Enabling Multicolor Information Encryption: Oleylammonium-Halide-Assisted Reversible Phase Conversion between CsPbX and CsPbX Nanocrystals.

Recently, halide perovskites have been recognized for their thermochromic characteristics, showing significant potential in information encryption applications. However, the limited luminescence color gamut hinders the encryption of complex multicolor information. Herein, for the first time, multicolor thermochromic perovskites with luminescence covering the entire visible spectrum have been designed.

Laser-Induced Nanostructured Si and SiGe Layers for Enhanced Optical and Thermoelectric Performance.

We investigate a method for fabricating layers that exhibit both high optical absorption and promising thermoelectric properties. Using plasma-enhanced chemical vapor deposition (PECVD), amorphous Si and SiGe layers are deposited on glass substrates and subsequently processed via laser annealing to achieve nanostructured layers. Our results show that a single laser annealing pulse at 40 mJ yields the highest power factor, approximately 90 μW/m·K.

Combining Simple Deformations to Elicit Complex Motions and Directed Swimming of Smart Organic Crystals with Controllable Thickness.

The lack of control over the crystal growth in a systematic way currently stands as an unsurmountable impediment to the preparation of dynamic crystals as soft robots; in effect, the mechanical effects of molecular crystals have become a subject of scattered reports that pertain only to specific crystal sizes and actuation conditions, often without the ability to establish or confirm systematic trends. One of the factors that prevents the verification of such performance is the unavailability of strategies for effectively controlling crystal size and aspect ratio, where crystals of serendipitous size are harvested from crystallization solution. Here we devised a water-assisted precipitation method to prepare crystals of chemical variants of 9-anthracene derivatives with various thicknesses that respond to ultraviolet light with simple mechanical effects, including bending, splintering, and rotation.

Efficient Aerial Water Harvesting with Self-Sensing Dynamic Janus Crystals.

Water scarcity is one of the most pressing issues of contemporary societal development that requires innovative technologies where the material not only harvests water but also plays an active role in the process. Here, we demonstrate a highly efficient optical self-sensing approach to humidity capture from the air, where both humidity-harvesting and water-transduction functionalities are imparted on slender organic crystals by partial silanization via layer-by-layer hybridization. We report that due to the integration of the harvesting of aerial moisture and the collection of the condensed water, the ensuing Janus-type crystals capture humidity with the highest-to-date water collection efficiency of 15.

Ferroelastic ionic organic crystals that self-heal to 95.

The realm of self-healing materials integrates chemical and physical mechanisms that prevent wear and fracturing and extend the operational lifetime. Unlike the favorable rheology of amorphous soft materials that facilitates efficient contact between fragments, the efficiency of recovery of atomistically ordered materials is restricted by slower interfacial mass transport and the need for ideal physical alignment, which limits their real-world application. We report drastic enhancements in efficiency and recovery time in the self-healing of anilinium bromide, challenging these limitations.

Exploratory risk prediction of type II diabetes with isolation forests and novel biomarkers.

Type II diabetes mellitus (T2DM) is a rising global health burden due to its rapidly increasing prevalence worldwide, and can result in serious complications. Therefore, it is of utmost importance to identify individuals at risk as early as possible to avoid long-term T2DM complications. In this study, we developed an interpretable machine learning model leveraging baseline levels of biomarkers of oxidative stress (OS), inflammation, and mitochondrial dysfunction (MD) for identifying individuals at risk of developing T2DM.

Ferroelastic Control of the Multicolor Emission from a Triply Doped Organic Crystal.

Emission from crystalline organic solids is often quenched by nonemissive energy-transfer deexcitation processes. While dispersion of fluorophores in polymers or other hosts has been used to enhance the emission intensity, this strategy results in randomization of guest orientation and optical losses at grain boundaries. Here, we report the doping of inherently nonemissive single crystals of anilinium bromide with three fluorescent organic molecules.

Highly efficient in crystallo energy transduction of light to work.

Various mechanical effects have been reported with molecular materials, yet organic crystals capable of multiple dynamic effects are rare, and at present, their performance is worse than some of the common actuators. Here, we report a confluence of different mechanical effects across three polymorphs of an organic crystal that can efficiently convert light into work. Upon photodimerization, acicular crystals of polymorph I display output work densities of about 0.

A Thermosalient and Mechanically Compliant Organic Crystalline Optical Waveguide Switcher.

The dense and ordered molecular arrangements endow dynamic molecular crystals with fast response, rapid energy conversion, low energy dissipation, and strong coupling between heat/light and mechanical energy. Most of the known dynamic crystals can only respond to a single stimulus, and materials that can respond to multiple stimuli are rare. Here, we report an organic crystalline material that can be bent plastically and is also thermosalient, as its crystals can move when they undergo a reversible phase transition.

Strategies to Diversification of the Mechanical Properties of Organic Crystals.

Structurally ordered soft materials that respond to complementary stimuli are susceptible to control over their spatial and temporal morphostructural configurations by intersectional or combined effects such as gating, feedback, shape-memory, or programming. In the absence of general and robust design and prediction strategies for their mechanical properties, at present, combined chemical and crystal engineering approaches could provide useful guidelines to identify effectors that determine both the magnitude and time of their response. Here, we capitalize on the purported ability of soft intermolecular interactions to instigate mechanical compliance by using halogenation to elicit both mechanical and photochemical activity of organic crystals.

Bending, Twisting, and Propulsion of Photoreactive Crystals by Controlled Gas Release.

