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Sensitization of NIR luminescence of Yb by Zn chromophores in heterometallic complexes with a bridging Schiff-base ligand.

Dalton Trans

August 2017

G. A. Razuvaev Institute of Organometallic Chemistry of Russian Academy of Sciences, Tropinina 49, 603950 Nizhny Novgorod, Russian Federation. and Nizhny Novgorod State University, Gagarina avenue 23/2, 603950 Nizhny Novgorod, Russian Federation.

Herein, complexes [ZnL] (1), {(HO)Zn(μ-L)Yb[OCH(CF)]} (2), {[(CF)HCO]Zn(μ-L)Yb[OCH(CF)](μ-OH)} (3), and [(HO)Ln(L)] (Ln = Yb (4) and Gd (5)) containing a bridging Schiff-base ligand (HL = N,N'-bis(3-methoxy salicylidene)phenylene-1,2-diamine) were synthesized. The compounds 1-4 were structurally characterized. The ytterbium derivatives 2-4 exhibited bright NIR metal-centred photoluminescence (PL) of Yb ion under one- (λ = 380 nm) and two-photon (λ = 750 nm) excitation.

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