Paste Aging Spontaneously Tunes TiO Nanoparticles into Reproducible Electrosprayed Photoelectrodes.

In this study, the spontaneous microstructure tuning of TiO was observed by aging the ethanol/water TiO paste for up to 20 days at ambient conditions. A dynamic light scattering study reveals that it formed the outstanding reproducible TiO microstructure with a ∼200 nm average particle size and stabilizes in 6 to 20 days under an ambient atmosphere. Interestingly, the as-deposited day 15 sample spontaneously changed its crystallinity upon keeping the paste at ambient conditions; meanwhile the day 0 sample showed an amorphous structure.

Environmentally Relevant Mixture of Pesticides Affect Mobility and DNA Integrity of Early Life Stages of Rainbow Trout ().

The aim of this study was to analyze the impact of three concentrations of a pesticide mixture on the first development stages of rainbow trout (). The mixture was made up of three commonly used pesticides in viticulture: glyphosate (GLY), chlorpyrifos (CPF) and copper sulfate (Cu). Eyed stage embryos were exposed for 3 weeks to three concentrations of the pesticide mixture.

Correction: Dinuclear cobalt complexes with a redox active biphenyl bridging ligand [Co(BP)(tqa)](PF) (HBP = 4,4'-bis(3-tert-butyl-1,2-catechol), tqa = tris(2-quinolylmethyl)amine): structure and magnetic properties.

Correction for 'Dinuclear cobalt complexes with a redox active biphenyl bridging ligand [Co(BP)(tqa)](PF) (HBP = 4,4'-bis(3-tert-butyl-1,2-catechol), tqa = tris(2-quinolylmethyl)amine): structure and magnetic properties' by Yusaku Suenaga et al., Dalton Trans., 2021, DOI: .

Chromosome-level genome assembly of Scapharca kagoshimensis reveals the expanded molecular basis of heme biosynthesis in ark shells.

Ark shells are commercially important clam species that inhabit in muddy sediments of shallow coasts in East Asia. For a long time, the lack of genome resources has hindered scientific research of ark shells. Here, we report a high-quality chromosome-level genome assembly of Scapharca kagoshimensis, with an aim to unravel the molecular basis of heme biosynthesis, and develop genomic resources for genetic breeding and population genetics in ark shells.

Structure of Coal-Derived Metal-Supported Few-Layer Graphene Composite Materials Synthesized Using a Microwave-Assisted Catalytic Graphitization Process.

Metal-supported few-layer graphene (FLG) was synthesized via microwave-assisted catalytic graphitization owing to the increasing demand for it and its wide applications. In this study, we quickly converted earth-abundant and low-cost bituminous coal to FLG over Fe catalysts at a temperature of 1300 °C. X-ray diffraction, Raman spectroscopy, transmission electron microscopy, and N adsorption-desorption experiments were performed to analyze the fabricated metal-supported FLG.

Dinuclear cobalt complexes with a redox active biphenyl bridging ligand [Co(BP)(tqa)](PF) (HBP = 4,4'-bis(3--butyl-1,2-catechol), tqa = tris(2-quinolylmethyl)amine): structure and magnetic properties.

The biscatechol, H4BP (4,4'-bis(3-tert-butyl-1,2-catechol)) that can directly connect two redox active catechol moieties was synthesized. Also, tris(2-pyridylmethyl)amine (tpa), bis(2-pyridylmethyl)(2-quinolylmethyl)amine (bpqa), (2-pyridylmethyl)bis(2-quinolyl methyl)amine (pbqa), and tris (2-quinolylmethyl)amine (tqa) were synthesized as terminal ligands of the tetracoordinated tripod. In total, five different dinuclear Co complexes were synthesized from H4BP with various terminal ligands as follows, [Co2(BP)(tpa)2](PF6)2 (1), [Co2(BP)(tpa)2](PF6)3 (2), [Co2(BP)(bpqa)2](PF6)2 (3), [Co2(BP)(pbqa)2](PF6)2 (4), and [Co2(BP)(tqa)2](PF6)2 (5).

Spray Pyrolyzed TiO Embedded Multi-Layer Front Contact Design for High-Efficiency Perovskite Solar Cells.

