Halogen-free layered double hydroxide-cyclotriphosphazene carboxylate flame retardants: effects of cyclotriphosphazene di, tetra and hexacarboxylate intercalation on layered double hydroxides against the combustible epoxy resin coated on wood substrates.

The development of halogen-free flame retardants as environmentally friendly and renewable materials for heat and fire-resistant applications in the field of electronics is important to ensure safety measures. In this regard, we have proposed a simple and halogen-free strategy for the synthesis of flame retardant LDH-PN materials to decrease the fire hazards of epoxy resin (EP), a co-precipitation reaction between Mg(NO) and Al(NO) and the subsequent incorporation of different cyclotriphosphazene (PN) carboxylate anions. The cyclotriphosphazene-based di, tetra and hexacarboxylate-intercalated layered double hydroxides are designated as LDH-PN-DC, LDH-PN-TC and LDH-PN-HC, respectively.