Probing resonating valence bond states in artificial quantum magnets.

Designing and characterizing the many-body behaviors of quantum materials represents a prominent challenge for understanding strongly correlated physics and quantum information processing. We constructed artificial quantum magnets on a surface by using spin-1/2 atoms in a scanning tunneling microscope (STM). These coupled spins feature strong quantum fluctuations due to antiferromagnetic exchange interactions between neighboring atoms.

Single-crystalline epitaxial TiO film: A metal and superconductor, similar to Ti metal.

Titanium monoxide (TiO), an important member of the rock salt 3d transition-metal monoxides, has not been studied in the stoichiometric single-crystal form. It has been challenging to prepare stoichiometric TiO due to the highly reactive Ti We adapt a closely lattice-matched MgO(001) substrate and report the successful growth of single-crystalline TiO(001) film using molecular beam epitaxy. This enables a first-time study of stoichiometric TiO thin films, showing that TiO is metal but in proximity to Mott insulating state.

Two-Dimensional Superconductivity at the LaAlO_{3}/KTaO_{3}(110) Heterointerface.

We report on the observation of a T_{c}∼0.9  K superconductivity at the interface between LaAlO_{3} film and the 5d transition metal oxide KTaO_{3}(110) single crystal. The interface shows a large anisotropy of the upper critical field, and its superconducting transition is consistent with a Berezinskii-Kosterlitz-Thouless transition.

Observation and control of the weak topological insulator state in ZrTe.

A quantum spin Hall (QSH) insulator hosts topological states at the one-dimensional (1D) edge, along which backscattering by nonmagnetic impurities is strictly prohibited. Its 3D analogue, a weak topological insulator (WTI), possesses similar quasi-1D topological states confined at side surfaces. The enhanced confinement could provide a route for dissipationless current and better advantages for applications relative to strong topological insulators (STIs).

Multicritical Deconfined Quantum Criticality and Lifshitz Point of a Helical Valence-Bond Phase.

The S=1/2 square-lattice J-Q model hosts a deconfined quantum phase transition between antiferromagnetic and dimerized (valence-bond solid) ground states. We here study two deformations of this model-a term projecting staggered singlets, as well as a modulation of the J terms forming alternating "staircases" of strong and weak couplings. The first deformation preserves all lattice symmetries.

High-Pressure Synthesis of Double Perovskite BaNiIrO: In Search of a Ferromagnetic Insulator.

Double perovskite oxides with d-d electronic configurations are expected to be ferromagnetic from the Goodenough-Kanamori rules, such as ferromagnetic LaNiMnO. In search of new ferromagnetic insulators, double perovskite BaNiIrO was successfully synthesized by high-pressure and high-temperature methods (8 GPa and 1573 K). BaNiIrO crystallizes in a cubic double perovskite structure (space group: 3Ì…), with an ordered arrangement of NiO and IrO octahedra.

Strong Ferromagnetism Achieved via Breathing Lattices in Atomically Thin Cobaltites.

Low-dimensional quantum materials that remain strongly ferromagnetic down to monolayer thickness are highly desired for spintronic applications. Although oxide materials are important candidates for the next generation of spintronics, ferromagnetism decays severely when the thickness is scaled to the nanometer regime, leading to deterioration of device performance. Here, a methodology is reported for maintaining strong ferromagnetism in insulating LaCoO (LCO) layers down to the thickness of a single unit cell.

Ultrahigh-resolution scanning microwave impedance microscopy of moiré lattices and superstructures.

Two-dimensional heterostructures composed of layers with slightly different lattice vectors exhibit new periodic structure known as moiré lattices, which, in turn, can support novel correlated and topological phenomena. Moreover, moiré superstructures can emerge from multiple misaligned moiré lattices or inhomogeneous strain distributions, offering additional degrees of freedom in tailoring electronic structure. High-resolution imaging of the moiré lattices and superstructures is critical for understanding the emerging physics.

Strain-Mediated High Conductivity in Ultrathin Antiferromagnetic Metallic Nitrides.

Strain engineering provides the ability to control the ground states and associated phase transition in epitaxial films. However, the systematic study of the intrinsic character and strain dependency in transition-metal nitrides remains challenging due to the difficulty in fabricating stoichiometric and high-quality films. Here the observation of an electronic state transition in highly crystalline antiferromagnetic CrN films with strain and reduced dimensionality is reported.

Fabry-Pérot Oscillations in Correlated Carbon Nanotubes.

We report the observation of an intriguing behavior in the transport properties of nanodevices operating in a regime between the Fabry-Pérot and the Kondo limits. Using ultrahigh quality nanotube devices, we study how the conductance oscillates when sweeping the gate voltage. Surprisingly, we observe a fourfold enhancement of the oscillation period upon decreasing temperature, signaling a crossover from single-electron tunneling to Fabry-Pérot interference.

Non-Hermitian Skin Modes Induced by On-Site Dissipations and Chiral Tunneling Effect.

In this Letter, we study the conditions under which on-site dissipations can induce non-Hermitian skin modes in non-Hermitian systems. When the original Hermitian Hamiltonian has spinless time-reversal symmetry, it is impossible to have skin modes; on the other hand, if the Hermitian Hamiltonian has spinful time-reversal symmetry, skin modes can be induced by on-site dissipations under certain circumstances. As a concrete example, we employ the Rice-Mele model to illustrate our results.

A new Majorana platform in an Fe-As bilayer superconductor.

Iron-chalcogenide superconductors have emerged as a promising Majorana platform for topological quantum computation. By combining topological band and superconductivity in a single material, they provide significant advantage to realize isolated Majorana zero modes. However, iron-chalcogenide superconductors, especially Fe(Te,Se), suffer from strong inhomogeneity which may hamper their practical application.

