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Chem Commun (Camb)
August 2020
Department of Chemistry, Southern University of Science and Technology, Shenzhen, Guangdong 518055, P. R. China. and Department of Chemistry, State Key Laboratory of Synthetic Chemistry, The University of Hong Kong, Hong Kong, P. R. China and HKU Shenzhen Institute of Research and Innovation, Shenzhen, Guangdong 518057, P. R. China.
A panel of natural aliphatic tertiary alkaloids (R3N) were directly converted to R3N+-NH- (without the need to prepare protected aminimides R3N+-NR'- followed by deprotection) by [Mn(TDCPP)Cl]-catalysed N-amination reaction, with O-(2,4-dinitrophenyl)hydroxylamine as the nitrogen source, in up to 98% yields under mild reaction conditions.
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