Prelithiation strategies for enhancing the performance of lithium-ion batteries.

During the initial cycling of lithium-ion batteries, the generation of SEI at the electrode-electrolyte interface and the occurrence of irreversible side reactions consume the active lithium, resulting in irreversible loss of volume (ICL), which may also be accompanied by electrode volume changes and structural collapse. Addressing these challenges has become critical, and pre-lithiation with additional lithium has emerged as a key way to improve battery performance. Hence, this review comprehensively analyzes and summarizes the causes of ICL in lithium-ion batteries, and systematically discusses various prelithiation methods and mechanisms of different electrode structures, especially electrodes.