The photovoltaic performance of perovskite solar cells (PSCs) can be improved by utilizing efficient front contact. However, it has always been a significant challenge for fabricating high-quality, scalable, controllable, and cost-effective front contact. This study proposes a realistic multi-layer front contact design to realize efficient single-junction PSCs and perovskite/perovskite tandem solar cells (TSCs).

Hierarchical-pore UiO-66 modified with Ag for π-complexation adsorption desulfurization.

Adsorption desulfurization represents an alternative technology for the effective removal of thiophenic compounds from fuels. Metal-organic frameworks have been the ideal candidates for the adsorptive desulfurization of fuel due to the high surface areas. Pristine UiO-66 is thought to be appropriate for the removal of small thiophenic compounds.

Stochastic processes drive bacterial and fungal community assembly in sustainable intensive agricultural soils of Shanghai, China.

Sustainable intensive cropping systems have been implemented for three decades in suburban agricultural districts of Shanghai, China. These human-managed soils have been developed from paleosol or alluvial soils across different regions. However, little is known about the geographical distribution patterns of microbes and microbial community assembly in the sustainable intensive soils after decades of anthropogenic disturbances.

Direct Femtosecond Laser Fabrication of Chemically Functionalized Ultra-Black Textures on Silicon for Sensing Applications.

Here, we present the single-step laser-assisted fabrication of anti-reflective hierarchical surface textures on silicon locally functionalized with a photoluminescent (PL) molecular nanolayer. Using femtosecond-laser ablation of commercial crystalline Si wafers placed under a layer of a solution containing rhodamine 6G (R6G) a triethoxysilyl derivative, we fabricated ordered arrays of microconical protrusions with self-organized nanoscale surface morphology. At the same time, the laser-induced temperature increase facilitated surface activation and local binding of the R6G derivative to the as-fabricated nanotextured surface.

Black Au-Decorated TiO Produced via Laser Ablation in Liquid.

The rational combination of plasmonic and all-dielectric concepts within hybrid nanomaterials provides a promising route toward devices with ultimate performance and extended modalities. Spectral matching of plasmonic and Mie-type resonances for such nanostructures can only be achieved for their dissimilar characteristic sizes, thus making the resulting hybrid nanostructure geometry complex for practical realization and large-scale replication. Here, we produced amorphous TiO nanospheres decorated and doped with Au nanoclusters via single-step nanosecond-laser irradiation of commercially available TiO nanopowders dispersed in aqueous HAuCl.

Structure and Properties of Biodegradable PLLA/ZnO Composite Membrane Produced via Electrospinning.

These days, composite materials based on polymers and inorganic nanoparticles (NPs) are widely used in optoelectronics and biomedicine. In this work, composite membranes of polylactic acid and ZnO NPs containing 5-40 wt.% of the latter NPs were produced by means of electrospinning.

Trehalose induces SQSTM1/p62 expression and enhances lysosomal activity and antioxidative capacity in adipocytes.

Adipocytes, which comprise the majority of white adipose tissue (WAT), are involved in obesity-related pathology via various mechanisms, including disturbed lysosomal enzymatic activity and accumulation of oxidative stress. Sequestosome 1 (SQSTM1/p62) is an autophagy marker that participates in antioxidative responses via the activation of nuclear factor erythroid-derived 2-like 2 (NRF2). Trehalose is a non-reducing disaccharide reported to suppress adipocyte hypertrophy in obese mice and improve glucose tolerance in humans.

Large-Scale and Localized Laser Crystallization of Optically Thick Amorphous Silicon Films by Near-IR Femtosecond Pulses.

Amorphous silicon (α-Si) film present an inexpensive and promising material for optoelectronic and nanophotonic applications. Its basic optical and optoelectronic properties are known to be improved via phase transition from amorphous to polycrystalline phase. Infrared femtosecond laser radiation can be considered to be a promising nondestructive and facile way to drive uniform in-depth and lateral crystallization of α-Si films that are typically opaque in UV-visible spectral range.

Author Correction: The Japanese herbal medicine Hangeshashinto enhances oral keratinocyte migration to facilitate healing of chemotherapy-induced oral ulcerative mucositis.

An amendment to this paper has been published and can be accessed via a link at the top of the paper.

