DMSO promoted catalyst-free oxidative C-N/C-O couplings towards synthesis of imidazoles and oxazoles.

Dimethyl sulfoxide (DMSO)-promoted catalyst-free oxidative C-N coupling and C-O coupling under oxidant-free conditions are outlined. This protocol is operationally simple and leads to various functionalized substituted imidazoles or oxazoles in good yields. To date, a very limited number of oxidation protocols have been established, where DMSO acts solely as a catalyst or an oxidant or both.

Fe(III) cross-linked cellulose-agar hydrogel beads for efficient phosphate removal from aqueous solutions.

Fe(III) cross-linked cellulose agar beads (Fe-CLCAB) were synthesized by sol-gel method and employed as adsorbents for the removal of phosphate ions from aqueous medium. The synthesized Fe-CLCAB was characterized by its swelling property, Fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM), and UV-Vis absorption spectroscopic analysis. Batch adsorption studies were carried out to find out the optimum conditions of phosphate uptake.

A trinuclear nickel(II) Schiff base complex with phenoxido- and acetato-bridges: combined experimental and theoretical magneto-structural correlation.

We describe the synthesis and characterization of a new trinuclear Ni(ii) Schiff base complex of formula [Ni3(L)2(NCS)2(OAc)2(CH3OH)2] (1) where HL is the 1 : 1 condensation product of 2-picolylamine and o-vanillin. The crystal structure of complex 1 shows that the two terminal Ni(ii) ions are connected to the central one through a phenoxido- and a syn-syn acetato bridge, giving rise to a very bent configuration in the Ni3-core. Magnetic susceptibility measurements show the presence of a weak antiferromagnetic coupling with J = -3.