Studies on the formation of todorokite-type manganese oxide with different crystalline birnessites by Mg2+-templating reaction.

The formation of todorokite-type manganese oxide (TodMO) by hydrothermal soft chemical reaction (Mg2+ exchange followed by hydrothermal treatment) was studied using three kinds of Na-type birnessite (Na-BirMO) with different crystallinities. Buserite (BusMO) formation by Mg2+ exchange and TodMO formation by hydrothermal treatment progressed in a similar manner regardless of the crystallinity of the initial Na-BirMO, but the crystallinity of the synthesized TodMO depended on that of the initial Na-BirMO. Particle morphology of the synthesized TodMO was related to the crystallinity of the initial Na-BirMO.