Case specific: Addressing co-digestion of wastewater sludge, cheese whey and cow manure: Kinetic modeling.

The study investigated the methane production efficiency in a semi-continuous laboratory experiment with periodic feeding of wastewater sludge (WWS) as primary substrate and addition of whey (CW) and cow manure (CM). The short-term behavior of a real-scale anaerobic digester with WWS and the methane production improvements with different feeding mixtures of WWS, CW and CM were addressed. Gradual addition of CW to WWS (WWS:CW:CM = 70:20:0 to 70:55:0) increased the average daily methane production to 48.

The evolution of organic material on Asteroid 162173 Ryugu and its delivery to Earth.

The recent return of samples from asteroid 162173 Ryugu provides a first insight into early Solar System prebiotic evolution from known planetary bodies. Ryugu's samples are CI chondrite-like, rich in water and organic material, and primarily composed of phyllosilicate. This phyllosilicate surrounds micron to submicron macromolecular organic particles known as insoluble organic matter.

Commercially available mouthguards: Unearthing trace elements for the first time.

The use of mouthguards is advocated by the American Dental Association for orofacial injury prevention and teeth protection. However, the chemical environment in the mouth may cause harmful substances within the mouthguard's polymer material to leach out and be absorbed by the user. Considering this, the present study for the first time analyzed commercially available mouthguards and disclosed the presence of trace elements.

Numerical Investigation of the Damage Effect on the Evolution of Adiabatic Shear Banding and Its Transition to Fracture during High-Speed Blanking of 304 Stainless Steel Sheets.

This paper investigates numerically the effect of damage evolution on adiabatic shear banding (ASB) formation and its transition to fracture during high-speed blanking of 304 stainless steel sheets. A structural-thermal-damage-coupled finite element (FE) analysis is developed in LS-DYNA considering the modified Johnson-Cook thermo-viscoplastic model for both plasticity flow rule and damage law, while further, a temperature-dependent fracture criterion is implemented by introducing a critical temperature. The modeling approach is initially validated against experimental data regarding the fracture profile and ASB width.

How ICP-OES changed the face of trace element analysis: Review of the global application landscape.

The 50th anniversary of Inductively Coupled Plasma-Optical Emission Spectrometry (ICP-OES) will be observed in 2024. ICP-OES was first commercially available in 1974, and since then, it has become one of the most widely used analytical techniques in the world. ICP-OES is a powerful tool for the determination of trace and ultratrace elemental concentrations in a wide variety of samples specifically for multielement analysis.

Hydrometallurgical recovery of silver and gold from waste printed circuit boards and treatment of the wastewater in a biofilm reactor: An integrated pilot application.

A hydrometallurgical process for the recovery of gold and silver from waste printed circuit boards (PCBs) was experimentally verified and tested at pilot scale. The process comprises four sequential leaching stages; the first two based on HCl, correspond to base metals (e.g.

Surges in volcanic activity on the Moon about two billion years ago.

The history of mare volcanism critically informs the thermal evolution of the Moon. However, young volcanic eruptions are poorly constrained by remote observations and limited samples, hindering an understanding of mare eruption flux over time. The Chang'e-5 mission returned the youngest lunar basalts thus far, offering a window into the Moon's late-stage evolution.

Modeling biological denitrification in the presence of metal ions and elevated chloride content: Insights into abiotic and biotic mechanisms regulating metal bioprecipitation.

Biological denitrification is a critical process in which microorganisms convert nitrate to nitrogen gas. Metal ions, such as those found in industrial wastewater, can be toxic to microorganisms and impede denitrification. It is critical to identify the mechanisms that allow microorganisms to tolerate metal ions and understand how these mechanisms can be utilized to improve denitrification efficiency by modeling the process.

A novel hydrogeochemical approach to delineate the origin of potentially toxic elements in groundwater: Sophisticated molar ratios as environmental tracers.

The occurrence, mobilization, and origin of Potentially Toxic Eelements (PTEs) in the environment is always a difficult research question that has not been fully addressed to date; solving this problem would be a major achievement for environmental science and pollution research, a significant scientific breakthrough, and an important contribution to environmental analysis and monitoring. The lack of a holistic methodology that uses chemical analysis to determine the origin of each PTE in the environment is the main motivation for this project. Therefore, the hypothesis tested here is to develop a scientific approach applied to each PTE to determine whether its origin is geogenic (i.

