7 results match your criteria: "Organisch-chemisches Institut der Ruprecht-Karls-Universität Heidelberg Im Neuenheimer Feld 270[Affiliation]"

Building complex carbon skeletons with ethynyl[2.2]paracyclophanes.

Beilstein J Org Chem

September 2014

Institut für Organische Chemie, Technische Universität Braunschweig, Hagenring 30, D-38106 Braunschweig, Germany.

Ethynyl[2.2]paracyclophanes are shown to be useful substrates for the preparation of complex, highly unsaturated carbon frameworks. Thus both the pseudo-geminal- 2 and the pseudo-ortho-diethynylcyclophane 4 can be dimerized by Glaser coupling to the respective dimers 9/10 and 11/12.

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The addition product of sodium hydride and the 2,3-dihydro-1,3-diborole (CiPr) (BEt) CHMe (3c) reacted with [{(C Me )FeCl} ] to produce the green sandwich complex [(C Me )Fe{n -(CiPr) (BEt) CMe}] (2 c), which formally contains 16 valence electrons (VE). Complex 2c has unexpected structural properties in the solid state: the 1,3-diborolyl ring is extremely folded (41°), and the Fe-C2 distance is short (1.90 Å).

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