Analysis of the stereoselective fate and toxicity of penflufen in the water-sediment system for risk reduction.

Chiral succinate dehydrogenase inhibitor (SDHI) fungicides are widely used in agricultural production, but there is insufficient research on their environmental risk in water-sediment ecosystems. Here, the stereoselective fate and toxic effects of the chiral SDHI fungicide, penflufen, in the water-sediment system were investigated. The results showed that S-penflufen is more persistent in water, sediment, and zebrafish.

Research on regional ozone prevention and control strategies in eastern China based on pollutant transport network and FNR.

O pollution in China has worsened sharply in recent years, and O formation sensitivity (OFS) in many regions have gradually changed, with eastern China as the most typical region. This study constructed the transport networks of O and NO in different seasons from 2017 to 2020. The transport trends and the clustering formation patterns were summarized by analyzing the topological characteristics of the transport networks, and the patterns of OFS changes were diagnosed by analyzing the satellite remote sensing data.

A systematic analysis of residue and risk of cyantraniliprole in the water-sediment system: Does metabolism reduce its environmental risk?

As a representative variety of diamide insecticides, cyantraniliprole has broad application prospects. In this study, the fate and risk of cyantraniliprole and its main metabolite J9Z38 in a water-sediment system were investigated. The present result showed that more J9Z38 was adsorbed in the sediment at the end of exposure.

Determining the trophic transfer of metal(loid)s and arsenic speciation in freshwater aquatic organisms by quantifying diet compositions.

Bioaccumulation through diet is the predominant source of metal(loid)s in fishes; however, the trophic transfer of metal(loid)s from the diet to aquatic organisms remains largely unclear. In this study, aquatic organisms and five potential food sources (leaf litter, coarse and fine particulate organic matter (CPOM and FPOM, respectively), epilithon and fish) were collected around the Shimen Realgar Mine of China. Stomach content analysis and stable nitrogen and carbon isotope analysis, combined with a new Bayesian mixing model (MixSIAR), were used to quantify diet compositions of aquatic organisms.

The stereoselective toxicity of dinotefuran to Daphnia magna: A systematic assessment from reproduction, behavior, oxidative stress and digestive function.

Dinotefuran is a promising neonicotinoid insecticide with chiral structure. In the present study, the stereoselective toxicity of dinotefuran to Daphnia magna (D. magna) was studied.

A Tiered Ecological Risk Assessment of Caffeine by Using Species Sensitivity Distribution Method in the Nansi Lake Basin.

Caffeine has been reported toxic to aquatic organisms, and it frequently occurs at relatively high concentrations in most of surface waters. However, it is difficult to control caffeine pollution because of the lack of Water Quality Criteria (WQC). In this study, species sensitivity distribution method and Log-normal model were applied to derive caffeine WQC as 83.

Physicochemical characteristics and microbial communities of rhizosphere in complex amendment-assisted soilless revegetation of gold mine tailings.

Amendment-assisted soilless revegetation is a promissing ecological restoration method of mine tailings because of its eco-friendliness and low-cost. However, it is difficult to establish the plant community during ecological restoration because of its nutrient deficiency and heavy metal toxicity. In this study, the complex amendment, consisting of 1% peat, 1% sludge and 4% bentonite, was used to assist tall fescue to revegetate gold mine tailings.

The fate, acute, and subchronic risks of dinotefuran in the water-sediment system: A systematic analysis at the enantiomer level.

Environmental risks associated with neonicotinoid insecticides have attracted considerable attention. This study systematically investigated the stereoselective behavior of dinotefuran in a water-sediment system. The results showed that S-dinotefuran accumulated more easily in sediment and zebrafish.

Concentrations of heavy metals in water, sediments and aquatic organisms from a closed realgar mine.

