Mn(I)-Catalyzed Site-Selective C-H Activation: Unlocking Access to 3-Arylated Succinimides from 2-Arylpyridines and Maleimides.

An efficient and cost-effective Mn(I)-catalyzed site-selective C-H activation of 2-arylpyridines with maleimides has been described. This approach facilitates the synthesis of 3-arylated succinimide derivatives with high site selectivity, chemoselectivity, catalytic efficiency, and outstanding tolerance to numerous functional groups. The practicality of this approach is further evidenced by its successful application in large-scale reactions and the conversion of the synthesized succinimide derivatives into other valuable compounds.

Gelation of aqueous pectin solutions: a dynamic light scattering study.

We report the dynamic light scattering study of the gelation of aqueous solutions of the biopolymer, pectin, induced by the addition of calcium chloride. The time correlation function data are analyzed under the framework of the coupling model. As the solution enters the semidilute regime where gelation sets in, the relaxation process shows a stretched exponential behavior.

Protein interactions in undersaturated and supersaturated solutions: a study using light and x-ray scattering.

Protein interactions in undersaturated and supersaturated solutions were investigated using static and dynamic light scattering and small angle x-ray scattering. A morphodrom of lysozyme crystals determined at 35 degrees C and pH = 4.6 was used as a guideline in selecting the protein and precipitant concentrations.

Salt-induced liquid-liquid phase separation of protein-surfactant complexes.

We report the cloud-point curve determination of lysozyme-sodium-doderyl-sulfate (SDS) complexes in solution. By varying the pH, salt concentration, and relative ratio of lysozyme to SDS, the phenomenon of clouding and liquid-liquid phase separation is investigated under different solution conditions. For the temperature, concentration, and pH ranges used in this study, the clouding phenomenon appears to be controlled by the electrostatic interaction between the lysozyme-SDS complexes.

Growth and thiophene accumulation by hairy root cultures of Tagetes patula in media of varying initial pH.

Hairy roots of Tagetes patula were grown for 24 days in modified Murashige and Skoog's liquid medium at different initial pH levels of 4.0, 5.0, 5.