Chitosan as a fluorescent probe for the detection of the AIE-active food colorant quinoline yellow.

The greenish-yellow synthetic dye quinoline yellow (Qy) is widely used in the food and pharmaceutical industries. However, this dye may lead to health and environmental problems. Therefore, investigating how Qy interacts with biological macromolecules is of great interest.

Solubility-Limited Small Molecule for Stable High-Capacity Potassium Storage.

Small molecule electrode materials with superb redox activity have significant applied implications for K-ion storage, but they face significant challenges like high solubility in electrolytes and low conductivity, limiting their capacity, rate, and cycling stability. Herein, a series of Ni-bis(dithiolene) (NiS)-based small molecules are designed with control of various redox-active substitutional groups for K-ion batteries anode materials. It is identified that bis[1,2-di(pyridine-4-yl) ethylene-1,2-dithiolate] nickel Ni[CSPy] demonstrates a high reversible specific capacity (399 mAh g at 0.

Astaxanthin promotes the longevity of modulation of the intracellular redox status and PHA-4-mediated autophagy.

Astaxanthin is a xanthophyll carotenoid which has been associated with a number of health-promoting effects, including anti-aging; however, the underlying mechanisms are not fully understood. In the present study, it was found that astaxanthin promoted the longevity of wild-type (N2) (). The lifespan-extending effect of astaxanthin was associated with a significant decrease of lipofuscin accumulation and the reduction of the age-related decline in spontaneous motility.

Bicontinuous Block Copolymer Microparticles through Hydrogen-Bonding-Mediated Dual Phase Separation between Polymer Segments and Fluorinated Additives.

Bicontinuous microparticles have advanced transport, mechanical, and electrochemical properties and show promising applications in energy storage, catalysis, and other fields. However, it remains a great challenge to fabricate bicontinuous microparticles of block copolymers (BCPs) by controlling the microphase separation due to the extremely narrow region of a bicontinuous structure in the phase diagram. Here, we demonstrate a strategy to balance the phase separation of BCPs and fluorinated additives at different length scales in emulsion droplets, providing a large window to access bicontinuous microparticles.

Excellent Electrochemical Performance and Air Storage Stability of Na-Ion Layered Oxide Cathodes Benefiting from Enhanced Ce-O Binding Energy.

The widespread application of layered oxides is constrained by their low electrochemical performance and complex irreversible phase transition. The high entropy oxide NaNiFeMnTiSnCoLiO (HEO) is synthesized by leveraging the entropy stabilization effect, which offers a partial solution to this issue, but electrochemical performance and air stability imperative to be improved. On the high entropy oxide HEO, due to the strong bond energy of Ce-O, the introduction of Ce improves the specific discharge capacity and reduces the battery gas production problem.

pH-responsive antibacterial emulsion gel based on cinnamaldehyde and carboxymethyl chitosan for fruits preservation applications.

Although the natural antibacterial agent, cinnamaldehyde, has been extensively studied in the field of food packaging, its water solubility and instability limit its further applications. The controllable responsive release can be achieved through encapsulation in responsive emulsion systems based on carboxymethyl chitosan. Herein, a pH-responsive antibacterial emulsion gel was constructed from cinnamaldehyde-loaded oil-in-water emulsion templates.

Study of the interaction between green Si quantum dots and bovine serum albumin via spectroscopic methods and its effects on antioxidant capacity and esterase activity.

In this study, the interaction mechanism between Si quantum dots (SiQDs) and bovine serum albumin (BSA), as well as the conformational and functional alterations of BSA, were rigorously investigated via multispectral techniques and dynamic light scattering analysis. van der Waals forces and hydrogen bonding, as well as an exothermic reaction and a decrease in entropy, were the primary forces involved in the binding of SiQDs to BSA. In the binding process, SiQDs exhibit preferential proximity to Site I over other potential binding sites.

Biologically-driven RAFT polymerization-amplified platform for electrochemical detection of antibody drugs.

The individualized administration and pharmacokinetics profiling are integral to the safe use of antibody drugs in immunotherapy. Here, we propose an electrochemical platform for the highly sensitive and selective detection of antibody drugs, taking advantage of the affinity capture by the peptide mimotopes together with the signal amplification by the biologically-driven RAFT polymerization (BDRP). Briefly, the BDRP-based platform involves the capture of antibody drugs by peptide mimotopes, the labeling of multiple reversible addition-fragmentation chain-transfer (RAFT) agents to the glycan chains of antibody drugs, and the BDRP-enabled controlled recruitment of numerous redox labels.

Development of a novel NIR-II fluorescence probe for monitoring serum albumin fluctuation in cerebra neurotoxicity induced by manganese exposure.

