second-shell modulation on porphyrin-like Pt single atom catalysts for boosting oxygen reduction reaction.

Chem Sci

October 2024

Shenzhen Key Laboratory of Micro/Nano-Porous Functional Materials (SKLPM), SUSTech-Kyoto University Advanced Energy Materials Joint Innovation Laboratory (SKAEM-JIL), Department of Chemistry and Department of Materials Science and Engineering, Southern University of Science and Technology (SUSTech) Shenzhen 518055 China

The first coordination shell is considered crucial in determining the performance of single atom catalysts (SACs), but the significance of the second coordination shell has been overlooked. In this study, we developed a post-doping strategy to realize predictable and controlled modulation on the second coordination shell. By incorporating a P atom into the second coordination shell of a porphyrin-like Pt SAC, the charge density at the Fermi level of Pt single atom increases, enhancing its intrinsic activity.

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