Rhenium in the core of porphyrin and rhenium bound to the periphery of porphyrin: synthesis and applications.

An overview of most of the well known rhenium porphyrins (rhenium in the core of porphyrins) is presented here reviewing their synthesis, coordination chemistry, and applications. The important features of oxorhenium(v) porphyrins are discussed elaborately taking into account their application in epoxidation reaction. Moreover, the chemistry of some recently known porphyrin-Re conjugates (rhenium bound to the periphery of porphyrin) is reported considering their applications in the photochemical carbon dioxide reduction process and photodynamic therapy.

Aflatoxins: A Global Concern for Food Safety, Human Health and Their Management.

The aflatoxin producing fungi, , are widely spread in nature and have severely contaminated food supplies of humans and animals, resulting in health hazards and even death. Therefore, there is great demand for aflatoxins research to develop suitable methods for their quantification, precise detection and control to ensure the safety of consumers' health. Here, the chemistry and biosynthesis process of the mycotoxins is discussed in brief along with their occurrence, and the health hazards to humans and livestock.

Essential Oils: Sources of Antimicrobials and Food Preservatives.

Aromatic and medicinal plants produce essential oils in the form of secondary metabolites. These essential oils can be used in diverse applications in food, perfume, and cosmetic industries. The use of essential oils as antimicrobials and food preservative agents is of concern because of several reported side effects of synthetic oils.