A novel and greener sequential column leaching approach for the treatment of two different Greek laterites.

Τhe present study investigates, from an environmental protection viewpoint, the efficiency of sequential column leaching of two different Greek laterites, i.e. a limonitic ore from central and a saprolitic ore from northern Greece.

Methods of Preparation and Performance Evaluation of ABS/Mineral Microsphere Composites Produced through FDM and Compression Molding.

The use of amorphous microspheres as filler in composites is promising due to their light weight, low cost, incombustibility, and the ability to alter relevant properties of the final composite. Contrary to glass spheres, perlite microspheres are much cheaper and can be tailor-made to facilitate purpose-oriented alteration of the final composite. We report the use of perlite microspheres for the preparation of: (1) composites, through a compression molding (hot pressing) technique; and (2) composite filaments, in a single screw extruder, as well as their use for sample printing through Fused Deposition Modeling (FDM).

Microstructure, Phase Formation and Heat-Treating of Novel Cast Al-Mg-Zn-Cu-Si Lightweight Complex Concentrated Aluminum Based Alloy.

In the current work, a novel complex concentrated aluminum alloy is designed and studied. In order to investigate the unknown region of the multicomponent phase diagrams, thermo-physical parameters and the CALPHAD method were used to understand the phase formation of the AlMgZnCuSi at.% (Al.

Thermal characteristics and combustion reactivity of coronavirus face masks using TG-DTG-MS analysis.

The presented paper deals with the influence of the heating rate on combustion characteristics (reactivity and reactivity evaluation, ignition index ( ), burnout index ( ), the combustion performance index (), and the combustion stability index ( )) of the protective coronavirus face masks. Two types of commonly used face masks in different state (new and exploited) were investigated by TG-DTG analysis in an air atmosphere, directly coupled with mass spectrometry (MS). Based on the experimental results, the impact of ultimate and proximate analysis data on the evolved gas analysis (EGA) was discussed.

Quantification of trace elements in surgical and KN95 face masks widely used during the SARS-COVID-19 pandemic.

During the current coronavirus disease (COVID-19) pandemic, face masks have been the single most important protective equipment against the threat of severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2). While masks are worn, both the nose and the mouth of the user come in contact with the mask material, and as the latter mediates the inhaled air and may interfere with the swallowed saliva, it is of paramount importance to assure that the mask is free of toxic substances. As there are currently no studies on the total amount of trace elements in masks, the present study fills the void and investigates 24 surgical and KN95 face masks.

Potentially toxic elements in groundwater: a hotspot research topic in environmental science and pollution research.

A scientometric analysis based on the Scopus database was conducted to provide insight into research activities on the occurrence of potentially toxic elements (PTEs) (As, Cd, Co, Cr, Cu, Hg, Ni, Pb, Sb, and Zn) in groundwater during 1970-2019. The selection of these PTEs was based on their significance concerning their reference frequency in environmental science and pollution research (ESPR) studies and their toxicity to living organisms. The analysis utilizes data about the quantity, type, journal, geographical, institutional, and funding patterns of publications.

Fixed-bed flow experiments with supported green nZVI for the remediation of contaminated waters: Effect of pH and background solution composition.

Aim of this study is to evaluate the performance of a nanocomposite material (R-nFe), consisting of nano zero valent iron (nZVI) and a cation exchange resin, for Cr(VI) reduction and heavy metals removal from contaminated water streams. The effect of pH and the background solution composition was investigated by conducting three columns tests. In Column I, the experiments were carried out using NaCl as background electrolyte while in Column II and III the background solution consisted of 50% tertiary effluents of a waste water treatment plant and 50% deionized water.

Preparation of hydrogen, fluorine and chlorine doped and co-doped titanium dioxide photocatalysts: a theoretical and experimental approach.

