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Dual-rotor strategy for organic cocrystals with enhanced near-infrared photothermal conversion.

RSC Adv

January 2024

College of Chemistry and Chemical Engineering, Key Laboratory for Preparation and Application of Ordered Structural Materials of Guangdong Province, Shantou University Shantou 515063 China

Article Synopsis
  • * A dual-rotor strategy involving single- and double-bond rotors is proposed to create effective D-A cocrystals, resulting in significant absorption from 300 nm to 2000 nm.
  • * The efficiency of PTC in these cocrystals is improved by adjusting rotor groups and substituents, with the performance linked to nonradiative decay mechanisms facilitated by the flexibility of the rotors in the excited states.
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