The rapid release of gas by a chemical reaction to generate momentum is one of the most fundamental ways to elicit motion that could be used to sustain and control the motility of objects. We report that hollow crystals of a three-dimensional supramolecular metal complex that releases gas by photolysis can propel themselves or other objects and advance in space when suspended in mother solution. In needle-like regular crystals, the reaction occurs mainly on the surface and results in the formation of cracks that evolve due to internal pressure; the expansion on the cracked surface of the crystal results in bending, twisting, or coiling of the crystal.

Hybrid and composite materials of organic crystals.

Organic molecular crystals have historically been viewed as delicate and fragile materials. However, recent studies have revealed that many organic crystals, especially those with high aspect ratios, can display significant flexibility, elasticity, and shape adaptability. The discovery of mechanical compliance in organic crystals has recently enabled their integration with responsive polymers and other components to create novel hybrid and composite materials.

Flexible Organic Chiral Crystals with Thermal and Excitation Modulation of the Emission for Information Transmission, Writing, and Storage.

Organic single crystals quickly emerge as dense yet light and nearly defect-free media for emissive elements. Integration of functionalities and control over the emissive properties is currently being explored for a wide range of these materials to benchmark their performance against organic emissive materials diluted in powders or films. Here, we report mechanically flexible emissive chiral organic crystals capable of an unprecedented combination of fast, reversible, and low-fatigue responses.

Prediction of transportation index for urban patterns in small and medium-sized Indian cities using hybrid RidgeGAN model.

The rapid urbanization trend in most developing countries including India is creating a plethora of civic concerns such as loss of green space, degradation of environmental health, scarcity of clean water, rise in air pollution, and exacerbated traffic congestion resulting in significant delays in vehicular transportation. To address the intricate nature of transportation issues, many researchers and planners have analyzed the complexities of urban and regional road systems using transportation models by employing transportation indices such as road length, network density, accessibility, and connectivity metrics. This study addresses the complexities of predicting road network density for small and medium-sized Indian cities that come under the Integrated Development of Small and Medium Towns (IDSMT) project at a national level.

Woven organic crystals.

Woven architectures are prepared by physical entanglement of fibrous components to expand one-dimensional material into two-dimensional sheets with enhanced strength and resilience to wear. Here, we capitalize on the elastic properties of long organic crystals with a high aspect ratio to prepare an array of centimeter-size woven network structures. While being robust to mechanical impact, the woven patches are also elastic due to effective stress dissipation by the elasticity of the individual warp and weft crystals.

Harvesting of aerial humidity with natural hygroscopic salt excretions.

Plants and animals that thrive in arid regions utilize the diurnal changes in environmental temperature and humidity to optimize their water budget by combining water-harvesting mechanisms and morphophysiological traits. The Athel tamarisk () is a halophytic desert shrub that survives in arid, hypersaline conditions by excreting concentrated solutions of ions as droplets on its surface that crystallize into salt crystals and fall off the branches. Here, we describe the crystallization on the surface of the plant and explore the effects of external conditions such as diurnal changes in humidity and temperature.

A modified coronavirus herd immunity optimizer for capacitated vehicle routing problem.

Capacitated Vehicle routing problem is NP-hard scheduling problem in which the main concern is to find the best routes with minimum cost for a number of vehicles serving a number of scattered customers under some vehicle capacity constraint. Due to the complex nature of the capacitated vehicle routing problem, metaheuristic optimization algorithms are widely used for tackling this type of challenge. Coronavirus Herd Immunity Optimizer (CHIO) is a recent metaheuristic population-based algorithm that mimics the COVID-19 herd immunity treatment strategy.

Multi-Agent Variational Approach for Robotics: A Bio-Inspired Perspective.

This study proposes an adaptable, bio-inspired optimization algorithm for Multi-Agent Space Exploration. The recommended approach combines a parameterized Aquila Optimizer, a bio-inspired technology, with deterministic Multi-Agent Exploration. Stochastic factors are integrated into the Aquila Optimizer to enhance the algorithm's efficiency.

Inflammation, oxidative stress and mitochondrial dysfunction in the progression of type II diabetes mellitus with coexisting hypertension.

Introduction: Type II diabetes mellitus (T2DM) is a metabolic disorder that poses a serious health concern worldwide due to its rising prevalence. Hypertension (HT) is a frequent comorbidity of T2DM, with the co-occurrence of both conditions increasing the risk of diabetes-associated complications. Inflammation and oxidative stress (OS) have been identified as leading factors in the development and progression of both T2DM and HT.

Construction of Microporous Zincophilic Interface for Stable Zn Anode.

Aqueous zinc ion batteries (AZIBs) are promising electrochemical energy storage devices due to their high theoretical specific capacity, low cost, and environmental friendliness. However, uncontrolled dendrite growth poses a serious threat to the reversibility of Zn plating/stripping, which impacts the stability of batteries. Therefore, controlling the disordered dendrite growth remains a considerable challenge in the development of AZIBs.

Collective photothermal bending of flexible organic crystals modified with MXene-polymer multilayers as optical waveguide arrays.

The performance of any engineering material is naturally limited by its structure, and while each material suffers from one or multiple shortcomings when considered for a particular application, these can be potentially circumvented by hybridization with other materials. By combining organic crystals with MXenes as thermal absorbers and charged polymers as adhesive counter-ionic components, we propose a simple access to flexible hybrid organic crystal materials that have the ability to mechanically respond to infrared light. The ensuing hybrid organic crystals are durable, respond fast, and can be cycled between straight and deformed state repeatedly without fatigue.