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A micron-thick (3-5 μm) and transparent cladding technique based on the environment friendly dimethyl carbonate solution of newly developed polyfluorosilicone acrylates was successfully applied to restore the surface of brick walls of a historic house which has been severely eroded by damp and mildew for more than 300 years in Hongcun village, one of the World Heritage sites in China. The restoration followed the rule of repairing old as old before. The cladding made from the copolymerized polyfluorosilicone acrylate resin, which mainly contained the chain fragments of dodecafluoroheptyl methacrylate and 3-(trimethoxysilyl)propyl methacrylate, permeated through the surface of old brick with an average depth of 14.
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