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Calix[2]thia[4]phyrin: an expanded calixphyrin with aggregation-induced enhanced emission and anion receptor properties.
J Org Chem
September 2013
School of Chemical Sciences, National Institute of Science Education and Research, IOP campus, Sainik School - PO, Bhubaneshwar 751005, Odisha, India.
The synthesis of calix[2]thia[4]phyrin 3, a core-modified expanded calixphyrin, by an efficient synthetic route is reported. 3 exhibits an aggregation-induced enhanced emission (AIEE) phenomenon upon addition of increasing amounts of water. This is attributed to the restricted intramolecular rotation of the meso-aryl rings present on the sp(3) bridging carbons.
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