Manganese is essential for various biological functions; however, excessive exposure can lead to significant health risks, particularly brain neurotoxicity. Understanding manganese-induced alterations in brain serum protein levels and brain function is crucial for elucidating the mechanisms underlying manganese neurotoxicity. To address this, we developed a novel NIR-II fluorescent probe, RSM, characterized by robust binding to serum albumin and high sensitivity.

A bifunctional naphthalimide-based fluorescent probe for imaging lysosomal peroxynitrite and viscosity in living cells and zebrafish.

Peroxynitrite (ONOO) and viscosity are critical indicators of lysosome functionality, intimately linked to numerous diseases' pathophysiological processes. Hence, creating reliable analytical techniques to observe fluctuations in lysosomal ONOO and viscosity is highly important. This study presents the development of a novel naphthalimide-based fluorescent probe, Nap-Cy, specifically designed to target lysosomes and simultaneously detect both ONOO and viscosity.

Suspended sediment (SPS) triggers nitrogen retention by altering microbial network stability and electron transport behavior during the aerobic-anoxic transition.

NO-N transformation, the vital biological process, determines nitrogen removal and retention in aquatic environment. Suspended sediment (SPS) ubiquitous in freshwater ecosystems can accelerate the transitions from aerobic to anoxic states, inevitably impacting NO-N transformation. To elaborate on the microbial mechanism by which SPS content affected NO-N transformation, we explored nitrogen removal and retention, microbial communities, co-occurrence networks, and electron transfer behavior under different SPS content during the aerobic-anoxic transition.

The transition of tetragonal to monoclinic phase in BiVO coupled with peroxymonosulfate for photocatalytic degradation of tetracycline hydrochloride.

At present, the mechanism difference between tetragonal BiVO (t-BiVO) and monoclinic BiVO (m-BiVO) coupled peroxymonosulfate (PMS) to realize photocatalysis is still unclear. In this study, m-BiVO and t-BiVO were obtained by adjusting the bismuth-vanadium ratio in the precursor solution (Bi:V=3:1; 1:1; 1:2 and 1:3). The results of photocatalytic experiments showed that both t-BiVO and m-BiVO had certain activation effects on PMS, and the prepared monoclinic B1V2 has the strongest photocatalytic performance.

Adhesive and antibacterial guar gum-based nanocomposite hydrogel for remodeling wound healing microenvironment.

Hydrogels are promising wound dressings due to their extracellular matrix-like properties and tunable structure-function characteristics. Besides the physical isolation effect, hydrogel dressings are highly expected to possess tissue-adhesive performance and antibacterial capacity, which are beneficial for their clinical translations. Herein, a guar gum (GG)-based nanocomposite hydrogel was fabricated by mixing methacrylated GG (GGMA), acrylic acid, acrylated 3-aminophenylboronic acid, mangiferin (MF)-loaded cetyltrimethyl ammonium chloride (CTAC) micelles (MF@CTAC) and radical initiator.

Antioxidant and antibacterial coconut mesocarp polyphenol hydrogel dressing based on PVA/quaternary chitosan/sodium alginate with β-glycerophosphate.

This study developed PQSp wound dressing hydrogels (S0-S6) using polyvinyl alcohol (PVA), quaternary chitosan (QCS), and sodium alginate (SA) as the matrix, with the addition of coconut mesocarp polyphenol (P-CTP, 0.1 %, 0.5 %, and 1.

Neoadjuvant chemotherapy by liposomal doxorubicin boosts immune protection of tumor membrane antigens-based nanovaccine.

Autologous tumor cell membrane antigen-based vaccines (TMVs) have garnered extensive attention as personalized immunotherapy. However, patients who take TMVs therapy usually undergo various treatments prior to surgery, and these processes modulate the immunogenicity of the tumor membrane and the tumor immune microenvironment. Herein, we investigate the impact of preoperative chemotherapy on the efficacy of TMVs.

Interfacial hydrogen bonds induced by porous FeCr bimetallic atomic sites for efficient oxygen reduction reaction.

Interfacial hydrogen bonds are pivotal in enhancing proton activity and accelerating the kinetics of proton-coupled electron transfer during electrocatalytic oxygen reduction reaction (ORR). Here we propose a novel FeCr bimetallic atomic sites catalyst supported on a honeycomb-like porous carbon layer, designed to optimize the microenvironment for efficient electrocatalytic ORR through the induction of interfacial hydrogen bonds. Characterizations, including X-ray absorption spectroscopy and in situ infrared spectroscopy, disclose the rearrangement of delocalized electrons due to the formation of FeCr sites, which facilitates the dissociation of interfacial water molecules and the subsequent formation of hydrogen bonds.