Titanium dioxide (TiO) has a strong photocatalytic activity in the ultra-violet part of the spectrum combined with excellent chemical stability and abundance. However, its photocatalytic efficiency is prohibited by limited absorption within the visible range derived from its wide band gap value and the presence of charge trapping states located at the band edges, which act as electron-hole recombination centers. Herein, we modify the band gap and improve the optical properties of TiO via co-doping with hydrogen and halogen.

Acid Generation and Heavy Metal Leachability from Lignite Spoil Heaps: Impact to the Topsoils of Oropos Basin, North Attica, Greece.

The disposal of lignite spoil and tailings poses a major environmental problem in lignite mining sites which is associated with the oxidation of sulfide minerals contained in the primary ore. This process renders acidic effluents. Lignite mining in the Oropos Neogene basin, North Attica, Greece operated since the last century and ceased in the late 1960s.

Dynamic modeling of anaerobic methane oxidation coupled to sulfate reduction: role of elemental sulfur as intermediate.

The process dynamics of anaerobic oxidation of methane (AOM) coupled to sulfate reduction (SR), and the potential role of elemental sulfur as intermediate are presented in this paper. Thermodynamic screening and experimental evidence from the literature conclude that a prominent model to describe AOM-SR is based on the concept that anaerobic methane oxidation proceeds through the production of the intermediate elemental sulfur. Two microbial groups are involved in the process: (a) anaerobic methanotrophs (ANME-2) and (b) Desulfosarcina/Desulfococcus sulfur reducers cluster (DSS).

Waste marble dust and recycled glass valorization in the production of ternary blended cements.

The purpose of the present investigation is to examine the physicomechanical properties and the hydration development of ternary blended cements, composed by waste marble dust (WMD) and soda lime recycled glass (SLRG). Both wastes characteristics were investigated by means of chemical analysis, laser particle size analyzer and X-ray diffraction (XRD). Prior to their addition as substitutes for Ordinary Portland Cement (OPC), they were grounded to a specific surface area of 4000 cm/g.

Chromium Removal Using Soil Loaded with Green Iron Nanoparticles.

Chromate is considered as a serious environmental problem due its toxicity. Iron nanoparticles produced by green tea polyphenols (GT-nZVI) is a powerful reductant, which can effectively reduce Cr(VI) to Cr(III). Nano ZVI suspension was initially conceived ideal for direct injection in the contaminated aquifers.

Contamination of stream waters, sediments, and agricultural soil in the surroundings of an abandoned copper mine by potentially toxic elements and associated environmental and potential human health-derived risks: a case study from Agrokipia, Cyprus.

Abandoned mining areas have left a legacy of environmental damage with potential public health implications. The present study aimed at (1) assessing the level of contamination of the sites surrounding the Agrokipia abandoned copper mine in Cyprus through the mobilization of potentially toxic elements (PTEs), (2) correlating results with the mineralogy of the area, (3) discussing potential ecological and human health risks, and (4) proposing regeneration strategies. To this effect, the levels of 22 PTEs and other major elements were assessed in the acidic water of pit lakes, the tailings, the waters, and sediments of several streams originating from the mining site and flowing through the village of Agrokipia, and from agricultural soil from an impacted adjacent olive orchard.

Introducing a novel multi-layer perceptron network based on stochastic gradient descent optimized by a meta-heuristic algorithm for landslide susceptibility mapping.

The main objective of the current study was to present a methodological approach that combines Information Theory, a neural network and meta-heuristic techniques so as to generate a landslide susceptibility map. Specifically, the methodology involved three important tasks: Classifying the landslide related variables, weighting them and optimizing the structural parameters of the neural network. Shannon's entropy index was used to estimate for each landslide related variable the number of classes which maximized the information coefficient, whereas the Certainty Factor method was used to weight the variables.

Evaluation of Calcium Polysulfide as a Reducing Agent for the Restoration of a Cr(VI)-Contaminated Aquifer.

This study aims at investigating the efficiency of calcium polysulfide (CPS) as a reducing agent for decontamination of a heavily Cr(VI)-contaminated aquifer. Batch experiments were carried out in order to evaluate the effect of time, CPS concentration and the presence of soil on the reductive behavior of CPS. CPS was used at several stoichiometric excesses with respect to Cr(VI) concentration detected in the contaminated groundwater.