2 results match your criteria: "Southeast University Nanjing 211189 China zhangwen@seu.edu.cn.[Affiliation]"

A three-dimensional lead iodide perovskite analog featuring hydrogen-bonded dual monovalent cations.

Chem Sci

October 2024

Jiangsu Key Laboratory for Science and Applications of Molecular Ferroelectrics, School of Chemistry and Chemical Engineering, Southeast University Nanjing 211189 China

Three-dimensional (3D) halide perovskites have attracted considerable research interest, yet the selection of A-site cations is restricted by the Goldschmidt tolerance factor. To accommodate cations beyond this acceptable range, novel 3D perovskite analog structures with edge- and face-sharing motifs have been developed. Until now, these structures have been limited to divalent cations due to significant electrostatic repulsion when incorporating two monovalent cations.

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Chiral three-dimensional organic-inorganic lead iodide hybrid semiconductors.

Chem Sci

July 2024

Jiangsu Key Laboratory for Science and Applications of Molecular Ferroelectrics, School of Chemistry and Chemical Engineering, Southeast University Nanjing 211189 China

Article Synopsis
  • Chiral hybrid metal halides (CHMHs) are gaining attention for their excellent optoelectronic properties and flexibility, making them promising for applications in chiroptoelectronics, spintronics, and ferroelectrics.
  • Previous attempts to synthesize stable chiral 3D structures, specifically CHFClNHPbI, at room temperature had been unsuccessful, limiting the study of their properties.
  • This study successfully created two types of chiral lead iodide hybrids and demonstrated their unique optical activity and bulk photovoltaic effects, showcasing their potential in developing advanced chiral electronic devices.
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