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Despite their remarkable mechanical, optical, and electrical properties, inorganic particles and dynamic polymer assemblies encounter difficulties in their compatibility with regards to structural order and complexity. Here, covalent organic frameworks (COFs) constructed through reversible coupling reactions were exploited as dynamic porous polymers to prepare inorganic nanocrystal-polymer assemblies. Under an growth process, carbon quantum dots (CDs) were gradually prepared in the COF cavity, with a narrow size distribution (2 ± 0.

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