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Spin crossover in a heptanuclear mixed-valence iron complex.
Dalton Trans
March 2010
Institute of Inorganic Chemistry, Slovak Technical University (FCHPT), SK-812 37, Bratislava, Slovakia.
The complex [Fe(II){(CN)Fe(III)L(5)}(6)]Cl(2) consists of a mixed-valence heptanuclear cyanide-bridged unit formed of a Schiff-base pentadentate ligand L(5) and it shows a spin crossover of the peripheral Fe(III) centres.
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