Mining activities can result in severe heavy metal contamination in freshwater ecosystems and lead to significant health risks. In this study, eight heavy metal concentrations in the water, sediments and aquatic organisms, including eighteen fish species, two shrimp species, one crab species and one amphibian frog species of the abandoned Shimen Realgar Mine area, were analysed. The results showed that most of the heavy metals detected in water, sediments and fish from the mine area were at relatively high levels, and historical realgar mining activities were a major source of arsenic (As) contamination in this area.

Urchin-like Co3O4 anchored on reduced graphene oxide with enhanced performance for peroxymonosulfate activation in ibuprofen degradation.

Urchin-like CoO anchored on reduced graphene oxide was easily prepared with hydrothermal reaction by using a cheap and green agent. First, the surface morphology and physicochemical properties of CoO-rGO were characterized. Compared with CoO, CoO-rGO possessed excellent activity in peroxymonosulfate (PMS) activation for ibuprofen (IBU) degradation.

Soilless revegetation: An efficient means of improving physicochemical properties and reshaping microbial communities of high-salty gold mine tailings.

Soilless revegetation is a cost-effective and eco-friendly method for the ecological restoration of gold mine tailings. However, due to gold mine tailings are high-salty, alkaline and low-nutrient, little research has been done on soilless revegetation of gold mine tailings. The aim of study was to apply soilless revegetation to gold mine tailings, and investigate the changes of physicochemical properties and microbial communities of tailings after soilless revegetation.

Adsorption behavior and mechanism of Au(III) on caffeic acid functionalized viscose staple fibers.

A novel fibrous adsorbent (DAVSF-CA) was synthesized via grafting caffeic acid (CA) onto dialdehyde viscose staple fiber (DAVSF), and used to selectively adsorb Au(III) from simulated wastewater. Fourier Transform Infrared (FTIR), X-ray Photoelectron (XPS) and Nuclear Magnetic Resonance (NMR) spectra confirmed that caffeic acid was successfully grafted on DAVSF through condensation reaction. Adsorption experiments revealed that the adsorption of Au(III) on DAVSF-CA was extremely dependent on pH values and temperatures, and the maximum adsorption capacity of 3.

Contrasting Patterns of the Bacterial Communities in Melting Ponds and Periglacial Rivers of the Zhuxi glacier in the Tibet Plateau.

Since the early 21 century, global climate change has been inducing rapid glacier retreat at an unprecedented rate. In this context, the melt ponds impart increasing unique footprints on the periglacial rivers due to their hydrodynamic connection. Given that bacterial communities control numerous ecosystem processes in the glacial ecosystem, exploring the fate of bacterial communities from melt ponds to periglacial rivers yields key knowledge of the biodiversity and biogeochemistry of glacial ecosystems.

Structural and functional alterations of gut microbiome in mice induced by chronic cadmium exposure.

Mammalian gut microbiome is readily affected by acute or subchronic cadmium (Cd) intoxication, but it susceptibility following chronic Cd exposure at environmentally-relevant levels remains unknown. This study comprehensively assessed the effects of Cd exposure at doses of 10 and 50 ppm in drinking water for 20 weeks on gut microbiome in mice. Results showed that the Cd exposure induced alterations in gut morphology with potentially increased gut permeability and inflammation.

Detectable Levels of Bacterial Pathogens in the Rivers of the Lake Chaohu Basin, China.

Bacterial pathogens are one of the causes of human diseases and have a serious impact on environmental health. In this study, we investigated the bacterial pathogen community in 88 sites at rivers around Lake Chaohu Basin, China, using Illumina miseq sequencing. The results showed that three opportunistic pathogens: , , and , were the three abundant bacterial genera in all samples, and had a relative abundance of 0.

Molecular biomarkers reveal co-metabolism effect of organic detritus in eutrophic lacustrine sediments.

