Resolving heterogeneous particle mobility in deeply quenched liquid iron: an ultra-fast assembly-free two-step nucleation mechanism.

Despite intensive research, little is known about the intermediate state of phase transforming materials, which may form the missing link between liquids and solids on the nanoscale. The unraveling of the nanoscale interplay between the structure and dynamics of the intermediate state of phase transformations (through which crystal nucleation proceeds) is one of the biggest challenges and unsolved problems of materials science. Here we show using unbiased molecular dynamics simulations and spatially resolved atomic displacement maps (d-maps) that upon deep quenching the solidification of undercooled liquid iron proceeds through the formation of metastable pre-nucleation clusters (PNCs).

Bilayered (silica-chitosan) coatings for studying dye release in aqueous media: The role of chitosan properties.

Chitosan and bilayered--Rhodamine 6G impregnated silica-chitosan--coatings (300-3000 nm thick) were prepared and investigated as a model for controlled drug release. Properties of native, ionically (sodium triphosphate) and covalently (glutaraldehyde) cross-linked layers of chitosan in contact with aqueous phase (modeling human blood pH of ca. 7.

Single beam grating coupled interferometry: high resolution miniaturized label-free sensor for plate based parallel screening.

Grating Coupled Interferometry (GCI) using high quality waveguides with two incoupling and one outcoupling grating areas is introduced to increase and precisely control the sensing length of the device; and to make the sensor design suitable for plate-based multiplexing. In contrast to other interferometric arrangements, the sensor chips are interrogated with a single expanded laser beam illuminating both incoupling gratings simultaneously. In order to obtain the interference signal, only half of the beam is phase modulated using a laterally divided two-cell liquid crystal modulator.

Ion-erosion induced surface nanoporosity and nanotopography on Si.

The low-energy ion-bombardment induced surface nanotopography and the nanopatterning of Si has been simulated by atomistic simulations using an approach based on molecular dynamics (MD). In order to speed up simulations a reasonable cutoff in simulation time and increased cooling rates for keeping in hand the system temperature have been used. We get an unexpectedly rich variety of disordered nanopatterns formed by the self-organization of the crater rims and adatoms islands generated by the individual ion impacts.

Self-organized transient facilitated atomic transport in Pt/Al(111).

During the course of atomic transport in a host material, impurity atoms need to surmount an energy barrier driven by thermodynamic bias or at ultralow temperatures by quantum tunneling. In the present article, we demonstrate using atomistic simulations that at ultralow temperature, transient interlayer atomic transport is also possible without tunneling when the Pt/Al(111) impurity/host system self-organizes itself spontaneously into an intermixed configuration. No such extremely fast athermal concerted process has been reported before at ultralow temperatures.