Numerical Simulation of CO Dissolution and Mineralization Storage Considering CO-Water-Rock Reaction in Aquifers.

CO storage technology is crucial in addressing climate change by controlling the greenhouse effect. This technology involves the injection of captured CO into deep saline aquifers, where it undergoes a series of reactions, such as structure binding, dissolution, and mineralization, enabling long-term storage. Typically, the CO is maintained in a supercritical state, enhancing its storage efficiency.

A turn-on AIE dual-channel fluorescent probe for sensing Cr/ClO and application in cell imaging.

A Cr/ClO-enhanced fluorescent probe, DNS (5-(dimethylamino)-N'-(2-hydroxy-4,6-dimethoxybenzylidene)-naphthalene-1-sulfonyl hydrazide), with aggregation-induced emission (AIE) properties was synthesized using dansylhydrazide and 4,6-dimethoxysalicylaldehyde as starting materials. The probe rapidly and selectively detects Cr and ClO in a solvent system of HO/DMSO (2:8). Upon binding with Cr/ClO, the probe exhibits a significant fluorescence enhancement, with minimal interference from other ions.

Research of neural network-based model for nonlinear temperature drift compensation of MEMS accelerometers.

Downhole instrumentation requires more and more accuracy of MEMS inertial sensors. However, in measurement while drilling, temperature drift phenomenon of the sensor will have a cumulative impact on the drill pipe attitude solution. After experimental testing, the output response of the accelerometer had strong local linear and global nonlinear characteristics.

Balancing the Charge Separation and Surface Reaction Dynamics in Twin-Interface Photocatalysts for Solar-to-Hydrogen Production.

Solar-driven photocatalytic green hydrogen (H) evolution reaction presents a promising route toward solar-to-chemical fuel conversion. However, its efficiency has been hindered by the desynchronization of fast photogenerated charge carriers and slow surface reaction kinetics. This work introduces a paradigm shift in photocatalyst design by focusing on the synchronization of charge transport and surface reactions through the use of twin structures as a unique platform.

pH-Responsive Natural Deep Eutectic Solvent: An Environmental Alternative for the Sustainable Extraction of Petroleum Hydrocarbons from Oil Sands.

The reversible shift in polarity or hydrophilicity/hydrophobicity of switchable solvents greatly simplifies the recovery capacity in extraction applications. However, the environmental and economical advantages of switchable solvents are not significant. In this work, we designed three pH-responsive natural deep eutectic solvents (NADESs) by combining the pH-switchable solvent fatty acids with the nonswitchable solvent ethyl lactate (EL), followed by the exploration of the solubilization and separation performance of these NADESs for petroleum hydrocarbons.

Transition Metals Doped into g-CN via N,O Coordination as Efficient Electrocatalysts for the Carbon Dioxide Reduction Reaction.

The electrochemical carbon dioxide reduction reaction (CORR) is a potential and efficient method that can directly convert CO into high-value-added chemicals under mild conditions. Owing to the exceptionally high activation barriers of CO, catalysts play a pivotal role in CORR. In this study, the transition metal (TM = Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, and Zn) is doped into g-CN with a unique N,O-coordination environment, namely, TM-NO/g-CN.

Enhanced Efficiency and Intrinsic Stability of Wide-Bandgap Perovskite Solar Cells Through Dimethylamine-Based Cation Engineering.

High efficiency and stable wide-bandgap (WBG) perovskite solar cells (PSCs) are crucial for the development of perovskite-based tandem solar cells. However, the efficiency and stability of WBG PSCs are compromised by significant phase segregation and surface defects. In this study, we introduce a cation engineering strategy for WBG perovskite, employing a two-step sequential method that incorporates dimethylamine hydroiodide (DMAI) into the lead halide complex during the initial step.

A deep learning-based method for assessing tricuspid regurgitation using continuous wave Doppler spectra.

Transthoracic echocardiography (TTE) is widely recognized as one of the principal modalities for diagnosing tricuspid regurgitation (TR). The diagnostic procedures associated with conventional methods are intricate and labor-intensive, with human errors leading to measurement variability, with outcomes critically dependent on the operators' diagnostic expertise. In this study, we present an innovative assessment methodology for evaluating TR severity utilizing an end-to-end deep learning system.

Study on the Impact of Porous Media on Condensate Gas Depletion: A Case Study of Reservoir in Xihu Sag.