Simultaneous modulation of Ni single atoms and NiO clusters on TiO for solar-driven CO and HO conversion to CH.

Construction of the photocatalysts with synergistic active sites holds great significance in enhancing the direct CO reduction coupled with HO oxidation under solar irradiation. This work demonstrates the fabrication of a dual-active-site catalyst (Ni-NiO/TiO) through in-situ formation and simultaneous modulation of Ni single atoms (Ni) and NiO clusters on porous TiO. Both Ni and NiO are characterized by X-ray absorption fine structure (XAFS) analyses and diffuse reflectance infrared Fourier transform spectroscopy using CO as a probe molecule (CO-DRIFTS).

Copper-based fluorescent nanozyme used to construct a ratiometric sensor for visual detection of thiophanate methyl.

Although nanozyme has shown great potential in designing fluorescent assays for pesticide residue, most of them are based on single emission, thus affecting the detection accuracy. Herein, a copper-based fluorescent nanozyme (Cu-BH) synthesized with dual-ligand, integrating fluorescence and oxidase-mimic into one spherical nanomaterial, was used firstly to establish a ratiometric approach for visual detection of thiophanate methyl (TM). Cu-BH possesses excellent oxidase-like activities, triggering the oxidation of colorless o-phenylenediamine (OPD) into yellow luminescent products (oxOPD, λem = 564 nm).

Enhancement of bismuth tungstate perovskite photoelectrical performance using elemental co-doping and construction of ternary heterojunction for sensitive detection of Trenbolone.

Bismuth tungstate perovskite has been identified as a promising photoelectric material. Nevertheless, the wide band gap of bismuth tungstate leads to short-wavelength absorption of a single material with an attenuated photocurrent response, hindering its realization in biosensing applications. In this study, F, S co-doped BiWO was synthesized by heat treatment and combined with SnS and CdS to form a ternary heterojunction composite.

Succinonitrile Electrolyte Additive for Stabilizing Aqueous Zinc Metal Batteries.

The utilization of water electrolytes in zinc-ion batteries offers the advantages of enhanced safety, reduced cost, and improved environmental friendliness, rendering them an optimal choice for replacing lithium-ion batteries. Nevertheless, the conventional zinc sulfate electrolyte fails to meet stringent requirements. Therefore, developing electrolytes is crucial for addressing the low cycle life of zinc ions and suppressing the growth of zinc dendrites.

Photocatalytic Partial Water Oxidation Promoted by a Hydrogen Acceptor-Hydroxyl Mediator Couple.

Hydrogen peroxide (HO) is an important chemical in synthetic chemistry with huge demands. Photocatalytic synthesis of HO via oxygen reduction and water oxidation reactions (ORR and WOR) is considered as a promising and desirable solution for on-site applications. However, the efficiency of such a process is low due to the poor solubility of molecular oxygen and the rapid reverse reaction of hydroxyl radicals (OH) with hydrogen atoms (H).

Low-Frequency Phonon Dispersion Relation Enabling Stable Cathode from Spent Lithium-Ion Batteries.

Direct recycling technology can effectively solve the environmental pollution and resource waste problems caused by spent lithium-ion batteries. However, the repaired LiNiCoMnO (NCM) black mass by direct recycling technology shows an unsatisfactory cycle life, which is attributed to the formation of spinel/rock salt phases and rotational stacking faults caused by the in-plane and out-of-plane migration of transition metal (TM) atoms during charge/discharge. Herein, local lattice stress is introduced into the regenerated cathode during repair.

Recent Progress of Substituted Allylboron Compounds in Catalytic Asymmetric Allylation Reactions.

The catalytic asymmetric allylation reaction involving allylboron species has emerged as a powerful tool to access highly stereoselective allylation products. In the early years, most of the researches focused on the reaction of unsubstituted allylboronates with ketones or imines. With the synthesis of complex substituted allylboronates, allylboronic acids and allyltrifluoroborates, the type of reactions and the variety of substrates are greatly expanded.

Nanopore Confinement Effect Mediated Heterogeneous Plasmonic Metasurfaces for Multifunctional Biosensing Interfaces.

Plasmonic metasurfaces (PMs) exhibit extraordinary optical response due to surface lattice resonance, which is crucial for realizing high-performance photovoltaic device preparation. In this work, a nanopore confinement effect-mediated MOF@UsAu is proposed as a novel PM heterojunction for photovoltaic interfaces. 2D MOFs have the unique advantage of a tunable and ordered porous structure.