In eutrophic lacustrine ecosystems, drifting algal blooms are easily trapped by emergent macrophytes in downwind littoral zones, potentially altering carbon cycling processes; yet, knowledge remains limited about the mechanisms driving these changes. In this study, Microcystis and Phragmites, two dominant photosynthetic organisms in a hypereutrophic (Lake Taihu, China), were collected to simulate their co-decomposition processes. We demonstrate how molecular-level biomarkers could be used to elucidate the degradation dynamics of these two distinct organic forms in mixtures.

Degradation Characteristics of Phosphorus in Phytoplankton-Derived Particulate Organic Matter and Its Effects on the Growth of Phosphorus-Deficient in Lake Taihu.

To illustrate the contribution of phytoplankton-derived particulate organic matter (PPOM) to endogenous phosphorus (P) cycling and its effects on cyanobacteria blooms, PPOM characteristics, the degradation mechanism, and the growth of P-deficient were studied in Lake Taihu. Results showed that PPOM is the most important P pool in the water column during cyanobacteria bloom, accounting for more than 80% of the total P (TP) in the water. During PPOM degradation, the particulate orthophosphate (Ortho-P) is the main species of P release from PPOM in the early degradation stage.

Ultrafiltration for the Determination of Cu Complexed with Dissolved Organic Matters of Different Molecular Weight from a Eutrophic River, China.

The molecular weight of dissolved organic matter (DOM) is one of the essential factors controlling the properties of metal complexes. A continuous ultrafiltration experiment was designed to study the properties of Cu complexes with different molecular weights in a river before and after eutrophication. The results showed that the concentration of DOM increased from 26.

Dynamic desorption of arsenic from polymer-supported hydrated iron(III) oxide in a wastewater treatment plant.

Polymer-supported hydrated iron(III) oxide (PHIO) was successfully applied as adsorbent for arsenic removal in a wastewater treatment plant in Nandan, China. The practical PHIO adsorbent samples (PHIO-P) were collected from the adsorption column of the wastewater treatment plant, and desorption experiments of the adsorbent were carried out. Our results showed that the formation of precipitates on the surface of PHIO-P might block the porous channel of the adsorbent and decrease its arsenic adsorption capacity.

Adsorption characteristic of As(III) on goethite waste generated from hydrometallurgy of zinc.

In this paper, goethite waste from hydrometallurgy of zinc was used as a raw material for arsenic adsorbent preparation. The goethite waste adsorbent (GWA) was characterized with scanning electron microscope (SEM), X-ray powder diffraction (XRD), and particle size distribution analysis. The adsorption of As(III) on GWA was studied as a function of contact time, pH, and coexisting anions.

Nitrate removal, spatiotemporal communities of denitrifiers and the importance of their genetic potential for denitrification in novel denitrifying bioreactors.

Nitrate treatment performance and denitrification activity were compared between denitrifying biological filters (DNBFs) based on dewatered alum sludge (DAS) and neutralized used acid (NUA). The spatiotemporal distribution of denitrifying genes and the genetic potential associated with denitrification activity and nitrate removal in both DNBFs were also evaluated. The removal efficiency of NUA-DNBF increased by 8% compared with that of DAS-DNBF, and the former NUA-DNBF emitted higher amount of NO.

[Fe-Mn Binary Oxide Impregnated Chitosan Bead (FMCB): An Environmental Friendly Sorbent for Phosphate Removal].

Fe-Mn binary oxide impregnated chitosan bead (FMCB), an environmental friendly sorbent for phosphate removal, was fabricated through impregnating Fe-Mn binary oxide into chitosan matrix. The FMCB was characterized by SEM and BET surface area measurement. The adsorption behavior of phosphate on the FMCB was systemically investigated.

Effect of ultrasonic and ozone pre-treatments on pharmaceutical waste activated sludge's solubilisation, reduction, anaerobic biodegradability and acute biological toxicity.

Ultrasonic and ozone pre-treatment technologies were employed in this study to improve the anaerobic digestion efficiency of pharmaceutical waste activated sludge. The sludge solubilisation achieved 30.01% (150,000 kJ/kg TS) and 28.