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Synthesis of different types of alkoxy fullerene derivatives from chlorofullerene CCl.
Org Biomol Chem
January 2017
IPCP RAS, Semenov Prospect 1, Chernogolovka, 142432, Russia. and Skolkovo Institute of Science and Technology, Nobel St. 3, Moscow, 143026, Russian Federation.
We report novel synthetic routes for facile preparation of highly functionalized fullerene derivatives C(OR)X (X = H, Cl, Br), C(OR)O and C(OR) from chlorofullerene CCl. The first water-soluble fullerene compound bearing residues of 3-oxypropanoic acid demonstrated a potent anti-HIV activity.
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