During the depletion and pressure reduction process in condensate gas reservoirs, the precipitation of condensate oil transforms the single-phase gas flow into a two-phase gas-liquid flow, significantly reducing the permeability. Currently, microscopic studies of the phase behavior of condensate gas in porous media mainly focus on observing and describing the occurrence of condensate oil, lacking quantitative calculations and direct observations of condensate oil throughout the entire depletion cycle. This paper uses a microvisualization method to simulate the depletion process of condensate gas reservoirs.

Optimizing the low-temperature performance of high-wax-content crude oil with emulsion-based wax inhibitors: Mechanisms and efficacy.

Wax deposition in constant-temperature transportation of waxy oil with high pour points poses a significant challenge for the oil industry. The demand for efficient methods to solve wax deposition has gained attention. To elucidate the impact of emulsion-based wax inhibitors on the performance of crude oils with varying wax content at low temperatures, experiments, rheological analyses, and microscopic analyses were conducted to study their pour point regulation, low-temperature flow improvement, wax prevention effectiveness, and wax crystallization behavior.

Identification and hazard prioritization of hydrophobic organic chemicals in flowback and produced water particles: Implications for water management.

Hydraulic fracturing flowback and produced water (HF-FPW) has raised significant concerns owing to its potential impact on aquatic organisms and human health. Understanding the chemical composition of HF-FPW is crucial for developing appropriate management and remediation strategies. Herein, we performed nontarget screening on hydrophobic organic chemicals in the particulate phase of FPW (P-FPW) using gas chromatography-Orbitrap mass spectrometry coupled with cheminformatic analysis.

Analysis and application of low frequency shadows based on the asymptotic theory for porous media.

Low-frequency shadows beneath gas reservoirs can be regarded as a time delay relative to the reflection from the reservoir zone, but they cannot be reasonably explained by the high-frequency attenuation or velocity dispersion observed in normal P-waves. According to the new asymptotic theory for porous media, seismic P-waves undergo multiple conversions between fast and slow modes during seismic waves passing through layered permeable reservoirs at low frequencies, and changes in the velocity and amplitude (i.e.

Research and Evaluation of a Nanometer Plugging Agent for Shale Gas Horizontal Wells.

Due to the low permeability of shales, drilling fluid filtrate is very likely to intrude into the formation along the nanomicron pore joints of shale, leading to microfracture expansion and causing a well wall destabilization phenomenon. Based on the characteristics of the formation shale, a new nano plugging agent, styrene (St)/2-acrylamido-2-methylpropanesulfonic acid (AMPS)/ethyl acrylate (EA), was synthesized by emulsion polymerization using St, EA, and AMPS as reaction monomers. The analysis results using infrared spectroscopy and transmission electron microscopy showed that the product met the expected design.

Understanding of Wetting Mechanism Toward the Sticky Powder and Machine Learning in Predicting Granule Size Distribution Under High Shear Wet Granulation.

The granulation of traditional Chinese medicine (TCM) has attracted widespread attention, there is limited research on the high shear wet granulation (HSWG) and wetting mechanisms of sticky TCM powders, which profoundly impact the granule size distribution (GSD). Here we investigate the wetting mechanism of binders and the influence of various parameters on the GSD of HSWG and establish a GSD prediction model. Permeability and contact angle experiments combined with molecular dynamics (MD) simulations were used to explore the wetting mechanism of hydroalcoholic solutions with TCM powder.

Efficient Nanofibrous Electromagnetic Wave Absorber Inspired by Spider Silk Hunting.

With the rapid advancements in wireless communication and radar detection technologies, there has been a significant uptick in the utilization frequency of electromagnetic waves across both civilian and military sectors, consequently generating substantial electromagnetic radiation and interference. These electromagnetic pollutants present a considerable threat to public health and information security. Consequently, materials capable of absorbing and mitigating electromagnetic pollution have garnered significant attention.

Reentrant Condensation of Polyelectrolytes Induced by Diluted Multivalent Salts: The Role of Electrostatic Gluonic Effects.

We explore the reentrant condensation of polyelectrolytes triggered by multivalent salts, whose phase-transition mechanism remains under debate. We propose a theory to study the reentrant condensation, which separates the electrostatic effect into two parts: a short-range electrostatic gluonic effect because of sharing of multivalent ions by ionic monomers and a long-range electrostatic correlation effect from all ions. The theory suggests that the electrostatic gluonic effect governs reentrant condensation, requiring a minimum coupling energy to initiate the phase transition.