Insight of the Influence of Magnetic-Field Direction on Magneto-Plasmonic Interfaces for Tuning Photocatalytical Performance of Semiconductors.

Boosting photocatalytic performance via external fields is an alternative and effective solution for improving the application performance of existing photocatalysts. Herein, using α-FeO-decorated TiO nanotube arrays as a model, we demonstrate the influence of magnetic field (MF)-direction on the photogenerated charge-carrier transfer behavior at plasmonic metal/semiconductor interfaces. For the first time, the photocatalytic activity is also found to correlate with the plasmonic metal species while applying an external MF.

Evidence of the Berezinskii-Kosterlitz-Thouless phase in a frustrated magnet.

The Berezinskii-Kosterlitz-Thouless (BKT) mechanism, building upon proliferation of topological defects in 2D systems, is the first example of phase transition beyond the Landau-Ginzburg paradigm of symmetry breaking. Such a topological phase transition has long been sought yet undiscovered directly in magnetic materials. Here, we pin down two transitions that bound a BKT phase in an ideal 2D frustrated magnet TmMgGaO, via nuclear magnetic resonance under in-plane magnetic fields, which do not disturb the low-energy electronic states and allow BKT fluctuations to be detected sensitively.

Continuous Matrix Product Operator Approach to Finite Temperature Quantum States.

We present an algorithm for studying quantum systems at finite temperature using continuous matrix product operator representation. The approach handles both short-range and long-range interactions in the thermodynamic limit without incurring any time discretization error. Moreover, the approach provides direct access to physical observables including the specific heat, local susceptibility, and local spectral functions.

Localized spin-orbit polaron in magnetic Weyl semimetal CoSnS.

The kagome lattice CoSnS exhibits the quintessential topological phenomena of a magnetic Weyl semimetal such as the chiral anomaly and Fermi-arc surface states. Probing its magnetic properties is crucial for understanding this correlated topological state. Here, using spin-polarized scanning tunneling microscopy/spectroscopy (STM/S) and non-contact atomic force microscopy (nc-AFM) combined with first-principle calculations, we report the discovery of localized spin-orbit polarons (SOPs) with three-fold rotation symmetry nucleated around single S-vacancies in CoSnS The SOPs carry a magnetic moment and a large diamagnetic orbital magnetization of a possible topological origin associated relating to the diamagnetic circulating current around the S-vacancy.

Spontaneous (Anti)meron Chains in the Domain Walls of van der Waals Ferromagnetic Fe GeTe.

The promise of topologically vortex-like magnetic spin textures hinges on the intriguing physical properties and theories in fundamental research and their distinguished roles as high-efficiency information units in future spintronics. The exploration of such magnetic states with unique spin configurations has never ceased. In this study, the emergence of unconventional (anti)meron chains from a domain wall pair is directly observed at zero field in 2D ferromagnetic Fe GeTe , closely correlated with significant enhancement of the in-plane magnetization and weak van der Waals interactions.

Broad-Spectral-Range Sustainability and Controllable Excitation of Hyperbolic Phonon Polaritons in α-MoO.

Hyperbolic phonon polaritons (HPhPs) in orthorhombic-phase molybdenum trioxide (α-MoO ) show in-plane hyperbolicity, great wavelength compression, and ultralong lifetime, therefore holding great potential in nanophotonic applications. However, its polaritonic response in the far-infrared (FIR) range remains unexplored due to challenges in experimental characterization. Here, monochromated electron energy loss spectroscopy (EELS) in a scanning transmission electron microscope (STEM) is used to probe HPhPs in α-MoO in both mid-infrared (MIR) and FIR frequencies and correlate their behaviors with microstructures and orientations.

Integrated Plasmonics: Broadband Dirac Plasmons in Borophene.

The past decade has witnessed numerous discoveries of two-dimensional (2D) semimetals and insulators, whereas 2D metals were rarely identified. Borophene, a monolayer boron sheet, has recently emerged as a perfect 2D metal with unique electronic properties. Here we study collective excitations in borophene, which exhibit two major plasmon modes with low damping rates extending from the infrared to ultraviolet regime.

Spin-Related Electron Transfer and Orbital Interactions in Oxygen Electrocatalysis.

Oxygen evolution and reduction reactions play a critical role in determining the efficiency of the water cycling (H O ⇔ H + O ), in which the hydrogen serves as the energy carrier. That calls for a comprehensive understanding of oxygen electrocatalysis for efficient catalyst design. Current opinions on oxygen electrocatalysis have been focused on the thermodynamics of the reactant/intermediate adsorption on the catalysts.

Fabrication and evaluation via nuclear quadrupole resonance of a palm cubic-anvil pressure cell.

A "palm" cubic-anvil pressure cell (PCAC) having an outer diameter of 60 mm, the smallest cubic-anvil cell to date, was fabricated to insert in a large-bore superconducting magnet. The pressure cell has a sample space of ϕ 2.5 × 1.

Superconductivity related to the suppression of exciton formation in 1T-TiSe.

In strongly correlated electron system, the impact of elementary substitution or intercalation plays a crucial role in determining electronic ground state among various macroscopic quantum phases such as charge order and superconductivity. Here, we report that simultaneous Cu intercalation and Ta substitution at Ti site in 1T-CuTiTaSeinduce an intrinsic electronic phase diagram, characterized by an inherent superconducting transition in theregion of 0 ⩽⩽ 0.12, with a maximum superconducting transition temperatureof 2.