Isotope chemometrics determines farming methods and geographical origin of vegetables from Yangtze River Delta Region, China.

Shanghai city has encountered possible food fraud regarding the geographical mislabeling of vegetables for economic gain. A combination of δC, δN, δH and δO values and partial least squares discrimination analysis and support vector machine (SVM) methods were used for the first time to assess farming methods and determine the origin of vegetables from Shanghai city, Anhui and Zhejiang provinces. The results showed that 65.

Bioeconomy perception by future stakeholders: Hearing from European forestry students.

This article provides useful information for universities offering forestry programs and facing the growing demand for bioeconomy education. An explorative survey on bioeconomy perception among 1400 students enrolled in 29 universities across nine European countries offering forestry programs was performed. The data have been elaborated via descriptive statistics and cluster analysis.

Correction: A CO-responsive smart fluid based on supramolecular assembly structures varying reversibly from vesicles to wormlike micelles.

[This corrects the article DOI: 10.1039/D0RA03854G.].

Sequential recovery of gold and copper from bioleached wastewater using ion exchange resins.

Numerous studies have sought to address the extraction of metals from printed circuit boards by employing bioleaching process. However, separation and recovery of the bioleached metals have always been a bottleneck. Herein, we demonstrate effective recovery of bioleached Au and Cu via selective separation using ion exchange resins.

A CO-responsive smart fluid based on supramolecular assembly structures varying reversibly from vesicles to wormlike micelles.

CO-responsive smart fluids have been widely investigated in the past decade. In this article, we reported a CO-responsive smart fluid based on supramolecular assembly structures varying from vesicles to wormlike micelles. Firstly, oleic acid and 3-dimethylaminopropylamine reacted to form a single-chain weak cationic surfactant with a tertiary amine head group, -[3-(dimethylamino)propyl]oleamide (NDPO).

A novel method for evaluating activity of transient receptor potential channels using a cellular dielectric spectroscopy.

Cellular dielectric spectroscopy (CDS) is a novel technology enabling pharmacological evaluation of multiple receptor types with a label-free cell-based assay. We evaluated activities of a family of ligand-gated channels, transient receptor potential vanilloid 1 (TRPV1) and transient receptor potential ankyrin 1 (TRPA1) channels by an electrical impedance-based biosensor (CellKey™ system) using CDS. Measures of both potency (EC) and efficacy (E) of these agonists with CellKey™ were almost identical to those made using the traditional Ca influx assay in TRPV1- or TRPA1-expressing cells, suggesting that CellKey™ is a simpler and easier means of evaluating TRP activities.

Nutrient removal, methane and nitrous oxide emissions in a hybrid constructed wetland treating anaerobic digestate.

A pilot hybrid constructed wetland (CW) planted with reeds (Phragmite australis) and rice (Oryza sativa L.) was designed to treat liquid anaerobic digestate in the Yangtze River Delta, China. The hybrid CW system was composed of four stages: two reed vegetated vertical subsurface flow beds (VSSF: U1 and U2) in sequence, followed by a reed vegetated horizontal subsurface flow bed (HSSF: U3) and a rice vegetated surface flow bed (SF: U4).

Experimental Study on the Failure Mechanisms in Brittle Shales.

The brittle failure of Chengkou shale occurs throughout the exploration and development processes of hydrocarbons. To investigate the failure mechanisms of Chengkou shale and analyze the associated mechanical behavior such as crack initiation, propagation, and coalescence at different stress levels, a series of laboratory experiments were conducted on servo-controlled triaxial cells equipped with ultrasound monitoring. The experimental results show that key mechanical parameters such as peak stress σ, stress onset of dilation σ, and strain at peak stress ε exhibit nearly linear relationships at various confining pressures.

Nutlin-3a suppresses poly (ADP-ribose) polymerase 1 by mechanisms different from conventional PARP1 suppressors in a human breast cancer cell line.

Poly (ADP-ribose) polymerase 1 (PARP1) plays important roles in single strand DNA repair. PARP1 inhibitors enhance the effects of DNA damaging drugs in homologous recombination-deficient tumors including tumors with breast cancer susceptibility gene (BRCA1) mutation. Nutlin-3a, an analog of cis-imidazoline, inhibits degradation of murine double minute 2 (MDM2) and stabilizes p53.